I really like the addition of clocks and timers to give context to the time lapse footage! Thanks Sreetips!
@arnold4radiators Жыл бұрын
I love the new lighting! Watching that gold precipitate with the SMB under that light is magical.
@pank524 Жыл бұрын
Man that blue color is something else
@wannabetall2000 Жыл бұрын
It's really cool to see the process with a different base metal. I was quite surprised at how difficult the copper looked when melting.
@duanedodson1 Жыл бұрын
Copper melts at a very high temperature.
@williamfoote2888 Жыл бұрын
@@duanedodson1Well.. higher than Ag.
@duanedodson1 Жыл бұрын
@@williamfoote2888 Yes, it is about 20 degrees Celsius higher than gold. Also, the smaller gold pieces heat up quicker than the larger piece of copper wire.
@buenodye4723 Жыл бұрын
MSB , on that first spoonful has always been my favorite part . Watching the cloud form and change 👌
@DonnyHooterHoot Жыл бұрын
I know professional refiners don't value copper too much but I love it's color! The colors of copper's salts are very beautiful blues and greens. Great video!
@prophylaxis24 Жыл бұрын
That beaker bump at 14:35 nearly gave me a heart attack. Loving the increased production value, thank you again sir, always a treat.
@mijour Жыл бұрын
I would love to see a video on the setup you have and all the safety equipment you use and wear.( Fume hood,chemical storage ,etc.) My wife and I have collected over 4 lbs of Gold filled scrap from thrift stores over the last two years (tip .go on senior's day to get 20 % off) and was thinking of processing it in the near future and would like to do it as safely as possible
@sreetips Жыл бұрын
Fume hood is a must. After that, I’d recommend doing a small batch, a hundred grams, to completion. To get a feel for it. Then scale up a little at a time. Four pounds is enough to do several small batches.
@progoldsmith Жыл бұрын
I’ve been a goldsmith 36 years refined my first through electrolysis. ( I was a novice at the time). Apprentice. I’ve relearned a lot from your knowledge of chemistry and safety . Your teaching a whole generation to be confident in skills instead of college debt.
@sreetips Жыл бұрын
Thank you!
@Phoenix38m Жыл бұрын
A thought occurred to me, Sr. Chief....i looked up the melting points of both copper and silver....silver melts at 1763 F. Copper melts at 1984 F. I don't know how much Acetelyne or MAP gas costs out there, but the extra 200 degrees to melt copper every time you need to inquart might start to add up.
@tribble1 Жыл бұрын
The specific heat of copper is higher than the specific heat of silver, however the amount of material we're looking at is so small that we're talking about a few more seconds of acetylene to melt the copper anyway.
@sreetips Жыл бұрын
Correct, but I’m still using silver. This was just a demo
@MADDLADO1 Жыл бұрын
Nice alternative to always having to deal with silver every time, well done !!
@Antonowskyfly Жыл бұрын
You are welcome. Adding copper to my placer gold was something a friend suggested I do a few years ago, I thought he was nuts until he briefly explained inquarting. Fortunately, I wandered into your channel whist in search of a more thorough explanation and found not only that but much more. Thank you Sir!👍👍🤟
@tyrettke2450 Жыл бұрын
Those blue shades are incredible. I love the pulsing during the boilings that has been happening the last couple videos during the nitric boil time lapses. It is reminiscent of heart beats.
@Rob337_aka_CancelProof Жыл бұрын
I've been noticing that too and it's kind of interesting that it happens with the 6 carrot (25%) Nitric boils but not with hydrochloric or AR but only with the inquarted gold nitric boils which is kind of interesting and I wonder why that is
@timhooper1557 Жыл бұрын
It's the hotplate turning on then off, maintaining temperature. I too find the rhythm pleasing to watch :)
@sreetips Жыл бұрын
It’s the thermostat on the heating pad cause it to pulse during the time lapse.
