As soon as I saw the expensive olive oil, I was screaming "NOOOOO!! The chlorophyll is fluorescent!!" More expensive virgin olive oils contain more chlorophyll. It is one of the ways you can check for olive oil quality.
@NathanaelNewton7 ай бұрын
LOL
@ExtractionsAndIre7 ай бұрын
Sometimes you really can see the Extractions&Ire train wreck coming
@superme637 ай бұрын
@@ExtractionsAndIre it"s kinda hard to miss a train wreck when it is a fluorescent train wreck. Also, isn't selenium sulfide the active ingredient in many brands of anti-dandruff shampoo? Your choice to not have that as your common substance for selenium extraction fills me with ire. 😏
@guytech73107 ай бұрын
Doesn't chlorophyll count as quantum dots or rather Carbon quantum dots (CQDs)
@NathanaelNewton7 ай бұрын
@@superme63 Oh that's a good suggestion, I wonder what the concentration is
@thethoughtemporium7 ай бұрын
Ah foiled by chlorophyll. Classic. There's a reason I wanted to make a laser out of chlorophyll. That red glow is so lovely
@Barty.Crowell6 ай бұрын
Please do! That'd be cool as hell
@christopherleubner66335 ай бұрын
It actually does lase, range is 680 to 740nm. Cam pump with either blue 470nm or red 660nm light both of which you can get from laser diodes. Disolve in ether and mix with propylene glycol and put in a dye jet fir continuously or flash pumped laser.
@cambridgemart20753 ай бұрын
@@christopherleubner6633 Another PL member?
@dalitas7 ай бұрын
Ah yes, the famous Wállët reduction method, works every time.
@joshmyer97 ай бұрын
It's fascinating just how many compounds can act as the catalyst in that reaction.
@tibr7 ай бұрын
It even works on leather!
@Duda2867 ай бұрын
@@joshmyer9 even a phone can act as a catalyst
@mattymerr7017 ай бұрын
According to the news, avocado is the primary catalyst
@SafetyLucas7 ай бұрын
@@joshmyer9 The Wállët catalyst must sublime. It seems like it's lighter every time I check it.
@gcewing6 ай бұрын
Quite annoying that olive oil manufacturers don't list their products' propensity for dissolving cadmium and selenium.
@droppedpasta7 ай бұрын
Extractions: 6/10 Ire: 10/10
@SamanthaLaurier7 ай бұрын
I have learned not to attempt to make a fluorescent compound with an even more fluorescent solvent
@ExtractionsAndIre7 ай бұрын
A valuable lesson that you’d think I would have learned already, but oh well, we know now I guess
@SamanthaLaurier7 ай бұрын
@@ExtractionsAndIre Well I'm no chemist, I sincerely had not considered that solvents could be fluorescent. I have the intelligence of a brick.
@hammerth14217 ай бұрын
@@SamanthaLaurier It's the chlorophyl from the bloody plant the oil comes from. Chlorophyl A fluoresces blood red under UV light.
@infectedrainbow7 ай бұрын
@@SamanthaLaurier Do you have the semen absorbance of a brick? If you aren't sure, I'd love to setup an experiment.
@crackedemerald49307 ай бұрын
the florescent solvent keeps the solute on it's toes
@Borsuk33447 ай бұрын
Olives are green and your neck is red. The important part is that neither is yellow.
@CAMSLAYER137 ай бұрын
As long as he doesn't mix them together...
@infectedrainbow7 ай бұрын
@@CAMSLAYER13 haha that would make poop
@kenny56767 ай бұрын
Olives are green and your neck is red. So much time wasted in the shed
@youkofoxy7 ай бұрын
He needs to get more protection.
@BlackPawn147 ай бұрын
(low-quality) olive oil is yellow, though.
@etelmo7 ай бұрын
"I wouldn't recommend this method, not that... why the fuck would you be doing this?"
@infectedrainbow7 ай бұрын
indeed.
@sphenodon20167 ай бұрын
Bro said this and I realized... why the fuck is *he* doing this? Most of his viewers, myself included, are prolly not actual trained chemists, so he could do any old reaction and I'd watch and enjoy regardless. God bless him deliberately choosing funky and difficult reactions for those of us who are smart enough to realize how funky/difficult the process is (not me)
@ricknijm7 ай бұрын
Cuz we love seeing people desolve into madness, isn't it more fun when it goes alll wrong?
