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Many microbes like bacteria and fungi live in the fur of a dog. These microbes excrete waste in the form of volatile organic compounds or VOCs. These VOCs are responsible for the stink.
Now usually, when the dog is dry, some VOCs evaporate into air. So, the stink or smell is hardly noticeable. However, when the dog plays in water or bathes, the water liberates most of the VOCs from its skin and fur into air, thus making the stink more noticeable. In addition to this, some VOCs even dissolve in water. As this water evaporates, it carries the VOCs with it, thus contributing to the stink.
Also, as the water evaporates, it increases the humidity in the air surrounding the dog. Humid air can hold more molecules. So, a higher concentration of VOCs reaches our nose, thus intensifying the stink.
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