@mikeconnery4652 Жыл бұрын
That was so funny
@NorthFlPicker Жыл бұрын
I’ve been hoarding scrap gold and silver for awhile now. I found your channel a couple of years ago and have been trying to learn everything I can from you. We are going to be moving soon, and when we do, I’ve already budgeted in a large shed and everything I need to. I’ve been wanting to refine my gold and have to stay on myself to wait until I have everything I need… thanks for another great video sir
@sreetips Жыл бұрын
Get a fume hood! No way to safely do these reactions without one.
@NorthFlPicker Жыл бұрын
@@sreetipsyes sir, I’ve already designed my setup and made a list of everything I need and want and a fume hood is #1 on the list.
@Sanzus2 Жыл бұрын
The smb drops were stunning, loved the close ups! Great result with a nice little bar at the end!
@BeMoreGooderPeople Жыл бұрын
When you add the stump out it reminds me of the surface of a few planets they show.
@copperinquarter Жыл бұрын
Wonderful video, Mr Sreetips! But everybody knows I'm the REAL Copper Inquarter! 😆 Let me give you some advice, good sir. When you do your nitric acid boils to remove base metals... for copper inquartations, measure out 4.2ml of nitric acid per gram of base metal and add a little more nitric acid for good measure. For 10k, you can use the 5.2542 constant multiplied by the weight of the karat gold to easily determine how much nitric acid in ml is required. For 14k, you can use the 7.3584 constant. Use this same amount of distilled water for your nitric acid dilution. Let the reaction progress for about 3-4 hours until there are absolutely zero fumes left. Then decant this base metal solution and rinse the gold well with distilled water followed by a distilled water boil. This distilled water boil with remove all remaining color deep within the gold. Rinse a few more times with distilled water then perform a second nitric acid boil. You will notice that this second nitric acid boil will produce zero fumes and zero color. Allow this second nitric acid boil to progress for a good 30 minutes for good measure, then decant and save this unreacted dilute nitric acid for a future refining. Then you can rinse the gold with distilled water a few times and perform another distilled water boil followed by a few final distilled water rinses. You can then proceed to dissolving the gold in aqua regia as usual. I have followed this procedure multiple times and it never fails and produces stunning looking gold. Again, great work, sir! And thank you for the wonderful content! Cheers! Copper Inquarter
@VendettaProspecting Жыл бұрын
there he is lol!
@kurtremislettmyr7108 Жыл бұрын
Just so calming to watch your videos. Thanks.
@Rob337_aka_CancelProof Жыл бұрын
It's that radio voice XD
@spencermaiers8322 Жыл бұрын
That's one of my favorite things about Sreetips. Totally chill. Enjoy on the edge of your seat or just listen.
@mikeconnery4652 Жыл бұрын
I agree
@jeepin4on4 Жыл бұрын
Thanks for sharing, I can't find much sterling silver around here so I almost always use copper for inquarting or parting. I'm glad you shared another video on using copper.
@ArielleViking Жыл бұрын
A lovely result. I too enjoy seeing the timelapses and the addition of clocks and timers. 👍
@PaulBrown-uj5le Жыл бұрын
Omg lol, I'm in bed just about to go to sleep and i see a new gold video, kevin, it's 2:54 here in Ireland 😂😂😂.
@sreetips Жыл бұрын
Sorry about that!
@adws5696 Жыл бұрын
I'll like to see copper being used to inquart the gold from now on. I don't know why but the rose gold is beautiful and of course very little silver chloride to deal with 🙌🏻. Also i would suggest that you sumerge the ingots in diluted sulfuric acid to remove any left over borax (like you do sometimes), i know it may be not needed but just to be perfect 👌🏻. I love this channel!
@NOFX0890 Жыл бұрын
Awesome work Sreetips.
@laserfloyd Жыл бұрын
I feel like the gold crashing out of the solution would be a cool effect in a movie if shot with a macro or probe lens. 🤔 Looks like billowing clouds forming out of nothing. It's very satisfying to watch that part.
@frantiseklaluch6605 Жыл бұрын
Hello sir, copper seems to be better indicator, if the nitric boil is clean, however nitric consumption is like 4x higher (I calculated it some time ago, I remember x3.5 or something). Also, clean silver is "byproduct" when using silver inquartation, so to disolve it separately is another amount of nitric. If clean gold is priority, copper definitely has advantages. If economy of process is priority, silver is way to go... That is my take from todays video. Thanks...