@StonedtotheBones136 ай бұрын
@@sphenodon2016ADHD. Plus you get to a certain level of skill/time where i.e. I'll do projects once or twice a year and want new recipes but also new ingredients and methods of making/etc than before. Due to lack of time, but still wanting to do a new thing and learn smthn new.
@Tunkkis6 ай бұрын
@@sphenodon2016 A personal challenge, I suppose. Otherwise, why do anything besides eat, sleep, and shit?
@LanceThumping7 ай бұрын
Experiments like these are why we absolutely should have a sub-field in all the sciences for duplicating experiments, techniques, designs, etc. with bare minimum and maximum accessibility. Not only would that help with education and engaging people in the sciences but I bet there is some amazing discoveries to be had in simplifying techniques, possibly including bringing production costs down. For instance, The Thought Emporium using Gatorade as a replacement for extremely expensive cell culture media. Increased accessibility, increased simplicity, and decreased costs all at the same time.
@jayodea49707 ай бұрын
As far as I'm aware, that's the nuts and bolts of chemical engineering. A chemist produces a bench top process, a chemical engineer adapts the bench top process to scale and works out how to reduce reliance on highly specialised reagents. True chemical engineering, not necessarily process engineering
@LanceThumping7 ай бұрын
@@jayodea4970 That might be one part of it, but I want to emphasize that I meant this for all the sciences. It'd be nice to see papers on tabletop entanglement demonstrations or garage genetics experiments.
@ZeLunatic7 ай бұрын
Yes! That video was great too, the results were very surprising hahaha
@Broken_Yugo7 ай бұрын
This reminds me of something I've been working on, an indicator test solution. Called for KOH and 95% ethanol, neither available locally, booze tops out at 75% in my state. I dug around a bit and found multiple people getting good results with drain cleaner grade NaOH and drug store 91% isopropyl. Should save me like 20 bucks and a week at least. Of course if I put my mind to it and dug into the research I probably could have guessed the critical parts are just the hydroxide ion in some solution that will also pick up the chemical I'm looking for, but its a lot easier and more approachable if somebody else already wrote that out.
@MrTuneslol7 ай бұрын
Truly the scuff serves a purpose. 😅
@NatetheAceOfficial7 ай бұрын
I thought this channel would help me better understand my wife's chemistry work. Unfortunately, she's not Australian, so she's not quite on this level, yet.
@Isissa1257 ай бұрын
we're built different
@tadcastertory10877 ай бұрын
Does she not have a scruffy shed?
@Yostuba7 ай бұрын
tfw I will never find a trailerpark meth chemist, shes a keeper m8 you're lucky.
@amykathleen27 ай бұрын
@@YostubaI’m not a trailer park meth chemist but I’m as jittery as one, wanna get married?
@diggysoze28976 ай бұрын
@AmyKathleen2 we could make the most beautiful yellow chemistry, together.
@theslenderfox7 ай бұрын
If I were to make an uneducated guess I would say it would be because you got the olive oil from the store and not a chemical supplier
@tildessmoo7 ай бұрын
Eh, super-cheap olive oil would probably have worked, too. The biggest issue was probably the impurities (mostly chlorophyll) that make good-quality olive oil taste good but are definitely not fatty acids.
@Gwallacec27 ай бұрын
Super cheap olive oil is not actually olive oil it’s seed oil.
@tildessmoo7 ай бұрын
@@Gwallacec2 Olive oil is seed oil, just fyi. Well, seed-and-fruit oil, anyway. But I get your meaning, it's cut with cheaper oils, and... That's only kinda sorta true sometimes? (Or maybe it's moreso in Australia, idunno, my only experience is in the US.) If it's not pure olive oil, it can't say "pure" or "pressed" or "virgin" olive oil (not to be confused with "extra virgin," which is the expensive olive oil you do want for your kitchen but don't want for this experiment), and if it's not 50+% olive oil, it can't be labeled "olive oil," just "blended oil" or "oil blend" or "olive-flavored oil." Basically, if it says "100% olive oil," and it doesn't say "extra virgin," (first cold press) it's probably good; if it doesn't say "virgin" (second cold press) at all, probably better.
