Markovnikov’s Rule vs Anti-Markovnikov in Alkene Addition Reactions

[@mayadepolo3648]

you ate this up and left no crumbs. you gobbled the whole plate if you will. i feel exponentially better at orgo chem just after a short 18 minutes. if i get a passing grade on my midterm i will name my first born after you. you are my lord and savior god bless you god bless america god bless canada god bless everyone because praise the lord i get organic chemistry. today is a good day. mark it in your calendars everyone. today is a good day.

[@Leah4sci]

This is probably the best thank you I've ever received lol!

[@princessdaughter-s2c]

I love this comment

[@hammystar1045]

IM CRYING this is exactly how i feel.... praying i dont gotta retake this class

[@michelleacquaye8771]

I laughed out loud at your answer to the question: "Leah, which one of these rules should I memorize?" Your answer "Neither"; that was great! Thank you so much for this clear video! Your pace and tone are great! Also I think your rule : "the rich get richer" can also be applied to the Nu because the C that is richer in substituents gets richer in substituents ? Again, Thank you SO much!!

[@Leah4sci]

You're very welcome!

[@jameyatesmauriat6116]

Why do you laugh at us?

[@damnthisgirl2130]

Fr I even copied down on my notes alr

[@kalamageshwaran1297]

U r one of d only tutors who actually respond to comments thumbs up 4 d video

[@Leah4sci]

I try, I don't always have time. :)

[@Xintoii]

I’m glad I found this video. I know it’s 3 years old, but I’m so thankful for it! I have a very bad professor who makes these topics more confusing than they are and barely delves into it, but coming to your video you made it seem so much easier. I’m not currently passing my class, but I hope and feel this video definitely made a difference for me and gives me hope for my quizzes/exams!

[@Leah4sci]

I'm glad you found this, too, but I'm so sorry that you're dealing with a bad professor and struggling in the course because of it. Use leah4sci.com/syllabus to match my resources to what you're studying.

[@sweetie1208]

Please don’t stop releasing these videos ! I have even paid for some and they explain in a complicated way still. You are the only one that even a baby can understand her teachings ❤ God bless you

[@Leah4sci]

I'm so glad to help! I plan to continue posting free videos, as I have time. But for more focused help on topics like this and more, I recommend joining the organic chemistry study hall. Details: leah4sci.com/join or contact me through my website leah4sci.com/contact/

[@vom-batus]

I want to give a very warm thank you Leah. You'll helping me get through my degree, and concepts that were once a mystery, now make sense so thank you

[@Leah4sci]

You're so welcome!

[@GreyHorn-sq3ug]

What's your degree

[@vom-batus]

@@GreyHorn-sq3ug it was a bachelor of science, major ecology. But I did organic chemistry units

[@GreyHorn-sq3ug]

@@vom-batus we study same concept in our high school So I thought to just confirm

[@AngelaW7995]

You are such a good teacher, explained the content so clearly and easy to understand! I appreciate your video!

[@Leah4sci]

Thank you so much! I'm glad you liked it.

[@noelmoon2454]

In a span of a week lecture, I understood this material in 18:31 -_- but, Thank you SOOO MUCH!!!

[@Leah4sci]

You're very welcome, glad I could clear it up for you!

[@rehabalsaleh166]

Thank you, I almost watched the whole video playlist of alkene reactions even though I knew about you today by accident. So happe I came across your channel!

[@Leah4sci]

Glad you found my channel!

[@johanncrispillejera2904]

omg, I'm so happy I found your channel! you gave me a different perspective towards this concept and I now understand it so much more holistically.

[@Leah4sci]

I'm so glad! Thanks for commenting to let me know!

[@socoriosa2423]

oy pisay scholar spotted

[@johanncrispillejera2904]

@@socoriosa2423 😅

[@JamesMusonda-db5tc]

So powerful than ever

[@ayeshamashiatisstudying]

In simple words, I love youuuuuuuuuuuuuu. Love the to-the-point explanations and you made a bonanza of em here lmaoo but love ittt

[@Leah4sci]

Awww thanks!

[@endyelijah1330]

I love your voice for your explanation comes so clear. Thank you so much Leah.👍👍

[@Leah4sci]

You're so welcome!

[@mikkocapio4078]

Thank you for your help im only a year 12 in New Zealand which just started to learning about this helps since my teacher likes our class to find our answers out there instead of teaching it to us directly. Thanks to this I might be able to get on top of this before anyone else.