@sreetips Жыл бұрын
Agree
@pdubhnic Жыл бұрын
Your work is incredible Sir!
@sreetips Жыл бұрын
Thank you.
@stixgonzalez5303 Жыл бұрын
"THE AMERICAN DROPPER" Mr Streetips content just keeps upgrading and is more addictive than ever( if this is your practice)
@stevebrown82996 ай бұрын
Beautiful, thank you for sharing your work sir.
@thebarryman9 ай бұрын
Looked very clean after the first refining pass. Probably was 3 9s already
@sreetips9 ай бұрын
That’s a testament to how good inquarting with silver and parting with nitric is at cleaning the gold.
@davidresar8256 Жыл бұрын
Very good video! Changing over to copper inquartation or just trying? It looks like your gold refining waste beaker is accumulating some gold pour off. How long do you wait before refining the gold refining waste? Keep up the great content!
@sreetips Жыл бұрын
Just a demo. I refine silver. I usually wait about six months to recover gold from the waste container.
@deepovertone Жыл бұрын
Sreetips, for some visual variety, I’d like to see the precipitaion done in “reverse" if thats possible. Create a dilute SMB solution and add concentrated gold solution to dilute SMB. Would be neat to see done a few drops at a time from a pipette or dropper. Maybe do a small scale test to see if its vaible first. Thanks!
@sreetips Жыл бұрын
Excellent suggestion. Thank you.
@mikeconnery4652 Жыл бұрын
That would be interesting. Nice idea
@JustKeepLivingFPV Жыл бұрын
Gold in solution never gets old
@jaygremillion3501 Жыл бұрын
Its nice to see how you have learned and grown with this.
@mikeconnery4652 Жыл бұрын
We have learned
@HellHoundOne Жыл бұрын
Good sir. Where is the video of the refinements of the jewelers gold, the one that was cracking due to lead. I believe it was a sheet that he was trying to roll out. I can’t find it. Thank you! ❤
@sreetips Жыл бұрын
I can’t remember
@HellHoundOne Жыл бұрын
@@sreetips Okay. Thank you good sir. I’ll keep looking. Thank you for all the videos and information you post up. By far, yours are the best! ❤️🔥
@bobross5580 Жыл бұрын
Great series! Thank you.
@skibidi.G10 ай бұрын
Boy, wet gold powder sure is stubborn, took much longer than usual to get that melted.
@sidneyriggs9764 Жыл бұрын
One of my favorite channels.
@whatthefunction9140 Жыл бұрын
Oh yeah. Kids go play, daddy is watching his sreetips
@TBBWDontPlayNoReindeerGames Жыл бұрын
@Sreetips It’s what I always use, only pure copper wire bare bright! The sterling silver I use up with making plain wedding bands and cuffs and jump rings! The down side is it eats up more HNO3! TBBW🐺
@ja-canadian5451 Жыл бұрын
In a previous video a year or two ago, I think I recall Sreetips saying it takes a lot more Nitric Acid to dissolve copper than the same volume of Silver. But in this video it was 6 doses the same as usual. Was the volume of Acid per dose higher?
@apveening Жыл бұрын
It was six boils, about the usual (I've seen seven a couple of times), the amount of nitric in each boil was about double.
@sreetips Жыл бұрын
For this amount of gold 5 nitric boils would have done it using silver, maybe four.
@SeriouslySickSerpents Жыл бұрын
I absolutely love your videos!! Will you be using copper from now on since it gives you such good results? Or, was this just something to switch things up this time? Either way, your videos are fascinating to me. Thank you for doing them.
@sreetips Жыл бұрын
I refine silver. The first step is to dissolve it n nitric. So I’ll be using silver to inquart. This was just a demo to show that copper can be used.
@piotr86 Жыл бұрын
Now I wonder if using pure silver crystals will produce equally pure gold. Maybe these impurities come from the sterling silver and not from the silver itself?
@sreetips Жыл бұрын
Pure silver is colorless, like water. I’d lose the blue color indicator. Plus, pure silver crystal has already been through the silver cell. Be like taking a step in the wrong direction.
