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In this screencast, we go over a chemical engineering example of using Matlab's fsolve to solve for unknown composition, molar flow rates, and temperature in a system of non-linear equations associated with a condenser.
To achieve a higher selectivity of C with respect to D, you would like to have a smaller reactor. This is because over time, C will degrade into D (A + C goes to D), and in a larger reactor, the components spend a longer time in the reactor, allowing for more time for this degradation process to take place. A smaller reactor will have time to make C, but not as much time for that to change into D.