Gibb's free energy doesn't change discontinuously in both 1st & 2nd order phase transitions. doesn't change discontinuously means changes continuously , what simply means graph is not broken anywhere.these change or doesn't change things are about the graphs of S,V,G with respect to temperature only (under phase change)
@itsme-xk9th5 жыл бұрын
Sir, could you please discuss about the two applications of TdS equation. (1) variation of intrinsic energy (2) joule kelvin coefficient... Please sir.
@palashnandi7787 Жыл бұрын
Hi Bidhan, your lectures are so beautifully presented that everything looks pretty clear in a very short duration. It's better than many professors delivering lectures in the universities. Sadly I couldn't find any recent video of your's in this channel. You must be busy in your career. But try to come up with new videos at least twice a month. Thanks and regards 😊🙏
@madhavdua124611 ай бұрын
Thankyou so much Sir 😇🙏 you made the concept crystal clear
@sakshishukla52556 жыл бұрын
I had learnt it in bsc 3rd year bt now i have forgotten bt your video make me remember... Thnk u sir
@tusharkumarraj60664 жыл бұрын
@Varun Tripathi mere yaha 1st year mai
@asf52752 жыл бұрын
Very easily and clearly covers a confusing topic....thanks a lot....superb explanation!!
@mohdsoheb24347 жыл бұрын
Nice video sir. ham logo ki itni madad karne ke liye bahut sukriya sir... thanks sir.
@bidhankhirali7 жыл бұрын
thanks soheb babu...
@vickyshankar48644 жыл бұрын
In 2nd order phase transition u said that neither heat absorb nor liberates. But when we heat the iron , by obsorbing the heat only it's temp increases...
@mishii05tmm3 ай бұрын
In 2nd order enthalpy and vilume change continuously
@suvashshrestha17315 жыл бұрын
I read the book BT I didn't understand and I searched and I found your video which made me clear thank you for this video 💞💞 💞
@shravanaa5 жыл бұрын
Where the graph is steeper and slope is positive or negative? How to draw the graph exactly after the distinct point of phase transition
@nivetha013456 жыл бұрын
Dont stop ur work. Upload more videos
@malavikas26394 жыл бұрын
I think there is an error in drawing the volume- time graph of 1 st order transition please check out
@suryaarmy11735 жыл бұрын
As per the first order phase transition that the Gibbs potential is constant. But you have represented in the graph it is changing with temperature. how??
@_tasneem7378 Жыл бұрын
Sir, you said in the second phase transition volume does not change, so why did you graph it like it is changing discontinuously!!!!!!!!!!
@brightsideofmaths7 жыл бұрын
Thanks for your videos!
@subhasissarkar13576 жыл бұрын
sir it will be helpful if you say something about why gibbs free energy does not change discontinuously.
@rohitsetty57416 жыл бұрын
Subhasis Sarkar Right
@riyashorts94763 жыл бұрын
Tnk u sir.. bahut acche se samjaya aapne🙏🏼❤️
@poonamnain5251 Жыл бұрын
Nicely explained
@suvashshrestha17315 жыл бұрын
You meant ferromagnetic changes into paramagnetic suddenly at that temperature, is it sudden action ??
@Learnergurl1233 жыл бұрын
Sir you said, both transition occur at constant temp and pressure....but graph are varying with temp....!! What is explanation for it ?
@pritamkumargiri5542 жыл бұрын
Graph are varying with time and temperature is constant
@suryalalgiri34525 жыл бұрын
What type of phase transition is ferroelectric to paraelectric and vice-versa?
@dkbswisdom90283 жыл бұрын
Great, 👏👏👏👏
@saurabhyadav-wh2mp4 жыл бұрын
Constant temperature nhi constant heat hota hai bhai
@sucharitapatra81856 жыл бұрын
sir u say phase transition happens under constant temp but if temp doesn't change then how will it be transformed from Fero to para.. i can't understand the matter of constant temp
@bidhankhirali6 жыл бұрын
Its all about latent heat.. if latent heat is required(to be absorbed or to be liberated)for phase change then its 1st order.. For example- when water is heated it doesnt change to steam as soon as it reaches 100 ° C.it waits there for a time and during this time heat comes(called latent heat) but temperature doesn't increase .& slowly all of water will change to steam .. So even if temp. reached 100°C but u need to wait to see complete phase change..bcoz phase change just is not finished at 100°c but it starts at 100°c..... On the other hand..a whole piece of ferromgnetic iron changes to paramagnetic iron as soon as it reaches temp. Of 1043 k . that means here we have instantaneous phase change & need not to wait at 1043 K for phase change to happen (since latent heat not required)
@lavanyakumarv62945 жыл бұрын
Gud video ...i liked ur teaching
@shoaib3493 жыл бұрын
thank you so much. it helped me🙂
@meghajoshi64426 жыл бұрын
Nicely explained 👌
@majedaljaber1347 жыл бұрын
beautiful work .. thanks a lot
@mayurakshigoswami80266 жыл бұрын
Sir what about 3rd order Transition and lambda phase transition
@vaishali6247 жыл бұрын
Very nice. Thank you.