@lylestavast7652 Жыл бұрын
Nice ~ good to see different processes to get to the final inglette.
@finkster7983 Жыл бұрын
Did this seem like it took forever to melt or is it just me ?
@sreetips Жыл бұрын
I slowed the melt sequence in this video.
@davidlewis90687 ай бұрын
Your orange tang and orange smoke are amazing.
@EpsilonHunters Жыл бұрын
So cool to see different methods, the last one was awesome too! Let's hope Streetips will decide to show us inquartation with other metals in the future, witch one can make the job and witch one can't...I presume there is something about the difference of fusion point...Loved this 6K rose gold!
@Ydnar1155 Жыл бұрын
In brewing and winemaking, we also use SMB. We use it to kill wild yeast a couple days prior to pitching the yeast of choice.
@sreetips Жыл бұрын
Yes, SMB can be purchased in bulk from beer and wine making suppliers.
@saeed_tavakoli Жыл бұрын
27:37 Thanks SREETIPS! This was a new experience, and I loved it. The finish with this method was something else in the video; also, you mentioned it. A question comes to my mind: why always pour into graphite mold? Could you explain what's benefit to that? I mean, if the mold can hold the temperature after pouring, further or directly, you can melt gold and shake the mold to have a perfect bar, isn't it?
@sreetips Жыл бұрын
That’s the way I learned it. I’ve always done it with graphite molds. I get excellent results.
@Ellis157 Жыл бұрын
is that some old indurated gold on the floor behind the melt table looks like old shot
@sreetips Жыл бұрын
Probably
@JoeyDadawg Жыл бұрын
Funny question. If some how you dropped the beaker with the gold in insulation on the floor. Would you take the stump out and sprinkle it on the floor to recover it?
@sreetips Жыл бұрын
Possibly, but I hope that day never comes.
@richardbeee Жыл бұрын
Copper has always been an excellent collector of precious metals. Easy to refine out also. That's how it's done in all the great copper smelters. Although in their large quantities they use electricity. Parting the precious as an end result.
@Hossak Жыл бұрын
Yup - that is why you get over 98% payment for the gold content of your copper concentrate.
@PetraKann Жыл бұрын
@@Hossak Not surprising - Gold is worth about 7,500 times more than copper. It means that you can have a copper sample that is 99.987% pure copper and the rest being gold and the value for each of these two metals will be the same. You should look into the price of Plutonium: over $4 million per kilogram which is about 65 times more expensive than gold (on a weight basis)
@Hossak Жыл бұрын
Sorry I work in the mining industry and was just pointing out that when you sell your copper concentrate (5000 tonnes at a time) to a smelter, they generally pay over 98% for the gold content. I am sorry for the confusion.@@PetraKann
@jamisontaylor878 Жыл бұрын
Excellent video thank you 😊
@Heymrk Жыл бұрын
Wow, been wondering when you'd try this. I saw Nile Red do this a few years back. So interesting to see how the process is different.
@bentationfunkiloglio Жыл бұрын
Cool. Love how you change things up.
@mikeconnery4652 Жыл бұрын
Great video it was brighter even as a melt. Awesome
@newtronix Жыл бұрын
Nice one! Is this the way forward?
@Richmart1955 Жыл бұрын
Is there a time limit that gold can be held in aqua Regia before it must be precipitated out? ❤ Always interesting.
@sreetips Жыл бұрын
None that I know of. It can be stored in solution or even evaporated to crystals of gold chloride and stored indefinitely.
@looweeg4229 Жыл бұрын
I wonder why at 6:15, the gold starts to go in solution without nitric. it was rinced with distilled water so I'm not sure what happened there.
@sreetips Жыл бұрын
Residual nitric in the gold
@EthanMcPhoenix Жыл бұрын
Hey Kevin, but if you inquart with copper, you miss the chance to get rid of all the sterling silver who as a higher value once refined in crystals no ?
@En-Pea-Sea Жыл бұрын
He has silver coming out of his ears, and has said so in a few videos.
