Carbanion Stability

This organic chemistry video tutorial provides a basic introduction into carbanion stability and compares it with carbocation stability.
Stereochemistry R/S Configuration: • Stereochemistry - R S ...
Optical Activity & Specific Rotation:
• Optical Activity - Spe...
SN1, SN2, E1, E2 Reaction Mechanisms:
• SN2 SN1 E1 E2 Reaction...
SN2 Reaction Mechanisms:
• SN2 Reaction Mechanisms
SN2 - Test Question:
• SN2 Reaction Mechanism...
_______________________________
SN1 Reaction Mechanisms:
• SN1 Reaction Mechanism
Carbocation Stability - Hyperconjugation:
• Carbocation Stability ...
Protic Vs Aprotic Solvents:
• Polar Protic Solvents ...
E1 Ring Expansion:
• E1 Reaction Mechanism ...
E2 - Test Question:
• Zaitsev vs Hoffman's P...
________________________________
E2 Stereochemistry - Newman Projections:
• E2 Stereochemistry Wit...
SN1, SN2, E1, E2 - Practice Test:
• SN1 SN2 E1 E2 Reaction...
Organic Chemistry PDF Worksheets:
www.video-tuto...
Organic Chemistry 1 Exam 2 Playlist:
bit.ly/3PKEApB
Full-Length Videos and Worksheets:
/ collections

[@TheOrganicChemistryTutor]

Organic Chemistry PDF Worksheets: www.video-tutor.net/orgo-chem.html Full-Length Exams and Worksheets: www.patreon.com/MathScienceTutor/collections Next Video: kzbin.info/www/bejne/rWjch4mCiLZsebc

[@PunmasterSTP]

I totally forgot that the stability of carbanions is exactly *opposite* to that of carbocations. Thanks for reminding me, and thanks again for all of your wonderful videos!

[@smilewithtrends804]

No it's not exactly opposite

[@PunmasterSTP]

@@smilewithtrends804 How so? Is there a mistake in the diagram he drew (3:46)?

[@ubiquitousgamer955]

@@PunmasterSTP it is true for those 1,2 and 3 degree carbanions but in the second part you can see that the carbanion with more resonance structures is more stable, same condition is true for carbocations. So yeah not exactly opposite.

[@PunmasterSTP]

@@ubiquitousgamer955 Gotcha, and yeah I totally agree! Sorry if my original comment was unclear; I just meant to refer to the ordering based on number of attached alkyl groups, not other things like resonance.

[@ubiquitousgamer955]

@@PunmasterSTP No worries mate.

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[@sundaskhan3426]

What is the relation of carbanion with stability??

[@nerengen0054]

Tertiary carbanion will be less stable and methy carbanion will be more stable... Do you want the reason??

[@luciferfan198]

@@nerengen0054 can u explain the reason pls

[@nerengen0054]

@@luciferfan198 Stability order of carbanions decreases as we move from primary to tertiary anion because due to +I effect of methyl groups there is an increased intensity of negative charge on central carbon of tertiary carbanion which further makes it unstable. If you dont understand Ask again ✨

[@mrsmaggie.]

So here he compared carbocations with carbanions?

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[@hanzsaribay233]

On the first group methyl is the least stable, then it became the most stable for the second group. How's that so?

[@fatimagajere7722]

For cation, methyl is the least stable and for the anion methyl is most soluble

[@nerengen0054]

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But aren't anions negatively charged?

[@ubiquitousgamer955]

they are.

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[@ketofitforlife2917]

I never have understood the orbital lobes or how they are drawn as overlapping. When I look at the actual lobe, I was assuming that is the region the bonding and nonbonding electrons with the associated atom resides. Then when my book talks about sigma, pi and overlapping bonds... that whole perception breaks down. If electric regions are overlapping, why don't we just draw them that way? I don't understand.

[@ubiquitousgamer955]

lobes are region where electron is present or can be found, when lobes overlap then we are trying to say that we can also find electrons in the overlapped region, in sigma and pi overlap, the overlap is big and strong enough to be considered a bond, but in hyperconjugation the overlapping is not that strong such that it can be considered a bond, it's just electron cloud, in fact it is so weak that we don't consider representing it. but when comparing stability those overlapped lobes can increase stability, that's how it helps us to explain why some compounds are more stable compared to others by comparing overlapping of their lobes.

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