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Thermodynamics: Estimating the Two-Suffix Margules Parameter A from Experimental VLE Data

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Purdue OXE

Purdue OXE

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A walk through of an example problem on estimating the two-suffix Margules parameter A from experimental vapor liquid equilibrium data:
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.
Purdue University Omega Chi Epsilon
Text: Engineering and Chemical Thermodynamics, 2nd edition by Koretsky.
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Topics: Thermodynamic properties, thermodynamic relations, thermodynamic property relations, vapor liquid equilibrium, experimental data, ideal gas, real gas, hypothetical processes, enthalpy change, entropy change, internal energy change, clausius-clapeyron equation, fugacity, vapor fugacity, pure species fugacity, mixture fugacity, lewis fugacity rule, liquid fugacity, binary mixture, Thermodynamics, Chemical thermodynamics, exam, CHE 211, Purdue, Purdue University, Purdue Engineering, Thermodynamic properties, thermodynamic relations, thermodynamic property relations, vapor liquid equilibrium, experimental data, ideal gas, real gas, hypothetical processes, enthalpy change, entropy change, internal energy change, clausius-clapeyron equation, fugacity, vapor fugacity, pure species fugacity, mixture fugacity, lewis fugacity rule, liquid fugacity, binary mixture, Thermodynamics, Chemical thermodynamics, exam, CHE 211, Purdue, Purdue University, Purdue Engineering, Thermodynamic properties, thermodynamic relations, thermodynamic property relations, vapor liquid equilibrium, experimental data, ideal gas, real gas, hypothetical processes, enthalpy change, entropy change, internal energy change, clausius-clapeyron equation, fugacity, vapor fugacity, pure species fugacity, mixture fugacity, lewis fugacity rule, liquid fugacity, binary mixture, Thermodynamics, Chemical thermodynamics, exam, CHE 211, Purdue, Purdue University, Purdue Engineering
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.
Liquid-vapor equilibrium data have been collected for a binary system of benzene (1)- cyclohexane (2) at 60°C. Mole fraction of liquid and vapor vs. total pressure are reported in the table below. From these data, determine the value of the two-suffix Margules parameter, A.

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