@alanpecherer5705 Жыл бұрын
The sterling will find another path into the silver cell. I don't think this is an issue. You could say that inquarting with copper doesn't give the used nitric a chance to do double duty after it dissolves the base metals in the 6K gold, but I don't think that's a big issue. If you wanted to say that this method uses a bit more nitric, I think that's correct.
@sreetips Жыл бұрын
Correct. I’m still using silver to inquart. This was a demo
@pazsion Жыл бұрын
I wonder when your going to do X-ray analysis to verify gold vs various methods. Would be interesting I think to see how much of what is left in the final product
@VendettaProspecting Жыл бұрын
"Copper Inquarter" is going to like this one lol
@NOFX0890 Жыл бұрын
Uh huh.
@sreetips Жыл бұрын
He made a comment.
@TheJeracuda Жыл бұрын
I like how after all the gold settles to the bottom after adding the stump out the water becomes so clear
@82gamerprincess31 Жыл бұрын
I like this process because you can save your silver to process separately with less steps getting you the 2 best metals, clean gold and silver, using up a very easy to find one in copper.
@sreetips Жыл бұрын
The first step with silver is to dissolve it in nitric. So that’s why I use silver to inquart. Refining both metals at the same time.
@TanteLaurana Жыл бұрын
hey sreetips! when i read the thumbnail of the video, i immediately went and read the wikipedia page for copper chloride. sure enough, it is soluble in hydrochloric acid, as i suspected. you taught me some chemistry :D
@sreetips Жыл бұрын
Excellent!
@sjs260563 Жыл бұрын
I don't know how much time it takes for the ice to cool down the solution or even if it's important, but I think crushing the ice would make it quicker or use chilled water instead
@chemistryofquestionablequa6252 Жыл бұрын
Nice, I love copper chemistry it has all the best colors without too much toxicity!
@s.unsworth2929 Жыл бұрын
I noticed you haven’t been showing your silver cell lately. I was wondering why?
@sreetips Жыл бұрын
I ran out of feed stock shot. The cement silver is backing up on me something terrible. I need to get my furnace fire up and melt some impure silver shot.
@10000276249 Жыл бұрын
Why are you not doing in purification dilute ammonia boils after rinsing smb with water and HCL boil, gets it cleaner.
@apveening Жыл бұрын
In the comments section of another video he told me he thought ammonia too corrosive and aggressive so he won't use it. He is right about that for the hot gas (ammoniak), but I've used ammonia (4N) at room temperature without problems. A fume hood is recommended when using larger amounts, be he already has that.
@sreetips Жыл бұрын
Because it’s not necessary.
@julianalcorso5703 Жыл бұрын
Good job. Copper is good when you dont have any silver to process. Good clean copper helps too.
@MrMsabyan Жыл бұрын
Have you ever heard of ORMUS? Or white powdered gold from egyption times? I,m doing research into this topic and i am sure a part of the process is when the gold is in sponge for since its non metallic,any thought on this sir?
@sreetips Жыл бұрын
I’ve looked into it. Everything I’ve found calls it pseudoscience.
@MrMsabyan Жыл бұрын
@@sreetips Have you watched David Hutchinson videos by chance ? His chemistry used when he found traces of it may interest you. He was leach mining / soil conditioning if I remember ?
@sreetips Жыл бұрын
I can’t even find out what it is. If it’s a compound of gold, then what are its constituents? You know, like chloroauric acid (gold dissolved in acid) is: H(AuCl4) according to Wikipedia. But nowhere to be found is the chemical formula compound known as “ORMUS”. It doesn’t exist.
@MrMsabyan Жыл бұрын
@@sreetips ORMUS is a acromion . It is basically when you get a metal down to the point where it loses its magnetic properties and and gains new properties . kinda like graphene in 1 nanometer size compared to carbon from the pencil
@sreetips Жыл бұрын
I see. I don’t know how it’s done or if it can be done. I’ve seen the video of a guy in a tunic making it. But it doesn’t give any specifics. A lot like refining videos used to be when I first started watching KZbin 15 years ago.
