at the very beginning, he had typos to say 4f electrons protected by 5s and 5p electrons for rare earth element, but I think they should be 6s and 5d electrons.
@vishnuunni.c98026 жыл бұрын
At 10.50,. Its stated that... An imaginary operator acting on a real function gives eigen value equal to zero ? How ?
@moglibora5 жыл бұрын
It's not the eigenvalue, the expectation value would be zero
@sairamithineni25884 жыл бұрын
@@moglibora why would that vanish again
@shaikwasef69744 жыл бұрын
The angular momentum Lz operator acts on a wave function ( say f ) as the following : -i.hbar.(dow.f/dowphi) = m.hbar.f if f is a real function, we would not get a real eigenvalue ( m is the magnetic quantum number and is real , hbar is real , hence m.hbar is real ) since the i term on the left cannot vanish. The only way this equation is satisfied is if the eigenvalue is zero.
@nabeel123ful Жыл бұрын
@@shaikwasef6974 Thanks for your explanation, but why would we force the eigenvalue to vanish instead of questioning the validity of the assumption of a real wavefunction? Of course, this goes back to why would a nondegenerate eigenvector of an operator must be real, which I don't quite get.