@Gwallacec27 ай бұрын
@@tildessmoo olive oil is not a seed oil it’s a vegetable oil. I’m from the USA and there are several documentaries and sources you can look at confirming it’s cut with other oils frequently.
@user-qw9yf6zs9t7 ай бұрын
Olive oil is actually just like, its own thing yk?
@wouldntyaliktono7 ай бұрын
I show my father (a retired physical chemist) your videos when I visit him, and he always spends the whole time flipping back and forth between uneasy laughter and hand-wringing anxiety.
@nickmcdonald30835 ай бұрын
As tom does visibly in most of his videos! A true chemist!
@leemadsen38217 ай бұрын
One problem is that nanoparticles are "sticky" and will aggregate and settle out (they are never really in solution, it's just that 5-100nm will remain colloidally suspended for a long time). The TOPO used in most of the common preparative methods serves to cap the particles to prevent aggregation. So, I suspect that any NP you may have made aggregated and were spun off with the rest of the gunge. Some literature demonstrated surface passivation with free fatty acids (oleic, stearic, etc.) so maybe it would be best to try this with oil (or lard, in the case of stearic acid) that you have first separated into free fatty acids and glycerol (via treatment with acid or base). You were getting there (conceptually) with the sulfuric acid, but probably didn't make much free acid...also, there was probably loss of CdSO4, which is likely insoluble in non-polar solvents. It's been a very long time since I ran this reaction, but I seem to recall using sodium selenite (e.g. selenious acid) as a nice source of selenium--that doesn't seem difficult to either acquire or prepare. Best of luck, this one was satisfying (I mean, using a UV-VIS to calculate particle size?! Brus...) to pull off.
@sophietaylor97536 ай бұрын
Following on from this, could you try doing progressive fractionation in the centrifuge, to settle out different density components of the scunge, and test them separately, like in cell fractionation?
@leemadsen38216 ай бұрын
@@sophietaylor9753 Good thinking because it works--and has been done to great effect, but seems like something that's out of reach for the typical home scientist...where shack-space is at a premium. For example, similar to cell component fractionation (in terms of size and geometry, some NP being quite a bit smaller,
@lucascsrs25816 ай бұрын
Would soap help somehow?
@pablodg3607 ай бұрын
hi, spanish here. Just to mention, usually, when a olive oil is more expensive, it's less pure than the cheapest one. That's because the "virgen extra" denomination means that all the olive oil was extracted only using mechanical methods, which are less efficient to extract the olive oil. But, extracting in that way it keeps some of the hues thats makes it more valuable in cuisine. The refined oil, the cheapest one, it's obtain by a combination of methods (mechanical and chemicals, mainly) that makes it more pure, but have a bland flavour.
@Flesh_Wizard6 ай бұрын
"full of spark plugs" I smell a precious metal extraction coming. I now have chemical burns in my lungs and 7 different cancers 😊
@Mattamue5 ай бұрын
ninja rocks
@jdmaine510847 ай бұрын
I can't overstate how much I love this channel. The juxtaposition of it all is perfect. You clearly know what you're talking about... but then also... all if your items on the chalkboard have smiley faces, and that fan is desperate to give you tetanus.
@humphreybumblecuck51517 ай бұрын
A vibe like “This old drying machine is broken so I just use it to store chemicals” Not that he’s done that exactly but similar. Jerry rigged, whatever’s on hand type of thing. It’s cozy and makes for a challenge, something about it is funny
@joshuaolander2017 ай бұрын
That poor old fan has been through a lot
@dwaynezilla6 ай бұрын
Carbon tet-anus
@ReaperUnreal7 ай бұрын
Neat, so you can deep-fry cadmium and selenium, and the crispy bits are quantum dots.
@SafetyLucas7 ай бұрын
Breaking News: KFC has just acquired Samsung
@DanBowkley7 ай бұрын
I wonder if lard would work better...
@Ezekiel_Allium7 ай бұрын
@@SafetyLucas bro you've made like 15 videos over like a decade why do you need the cool as hell logo?