@jackdunagan331 Жыл бұрын
Off topic, but I've been going through your old videos trying to get a handle on shop setup requirements. Do you have a video on your glassware? Looking for minimum requirements, a nice setup and possibly the dream collection. Keep up the good work!
@sreetips Жыл бұрын
Fume hood first. No way to safely do these reactions without one.
@jackdunagan331 Жыл бұрын
@@sreetips Most definitely a fume hood! Wouldn't even consider it otherwise. I'm trying to get a handle on price of entry into the hobby. Specifically I was interested in the glassware, since you seem to have a lot of various types and sizes of beakers, flasks, funnels, etc. I assume it's like most hobbies, the deeper you get the more you accumulate, but what do you consider the bare minimum needed to get started? Also are you picking them up at yard sales, Amazon or at the Lab Supply?
@sreetips Жыл бұрын
I buy my glassware on eBay. I had a chemistry lab in my basement when I was in 7th grade. This is more or less a carry-over into my adult life. I just bought the glassware as I needed it. You should be able to watch the videos and take notes. That’s what I did. But back then, there were no videos like mine to refer to.
@jackdunagan331 Жыл бұрын
@@sreetips I definitely appreciate the videos. I'll start taking notes. Thanks.
@shawnsmith9512 Жыл бұрын
The problem with copper is how much more nitric acid it takes to get it into solution. It also has a tendency to take some gold into solution with it. Silver can also do the same trick although not nearly so much.
@anthonyrstrawbridge Жыл бұрын
Alumina Can Copper is a nice shiny gold coveted by naval architects. 🤔
@woonsockettruthseeker9009 Жыл бұрын
Rhode Island police officer. Anther great finish to my awful night shift
@sreetips Жыл бұрын
I’ll bet it’s refreshing when you get to be helpful and take a break from the dark side of humanity. I support the police. Where would we be without you!
@woonsockettruthseeker9009 Жыл бұрын
@@sreetips I was a fire fighter from 18 to 25. Now I've been a law enforcement officer for 13 years. Always wanted to help people. There are still good people out here. Thanks for supporting my brothers and sisters
@dennisflemming826 Жыл бұрын
Wow thanks for that , very impressive. I noticed you had a slightly carbonised softer flame on your oxy torch , on other occasions you have had an oxidised hard flame with quite a lot of smoke ! You may be losing some of your yield to burning? Just a throat , cheers
@G-LoTheHero Жыл бұрын
Hey Mr. Sree! Next time you get bored, could you do me a HUGE favor? 😅 If you could go through your videos and create playlists, that would be epicly helpful! A playlist for your gold filled, karat, e-waste, silver cell, and maybe a playlist for your fails for fun?, etc… OH! And a playlist of you equipment! Your fume hood is something i would like to have a better look at. I think you have videos on that already, but I’ve been struggling to find it! Scrolling through all your videos can get tiresome! Thanks in advance, and a BIG thanks for the plethora of content you’ve posted. You have taught me so much, that words can’t describe my gratitude.
@chasemuehlbauer14 Жыл бұрын
Sreetips, is that precious metals splattered all around your melt dish area? You should do a clean up/ recovery video of that area.
@NorthDownReader Жыл бұрын
"You should do a clean up/ recovery video of that area." I think I remember that the sweeps go in the paper store for processing with that.
@billasegan3261 Жыл бұрын
Looks like its a lot cleaner but it seems like it took longer to melt down..👍🏻👍🏻
@sreetips Жыл бұрын
I slowed the video down on this one.
@Rob337_aka_CancelProof Жыл бұрын
20:09 So is there a reason why you cool it with ice before precipitating and then back on the heat afterwards rather than precipitating with a hot solution and saving a step?
@mike20sm Жыл бұрын
The paper filter has been known to fail with hot liquids, if I remember correctly.
@Rob337_aka_CancelProof Жыл бұрын
@@mike20sm thanks you're probably right for some reason I was thinking that was just with sulfuric but I guess that doesn't even need to be hot to degrade carbon-based materials or it wouldn't work so well on toilet paper and poo
@sreetips Жыл бұрын
Cool solution closes the pores in the filter paper and filters out solids more efficiently. Plus any silver chloride in solution will come out of solution’s in as it cools allowing it to be filtered out.