[@Leah4sci]

oh wow, on the one hand it's good that you're made to learn how to search for information, but to not teach at all... glad you found my videos to help you

[@metou3072]

0:50... instead of just saying that you are forced to name the lowest number first...and though it's correct I feel that it's easier to also add..." Everything takes the path of least resistance if no outside force is used on it"...why I think it's better is because not only are you learning a/the rule...you also learn exactly why it is the rule...understanding it instantly become extremely simple to understand and remember...the goal is to know information and remember it...not only just know it...tying multiple things together is easier to remember... even better if you have to remember lists of things is to make a short story using the first/or a few.. letters of the names of things you are trying to remember and use that in a short story /sentences... essentially it's a human zip.file and keeps more space to remember other things... people try to brute force information into their brains... guarantee that everyone struggling in school does not understand how information storage works in their brains and they try to force themselves to learn

[@Leah4sci]

Each person has to do what works best for their brains, this is just one way, but you do what works best for you!

[@pietrozangrando800]

i love you, you could explain difficoult concepts to my newborn niece, thanks a lot for all your chemisty videos

[@Leah4sci]

I could try, but I think she would rather hear a good book :)

[@marykrd456]

Lady I can not thank you enough!!!! I have to take this test for my new job and I had to go over my lessons from college and for someone in her 30s and being away from these concepts for more than 10 years I thought i had no chance. But you changed my life Thankssss

[@Leah4sci]

you're very welcome!

[@MELONHEAD13B]

Leah, you're a freaking genius and a queen. Thank you.

[@Leah4sci]

You're so welcome. :)

[@PHILIPSUBA-jb5df]

Thank you so much Leah, I tried to understand this concept for about a month but I didn't .With your explanation now I understood it very well.

[@Leah4sci]

You're welcome! Glad to hear it!

[@Akila-s]

The way you explain things is amazing I wish I didn't spend most of the semester sick and could have followed everything without being in a rush because of exams... Was probably going to do very well.. I can try to do better in the next ochem courses I take But it is what it is, still very thankful for your videos and will probably be the reason I pass(hopefully)

[@Leah4sci]

Fingers crossed (after I finish typing) that you're able to pull through. Hope you're recovering and can learn all you need to in time!

[@allwasmie]

youre the light shining in my worldddd thank youuu!! I have orchem exam tomorrrow and im currently binge watching your video XD

[@Leah4sci]

Oh wow, I am humbled, thank you! I hope your exam went very well and that my videos were able to help you learn and understand

[@Pete-da-peter]

God knows there would be a pandemic in 2020, and He also knew that student would have to learn online, AND GOD SAID to himself, I need to send leah on earth to save the world. THANK YOU SO MUCH FOR TAKING TIME TO DO THIS

[@Leah4sci]

Awwwwww! I'm very glad I could help you!

[@shreyaanand2193]

Thanks alot Ma'am , you have cleared my earlier doubts ... Which i had till now 😀

[@Leah4sci]

You're very welcome! Glad I could clear things up for you!

[@aditikumar6168]

Your explanations are amazing. I understood this way better now thanks to you.😀😀❤

[@Leah4sci]

Happy to help!

[@ua4788]

Leah you are awesome, thank you a lot!

[@Leah4sci]

You're so welcome!

[@Civil-Eng-Research]

Hello ma;am i am from nepal,your video is very supportive and helpfull for me ,so thank you for this👍️

[@Leah4sci]

You're welcome!

[@uppularajesh4659]

Nice i love your classes Very vivid good explanation It help me alot tq

[@Leah4sci]

Happy to help!

[@BlueLillica]

15:26 I am so confused here - Is it correct that the product with the Bromine atom on the primary carbocation at the bottom reaction related to your alkene practice problem 1? When I clicked on the link to learn more about the material tested in that problem, the examples solely portrayed Markovnikov rule. Does this difference have something to do with the peroxide solvents? Thank you for the content!

[@Leah4sci]

Yes, the major product of this reaction will have bromine on the primary carbon. But it's important to note that there is NO carbocation intermediate in this reaction. This is a radical reaction, with a radical intermediate, that is initiated by the use of peroxides. For more on the mechanism of the anti-markovnikov radical halogenation of alkenes, watch the following video: kzbin.info/www/bejne/bKHXdIStlJiEobc

[@choosen1130]

Thank you for the video it really helped

[@Leah4sci]

You're welcome!

[@GaminGVersE172]

Accidently I got your video. But Really your explanation is too good i was very confused about this topic but now its clear just bcz of u

[@Leah4sci]

Glad you accidentally found this video and it helped you!

[@harteijvkr5579]

Thanks a lot for that explanation really needed it, now understood the concept clearly .

[@Leah4sci]

So glad to hear it! You're very welcome.

[@shashankmhaldar9310]

Thanks for such a nice and clear video...