@DuringDark6 ай бұрын
@@Ezekiel_Alliumif you made it in preparation for making more videos and then you stop making videos, would you not just keep it since it's cool as hell?
@Ezekiel_Allium6 ай бұрын
@@DuringDark no I absolutely would I'm just baffled by how good it is lol.
@108kitsune7 ай бұрын
Little known fact but cadmium is delicious
@ExtractionsAndIre7 ай бұрын
Cadmium and olive oil 👌👌👌👌just like your nonna used to make
@lonelystrategos7 ай бұрын
You sure you don't mean Cadbury's?
@Willrocs7 ай бұрын
@@lonelystrategosno one likes those god awful abominations
@relwaretep7 ай бұрын
@@ExtractionsAndIrenext time you're down that way there are a couple places in Carlton that do a real good cadmium and olive oil bruschetta
@julitonano117 ай бұрын
Cadmium cream eggs
@stringbean027 ай бұрын
As this was what my research project for the past two years was, the title is terrifying. Looking forward to seeing your backyard shed version of my laboratory labors!
@Silve177 ай бұрын
I've done some research on olive oil standards in Australia (riveting stuff) that may be of help. First off, the standard for extra virgin olive oil requires that there is no more than .8 grams of oleic acid per 100ml so the mono saturated fat line cant possibly be only oleic acid and can't help us, however you do still probably end up being correct that the fancy olive oil is worse for you because the cheap stuff was only olive oil, and that has a maximum oleic acid content of 1g per 100ml. Now the helpful part, there is a standard for "olive oil not fit for human consumption", and that specifically lists an oleic acid content higher than 3.3g per 100ml. I'm going to guess that the paper used that kind of oil, though if it came from Poland I have no idea what standards they set. If you really want to use store bought oil, "Ordinary Virgin Olive Oil" has an acid content of 2-3.3g per 100ml which is notably higher than the maximum content of US olive oil that is considered fit for human consumption at only 2g per 100ml. I would love to see this reaction work, olive oil chemistry is peak extractions and ire
@guystokesable7 ай бұрын
Stop telling me that he has peaked, I still believe he will make meth one day, I mean he has the guys glassware.
@It_Was_A_Quark5 ай бұрын
17:30 never in my life would I ever have heard the words "aw Yes I'm using a paperclip as a stirbar"
@dobbi60835 ай бұрын
We used them regular in university, not for reactions itself, but drop one in an oil bath helps a bit having a more even heated oil bath
@NathanaelNewton7 ай бұрын
I must be stupid because I've been watching this channel for years and only just now realized that... Extractions and Ire: things don't go well Explosions and Fire: things also don't go well but there's a happy ending.. maybe.. after 3-5 years
@humphreybumblecuck51517 ай бұрын
Extractions and Ire is supposed to be “procedure” and explosions and fire is “result” The lines though, oh how they blur.
@SethCrowderMusic7 ай бұрын
I thought it was because he does... Firework... Stuff on the other channel and chemistry nerd stuff on this one
@silverrey73797 ай бұрын
Can't wait for him to have a collab channel with LegalEagle called "Extortions and Wire"
@somegeese7 ай бұрын
Heck yeah, existential crisis chem man posted
@altonschultheis3037 ай бұрын
Love the mic peaking in the first second of the video, it really sets the shed chemistry mood, lmao
@johndeaux88157 ай бұрын
I can't imagine being the chemist who is tasked with producing lab grade olive oil.
@peper.r10057 ай бұрын
A mediterranean one probably, we use it as much as other people use butter
@Gwallacec27 ай бұрын
Cheap olive oil is not actually olive oil it’s seed oil.
@heresie7 ай бұрын
prolly called up an olive farm/olive oil factory to get samples the very first press out of a clean press, then purified it of the stuff that might interfere with any relevant reactions
@mfbfreak7 ай бұрын
And wine made from grapes with the seeds in it, is seed wine, not grape wine! Wake up, sheeple! /s
@mattymerr7017 ай бұрын
@@Gwallacec2 can you stop going into the comment section and saying shit you have no idea about? Thanks 👍
@S.ASmith6 ай бұрын
"because then it'll sublime and i'll be asking 'where's the cadmium'" It's..in my lungs!!!