@wickedwidget3812 Жыл бұрын
Do you weigh out the 6K gold after inquiring the silver or in this case the copper?
@sreetips Жыл бұрын
No
@Lexst1 Жыл бұрын
So, I have an odd situation. I dumped about 5 pounds of trimmed fingers into a bucket of filtered HCL about 5 months ago. (I got busy) Today I opened it up and started taking out the fingers expecting a good number of foils. However, other than a few small pieces sticking to a finger here and there, there were no foils at all! It has been hot this summer (Florida) but I was under the impression that HCL did not affect gold in any way. What am I missing???? There may have been a little peroxide. But if there was it was not much.
@sreetips Жыл бұрын
Test with stannous
@walkthroughguru Жыл бұрын
I do mine in my stock pot with copper and just collect the residue later after the base metals have been removed. But i am not in a rush.
@hotrod47944 Жыл бұрын
I’m curious why you don’t use a rosebud heating tip with your oxy-acetylene torch instead of a cutting tip? It would heat much more quickly and much more thoroughly.
@sreetips Жыл бұрын
Didn’t think of it.
@uwillnevahno6837 Жыл бұрын
I see you got up to 6 acid boils. It finally clicked in my head to ask. Have you ever tried or considered the need for spectroscopy techniques to determine the amounts of copper or silver in solution as part of the acid boils? I remember these benchtop models from 1st yr General Chemistry that are probably a few hundred dollars.
@sreetips Жыл бұрын
It could be done. A few drops of ammonia is a very sensitive test for copper.
@ThorTubeview Жыл бұрын
Hi, Mister Sreetips. How did you cleaned up your melt dishes ? Thank you.
@sreetips Жыл бұрын
With flux and flame
@ThorTubeview Жыл бұрын
@@sreetipsThank you for your quick answer. Have a nice day.
@gnomespace10 ай бұрын
Ok, here's one for ya. What about making certain golds to spec? Black Hills gold 2nd and 3rd colors are 14k with copper for the 'red' gold and 14k with silver for the 'green' gold. True "Black Hills Gold' supposedly as to be mined from there to be certified as such, but the chemistry is still intersting!
@sreetips10 ай бұрын
I’m refiner of gold. Creating those alloys is like asking a surgeon to implant a tumor, rather than remove one.
@gnomespace10 ай бұрын
@@sreetips Or perhaps like a surgeon implanting an artificial joint? Not the same, but has other value than just financial. Gods forbid I should say 'art' because I totally don't get art, but ...
@mrimmortal1579 Жыл бұрын
Could this be something you could use your waste copper (the stuff you cement out on the iron prior to waste disposal) for?
@chemistryofquestionablequa6252 Жыл бұрын
Absolutely
@NorthDownReader Жыл бұрын
"Could this be something you could use your waste copper (the stuff you cement out on the iron prior to waste disposal) for?" Very, very dirty - tin and lead bringing extra problems to refining.
@chemistryofquestionablequa6252 Жыл бұрын
@@NorthDownReader where exactly are the tin and lead coming from if it's copper nitrate reacting with iron? I'd expect you'd filter the copper nitrate before adding yo the waste bucket and the lead has already been dropped out of solution as the sulfate and filtered previously.
@NorthDownReader Жыл бұрын
@@chemistryofquestionablequa6252 There's plenty of contamination being introduced into the system from Sterling silver, dirty copper and dirty iron.That's even if you are sure that anything in the carat gold and floor sweeps was precipitated by the sulphuric acid and caught in the filter papers (Then the filter papers get processed anyway) The stock pot and waste bucket aren't just precipitated from nitrates, they are cemented out in an electrochemical reaction. Anything more reactive than copper stays in solution in the stock pot and ends up in the waste bucket. Anything less reactive than iron cements out in the waste bucket along with the copper. I never saw any sign that there was any filtering of the bulk of the liquids going from the stock pot to the waste bucket, only the precious dregs were filtered for the stock pot recoveries.
@sreetips Жыл бұрын
No, that’s heavily contaminated.