[@Leah4sci]

You're welcome, glad it was helpful!

[@CarlosADasilva]

This was Gold thank you

[@Leah4sci]

You're so welcome!

[@anowerhossain3705]

Really, u explained this topic in a very easy way,thank u very much😍

[@Leah4sci]

Glad you liked it!

[@tatsu6855]

Thanks a lot for simple explanation!!! I needed this alot for my competitive exam.

[@Leah4sci]

You are welcome! Hope the exam went well.

[@hhan2470]

wow…. your videos are amazing thank you so much, this saved me from my 2 year brain drain, subscribed and liked thank you

[@Leah4sci]

Awesome, thank you! I'm so glad I was able to help you refresh what you had learned!

[@emersonlima9725]

Amazing explanation, thanks

[@Leah4sci]

You are welcome!

[@felixchiputa9969]

Bring up some more reactions

[@Leah4sci]

For more on Markovnikov's Rule, including examples and explanations, make sure to see my tutorial at Leah4sci.com/Markovnikov

[@pexaminer]

And yet another great video!

[@Leah4sci]

Glad you liked it!

[@pu-m3451]

Thank U. Than explanation is wonderful. 🙏

[@Leah4sci]

You're most welcome!

[@s-series1249]

Awesome lecture ❤️

[@Leah4sci]

Thanks! Glad you liked it!

[@oswardmumba5275]

Hello Leah kindly be writing the answers on top most of the things can't be seen due to the writings been done,.......Thank you for you will put this in consideration.

[@Leah4sci]

None of the text is overlapping in this video. You might try watching on a different device. Thanks for watching. :)

[@chimwemwegerald8745]

Wow I memorized this and I forgot now I know I will never forget

[@Leah4sci]

Glad to hear the video was helpful! Thanks for watching.

[@osamaemad4212]

Thank you so much ❤ From egypt 🇾🇪🇾🇪🧡

[@Leah4sci]

You're welcome 😊

[@fakhrulnawawi9681]

Totally understand your tutorial thank u

[@Leah4sci]

that's awesome! You're very welcome

[@5NChemistry]

Can you do the mechanism of reaction pent-2-ene + HBr? Thanks 🙏

[@Leah4sci]

I'm sorry, but I don't offer tutoring over social media. The mechanism presented in this video is almost exactly what you're looking for, as there is only one less carbon in the parent chain. For help with questions like this and more, I recommend joining the organic chemistry study hall. Details: leah4sci.com/join or contact me through my website leah4sci.com/contact/

[@koustubhranjan2573]

Nice one mam.... this helped me a lot..thank you ❤️

[@Leah4sci]

you're very welcome

[@jdollaz6827]

you are awesome thank you so much much better than my teacher

[@Leah4sci]

Wow, thanks!

[@sweetie1208]

Thanks

[@Leah4sci]

You're so welcome!

[@abelinagonzales8174]

Thank you very well explained😃!!

[@Leah4sci]

Glad you liked it! You're welcome.

[@tamjeedzawan6554]

QUEEN (PART 2)

[@Leah4sci]

thanks

[@jimhiggs6281]

Leah, Just BRILLIANT! Everything is about stability yes. But you didn’t explain WHY it would be more stable adding in that position. Would adding onto the more substituted group be more stable because it can spread the extra charge load better across more carbons in the nearby vicinity? Please help.

[@Leah4sci]

You mean carbocation stability? I cover that here leah4sci.com/carbocation-stability-and-ranking/

[@pumba250]

Thanks mam this topic is very important for JEE mains!!

[@Leah4sci]

You're so welcome 😊

[@becksn482]

Hey Lea, I'm enjoying your Content. This helps a alot for my exams. I have problems to know when a transition state and a intermediate are formed in a reaction. Unfortunately I cant find a Video about this. Is it possible to go in the deepth of ? Thanks so far for your value. :)

[@Leah4sci]

Glad my videos are helping. As for transition states and intermediates, this varies per reaction and is not a simple/generic answer. Which reactions specifically?

[@becksn482]

@@Leah4sci Hey Leah, lets take a example of an ester hydrolisis acid and base catalysed. I'm confused, if you have to write a transitionstate in both cause it is actually a SN2 reaction. Some websites show this reaction with, some without a transition state and instead of this with resonance structures. Thank you :)

[@maibarak1921]

Hi Leah i love you thank you for existing

[@Leah4sci]

Aww thanks for your kind words!

[@syuhadaafiqah]

Totally helped me understand better. Btw, idk if it’s just me but you sound like Harley Quinn from the suicide squad movie 😂

[@Leah4sci]

I'll take that as a complement, thanks!

