I had an intermittent p0420 caused by a leaking exhaust donut made worse by worn engine mounts (code would mainly occur going up steep hills or hard pulls on highway). I used the torque pro app and a elm325 adapter to read DTC and graph voltages of upstream and downstream sensors. Upstream sensor was switching normally, while the downstream sensor was reading lean. A new donut gasket and all new engine mounts (OEM) fixed it. Car is a 2006 Toyota Matrix with 227k miles.
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M - Thanks for taking the time to share your experience! This could certainly help future viewers.