@myzanaplays Жыл бұрын
The stump out is my fav part!
@terryray4646 Жыл бұрын
Would you do a video on the math and how you get the numbers and where they come from?
@sreetips Жыл бұрын
I already posted one on the math within the last three months.
@sreetips Жыл бұрын
How I Derive The Constants for Inquarting plus watch sale kzbin.info/www/bejne/fmLLoa1-i9qheaM
@williamfoote2888 Жыл бұрын
It seemed to take an awful long time to get the Au to melt. Was there something different with the heating equipment?
@sreetips Жыл бұрын
Yes, i usually speed up the footage to save time. I ran the melt sequence at normal speed for this video.
@petterandersson7429 Жыл бұрын
The deeper water container seems to be an improvement.
@sreetips Жыл бұрын
Agree
@UncalBertExcretes Жыл бұрын
Dang you got a serious blow torch to be able to melt copper without a furnace! Just out of interest what is your torch setup?
@sreetips Жыл бұрын
Oxy/acetylene.
@josephsichting8162 Жыл бұрын
If you added the dissolved copper solution to your dissolved silver waste solution, would that make the silver cement out faster than solid copper?
@sreetips Жыл бұрын
No
@DEmma1972 Жыл бұрын
every stage looked cripser than usual. I did write a few days ago about using copper, is this video a reply to that or was it already planned? Regardless it was great and thank you for showing the video. I assume you use silver to inquart because you can reclaim the silver so less wastage?
@sreetips Жыл бұрын
Yes, correct
@Phoenix_Enterprises Жыл бұрын
Haha, beautiful pour brother. Nice flame polish.
@antonschulte9150 Жыл бұрын
Thank you for yet another very educational video, I always enjoy them! One question: how do you deal with your used crucibles, especially the ones wich are too dirty or damaged to use anymore? Do you cook them in sulfuric acid to dissolve all the borax and collect the small beads of metal wich were stuck to the crucible / trapped in the borax accumulations? Or do your save them to crush them up some time in the future?
@sreetips Жыл бұрын
I save them in a big container. I have yet to figure out how to process them.
@williamfoote2888 Жыл бұрын
@@sreetipsGet a ball mill and crush them to a powder. Leach with excess HNO3 and HCl. Heating would help, but letting it soak for days/weeks, and topping the container off with fresh acid will be necessary. Filter off the solids, rinse the powder/sludge with a couple aliquots of fresh acid. Process the acid solution like you normally would. I don’t know where you’d get a ball mill from for a one time use. Maybe this is your chance to do a collab with the fellow at mmblc? He’s got one. You and Mrs S take a cross country trip, get him to smash your dishes to powder, and you show him how to do the Hoke procedure correctly. Win win. Nifty content creation.
@sreetips Жыл бұрын
I think they will disintegrate in water.
@williamfoote2888 Жыл бұрын
@@sreetips No more than your food dishes might. Hi temp ceramics are intentionally tough. You face the same problem that mmblc does: small amounts of valuable metal mixed in with lots of Si/Al oxides. He thinks he can simply crush them and float the Au out, like placer ores, but the amount retained on the alumina/silica grains is where the biggest volume remains. In his case, he has a witches brew of chemical elements that’d require him to use a cyanide leach to extract the important metal value, you only have a couple elements to deal with. All are amenable to a good acid leach.
@sreetips Жыл бұрын
The melt dishes are fused silica, not ceramic. Ralph at aquillarefining says that hot water will cause them to crumble. But I’ve never tried it.
@brianevans1851 Жыл бұрын
It looks like the copper version makes it a little more resistant to melting but boy dam it looks good
@Lancelot.666 Жыл бұрын
The amount of cement silver would drop off. How much do you need to keep the cells running?
@sreetips Жыл бұрын
I have about a hundred pounds waiting to be melted into shot for the silver cell.
@Lancelot.666 Жыл бұрын
@@sreetips well there is no shortage there for awhile.. 👍
@front2760 Жыл бұрын
Glad i can fast forward.He stretches it out to the max.
@timsmith9645 Жыл бұрын
Very beautiful gold bar thanks for sharing sreetips