[@killemlove4339]

Can't unsee thissss now that u mentioned it.

[@AlJofe]

Literally was copying down those 3 shortcuts in pen ugh 😑

[@Leah4sci]

Ugh is right!

[@hiramkenya2549]

Thanks @Leah I'm Hiram from Kenya,Africa, but is there a video about hybridization and drawing structures(open chain,and cyclic structures) for alkenes and alkynes.? Kindly help

[@Leah4sci]

Hi! I just replied to your email about my resources tonight. Please feel free to email about this, too.

[@letiwaloishoo4362]

very good for understanding

[@Leah4sci]

Glad to hear it!

[@superded6092]

How do you know when a reaction will become anti-markovnikov?

[@Leah4sci]

It really depends on the particular reaction mechanism. For instance, in radical reactions, the substituent adds to the alkene before the formation of the radical intermediate. Since we want that radical to be as stable as possible, we see the substituent adding to a less-substituted carbon to begin with. Another reason for Anti-Markovnikov products might include steric effects. To view my cheat sheet on alkene reactions, visit leah4sci.com/alkene-reactions

[@SajjadMoslehi]

Great job

[@Leah4sci]

Thank you!

[@MeruJain-jl5os]

thank you so much ❤

[@Leah4sci]

you are so welcome

[@sandisilesilvestermatroshe8980]

Wow! I'm mindblown!

[@Leah4sci]

Glad you like it!

[@VinodReddy03]

Leah for science its real🙌

[@Leah4sci]

Glad you like it!

[@Ap_Productions04]

Hey where did u get the OH from at 11:07

[@Leah4sci]

The alcohol group comes from an attacking water molecule. For more on the mechanism of an acid-catalyzed hydration reaction, visit my tutorial at leah4sci.com/acid-catalyzed-hydration-of-alkenes-reaction-and-mechanism/

[@shamic100]

Recommend this video tutorial. UP. 🙌👍

[@Leah4sci]

Thank you!

[@jasonvaughn4177]

You’re a badass Leah, thanks for all your videos 😁👍🏻❤️

[@Leah4sci]

You're welcome!

[@jz695]

i need your help leah, its my first year in biotechnology uni and i have a big problem, i study organic chemistry and i feel like i dont understand anything in the lec or when i study by myself, so i need a way to start organic chemistry from the very beginning , how to start , what to keep , etc. please help me.

[@Leah4sci]

Reach out to me with this at lea4sci.com/contact and let's discuss how to help you reach your goal

[@adiliraliyev5882]

Does Mk's rule governed by electronegativity: c-c-c (carbon between other carbons would be more positively charged, since electrons are more evenly spaced out) and h-c-h ( carbon between hydrogens would be less positively charged since it is more electronegative than hydrogen, thus pulling electrons closer), there for negative halogen would be attracted to carbon that is more positive because it is between other carbons that's share electrons more evenly making it more positive? Rule is more positive carbon would attract more negative atom.? Could this be it?

[@Leah4sci]

Yes, this is a correct observation. Markovnikov’s rule is governed by electronegativity in the sense that the more positively polarized atom will be attracted to the less substituted carbon and the more negatively polarized atom will be attracted to the more substituted carbon. As you said, a carbon between other carbons is able to share electrons more easily with neighboring atoms and, ultimately, holds a positive charge better.

[@Shan-sg7mm]

Please tell me Markovnikov reaction follows first order kinetics or 2nd order kinetics 🙏

[@Leah4sci]

That question is outside of the scope of this video. Since I don't offer tutoring over social media, I recommend joining the organic chemistry study hall for help with this question and more. Details: leah4sci.com/join or contact me through my website leah4sci.com/contact/

[@strugglingcollegestudent]

omg thank you its finally making sense

[@Leah4sci]

You're so welcome, I'm happy my video helped you!

[@Mohamed-xz1fq]

It s only hbr you can do anti markovnikove in it or al the halogene

[@Leah4sci]

The non-radical hydrohalogenation of an alkene always follows Markovnikov's rule. That would work for HCl, HBr or HI. But, the radical hydrohalogenation of an alkene with HBr would be anti-Markovnikov. Make sure to visit my tutorial and download my cheat sheet on these Alkene Reactions at Leah4sci.com/Alkene

[@srianitha3142]

Leah at "9.30" (time stamp) you said the nucleophile doesn't attack the more substituted Carbon because it's greedy !! What it means !! I'm collapsed at that point. Please clear me at that point Leah. Thanks a lot for that. Looking for your answer.