@rainysalman52275 жыл бұрын
Nice explanation
@kamleshkumar-io2fb7 жыл бұрын
Very nice video sir very deeply lern its
@PoonamSingh-uv4cf6 жыл бұрын
Nice sir Suggest a good book for us
@jeetendhobi3565 жыл бұрын
sir appne second order ka derivative nahi batahya
@samirmondal77816 жыл бұрын
Then what thermodynamics property change discontinuity during 2nd order phase transition?
@neelamkashyap53964 жыл бұрын
Thanku sir
@deepachauhan93653 жыл бұрын
Thanku sir 😊
@sagarrawal83326 жыл бұрын
Somewhere I read that "The first order derivatives of Gibb's free energy change Discontinously in First order phase transition" but you said continously..can you please elaborate.
@bidhankhirali6 жыл бұрын
"yes that is it.you can see that entropy and volume are actually first order derivatives of G(gibbs free energy)and u can see that they change discontinuously in S vs T and V vs T graphs..".. but G itself doesnt change discontinuously even if it's first order derivatives do change discontinuously
@sagarrawal83326 жыл бұрын
ohh thank you for reply.....I totally understood now.
@kankaiahk71975 жыл бұрын
very fine sir, please upload a video of Crystal structures
@munishgarg40025 жыл бұрын
Bhaiya graph m entropy ki jgah book m G Gibbs free energy de rkha h
@venkatalakshmipeyyala73156 жыл бұрын
Thank you Sir, very good explanation. Sir please do some previous problems on this topic.
@alokparichha55536 жыл бұрын
Sir in both cases G changes discontinuously?
@priyamvadavishwakarma78086 жыл бұрын
thankyou sir ..it is very useful for me
@bookofspirit5 жыл бұрын
Thankyou
@harmeetsingh1756 жыл бұрын
V good explanation sir
@bhuvanam61057 жыл бұрын
tq so much sir...
@t2chetansingh2807 жыл бұрын
thanks very well explained sir
@harshrathore57947 жыл бұрын
sir plz suggest for csir physical science book
@bidhankhirali7 жыл бұрын
+harshvardhan rathore yes ; apka dec wala xam k bad bataunga...
@harshrathore57947 жыл бұрын
bidhan khirali ohk sir....thank u so much
@Taksheel_ethnic7 жыл бұрын
please suggest books for Thermodynamics & statistical mechanics..i find it difficult ,,bidhan sir
@bsstudy7606 жыл бұрын
NYC video sir
@hemrajpatel17427 жыл бұрын
nice concept
@sagarrawal83326 жыл бұрын
Thank you for such awesome explanation. Really helped me a lot....One question you said that at constant Temperature but when we heat substance the Temp changes and it doesn't remain constant ? In my understanding we are talking about lattice heat . can you please explain on this?
@bidhankhirali6 жыл бұрын
yes,, during phase chage T is constant and heat given to it doesnt change T so called latent heat
@ramsharma8437 жыл бұрын
sir 2nd order Phase trans maie gibbs energy change krti hai ya nhi?
@bidhankhirali7 жыл бұрын
+Aim Nthing nai karti...even first order k comparison m or jada smooth graph hoti hai...
@ramsharma8437 жыл бұрын
+bidhan khirali ok sir
@bidhankhirali7 жыл бұрын
Aim Nthing yes,,more smooth means here more linear...transition point k is par or uspar ka slope same or almost same hota h jabki G vs T ka graph m (in first order) dono chor ke point ka slope m difference hota h....
@ramsharma8437 жыл бұрын
+bidhan khirali ok sir.. gibbs energy or helmoltz energy ko kaise bta skte hai hmm simple words maie
@ramsharma8437 жыл бұрын
+bidhan khirali mujhe kisi teacher ne btaya tha helmoltz energy mechaincal work ho tb use krte hai aur gibbs energy jb chemical rection ho tb use krte hai... sir mujhe abhi tk yeh smaj nhi aaya ki agar hmm baat kre free enery... toh sirf free energy ka kya matlab hai ... mujhe ek teacher ne btaya ki aap kisi system pr restriction lga do.. restriction lgane ke baad jo energy exist kregi vhi free energy hai.. sir plz mera doubt clear kriye aap.