[@Leah4sci]

Thanks for asking so I can clear this up for you! The nucleophile DOES attack the more substituted carbon. I think you misunderstood my statement. It’s greedy in the sense that it is negatively charged and will naturally be drawn to attack anything with a positive charge. The reason why the majority of our product is the more substituted halide is because more of the tertiary carbocation is present as an intermediate.

[@srianitha3142]

@leah4sci Thanks a lot Leah for clearing me with that. I'd misunderstood that. Now I'm clear !

[@nurulalya8769]

okay its so hard at the first try, lemme try it again and i will share my progression here

[@Leah4sci]

Yes, keep trying, and if you need more help check out the Study Hall: leah4sci.com/join

[@hiba2557]

Thank you ❤ from Algeria 🇩🇿🫂

[@Leah4sci]

You're welcome!

[@Mohammed-wy2yh]

Thanx 4 this videos

[@Leah4sci]

You're welcome!

[@treasureordinioha4206]

Hello please H2SO4 was cancelled to give OH How did it happen

[@Leah4sci]

I crossed out the H2SO4 and wrote H+, because we should recognize that sulfuric acid is simply a source of protons for the reaction. The reaction you're looking at is the Acid Catalyzed Hydration of an Alkene. For more on the reaction and mechanism, see my tutorial at leah4sci.com/acid-catalyzed-hydration

[@treasureordinioha4206]

@@Leah4sci Thank you

[@elizabethmulenga298]

Wow thanks very much

[@Leah4sci]

You're so welcome!

[@secretsocietyserver]

Thanks!

[@Leah4sci]

You're welcome!

[@chipambalamusole7831]

The anti markonikov is really confusing passed through it a couple of times but still couldn't get it

[@Leah4sci]

Sorry you're having problems with that. Some reactions choose NOT to follow Markovnikov’s rule, and this is not because they don’t want to have stable intermediates. Actually, it’s quite the opposite. Depending on the mechanism, some reactions find that their more stable intermediate allows for addition at the less substituted carbon. For more on this, visit Leah4sci.com/markovnikov.

[@rudro5784]

Thank you mam

[@Leah4sci]

Most welcome 😊

[@arpitwasnik]

Ty

[@Leah4sci]

You're welcome

[@gavinlopez7302]

Thank you :)

[@Leah4sci]

You're welcome!

[@Fmartey]

Very useful

[@Leah4sci]

Glad you like it!

[@mahfoodaldery4735]

Miss please try to explain general chemistry 2 please please please

[@Leah4sci]

Thanks for the recommendation. I post free videos as I have time and am always looking for suggestions. For more help with this topic in the meantime, contact me through my website: leah4sci.com/contact

[@aqualife88]

so much fun i love it

[@Leah4sci]

YAY, so glad you find it fun, that's my secret mission!!!

[@abdellkadermco6407]

u r the best ❤

[@Leah4sci]

Thanks so much!

[@evann1136]

Alright lady you got your like, lol. Great vid

[@Leah4sci]

Awesome, thanks!

[@legna3648]

Haha just what I was thinking !

[@tamilbiology5078]

Mind blowing 17.17

[@Leah4sci]

:)

[@mohamedbawzyr1802]

H Rich get H Richer..love it Thanks 😻🌷

[@Leah4sci]

You're welcome!

[@r.l.jackson6252]

You ROCK!

[@Leah4sci]

Thanks!

[@babygiirl0931]

I don’t get it 😢

[@Leah4sci]

Which aspect?

[@babygiirl0931]

@@Leah4sci all of it. It’s ok. I’ll go to tutoring

[@8Aboudi8]

I just want to say that I love you

[@Leah4sci]

Thanks, but let's keep it professional :)

[@kadirbadshah4853]

Oh thanks mam i like it

[@Leah4sci]

You're very welcome

[@kadirbadshah4853]

@@Leah4sci mam where are you from

[@theclassroomdoc]

Leah, please never do anything else in your professional life BUT teach because you have such a gift it would be a shame not to use it!!!

[@Leah4sci]

Thanks so much for the amazing compliment!

[@Монсие]

T hank you

[@Leah4sci]

You're welcome!

[@superhessu3]

let it be known rich get richer :/

[@elizabethmulenga298]

You are a great teacher thank you so much 🙏🙏😌

[@Leah4sci]

You're very welcome

[@1337rico]

Thanks Leah, youre a badass!

[@Leah4sci]

You're so welcome, and thanks!

[@tidimalotseke9541]

Rich get richer, poor gets poor...😊...

[@Leah4sci]

Lol

[@RobaDesta-i7g]

Please romove sub title it is blocking leah❤❤❤

[@Leah4sci]

Do you mean the closed caption? They are really important for many of my students, but you can remove them on your end, simply click the CC button at the bottom of your screen.