@gadgehamilton31347 ай бұрын
Finally got to watch one of these immediately after drop instead of finding out weeks later when i check
@alexrogers7777 ай бұрын
As much as I miss the meme heavy editing I love that your humor is still present. The bit about "the science appreciating it when you commit to a bit" was hilarious
@DukeOfEarle887 ай бұрын
The fact that Australians call their currency "dollary-doos" has to be the most unhinged thing to come out of the 21st century.
@TheSunnyTrails7 ай бұрын
There was a genuine petition here in Australia a few years ago that several hundred thousand people signed to changed the physical Australian dollar to “The Aussie dollary doo” Just for shits and memes
@R4nd0mScience7 ай бұрын
The olive Oil turns solid because of the high heat and selenium the cis double bonds in the fatty acids all turn trans. This makes the packing of the molecules much easier, and that's why it freezes at same temperature after extended heating
@herrbrahms6 ай бұрын
So in case the cadmium waste wasn't bad enough, he also made those horrible *trans fats.*
@dajuwilson817 ай бұрын
“Where did the cadmium go?” The scariest line I’ve ever heard from a KZbin chemist.
@Flesh_Wizard6 ай бұрын
Sorry I was hungry 🥺
@chaosvolt7 ай бұрын
That solidified selenium olive oil goop is only halfway towards becoming some form of blursed homemade dandruff soap.
@brianbarrett24876 ай бұрын
Uncle Tom's Head and Shoulder Tonic!
@wtfftw707 ай бұрын
I work in a nano synth lab now. atmosphere, temperature, and moisture is really important. degass the olive oil first ( I have to degass the lab grade ODE, OLAc, OLAM...etc), get some sort of better temperature control and measurement (nanoparticles are highly sensitive to heating rates and maturation times), and lastly go back to using argon or N2. Oleic acid is a good surfactant and can help the seed mediated growth but you really dont need that much of it so dont worry about that. can use hexanes to wash the particles and the IPA to crash them out via centrifugation.
@Furtuim7 ай бұрын
One of my profs in university were doing quantum dots, and it's intrigued me since. Thanks for this!
@kumiredruid7 ай бұрын
I work for a university, and we do this experiment with our freshmen. We use pure oleic acid as the solvent. It was pretty cool, one of our teams got a full set of quantum dots this year. Violet, blue, green qdots are always so difficult to collect as they only exist for a short period of time after the reaction starts. Wish I could post the picture here, they're beautiful.
@kimtae8587 ай бұрын
Don't rub it in, man! Poor guy has it bad enough with a lab covered in burnt olive oil. (Hopefully he tries again with a cleaner solvent though)
@nickmcdonald30835 ай бұрын
He does have a discord, im sure they would welcome the pictures there.
@MattC6267 ай бұрын
Good to see you, Dr.
@mersilvaureus15257 ай бұрын
"Full of spark plugs" I honestly thought you were going to say it was full of spiders.
@nicholasneyhart3967 ай бұрын
I mean it is Australia, there are probably a dozen or more spiders in that box as well.
@Flesh_Wizard6 ай бұрын
Just saving some for later
@butterw556 ай бұрын
28:48 "A bit more patience, a bit more money spent on olive oil, TLC, maybe the chemistry will appreciate that." Narrator: It didn't.
@pauldrice19966 ай бұрын
Pro Tip: When trying to view fluorescence under UV light use yellow lenses to cut out the visible violet so it doesn't wash out the glow of the actual fluorescence.
@TheRedStig7 ай бұрын
Yes! My morning just got 100x better
@Chiberia7 ай бұрын
"Cheapest olive oil I can find" - during the year where olive oil prices are at record highs because of a bad harvest. Good timing, Tom!
@chrisb35857 ай бұрын
Just to confirm what you were saying concerning the oleic acid content, generally the 'higher quality' of the oil, the lower concentration of free fatty acids. For our analysis method we had to spike an oil sample with oleic acid for use as a QC as most off the shelf oils from retail sources lacked the FFA concentration to be used as a valid QC.
@virior7 ай бұрын
The only logical conclusion is that expensive olive oil is expensive because it already comes with quantum dots
@TheComicChild6 ай бұрын
SUPER COOL YOU FOUND A USE FOR THE CADMIUM ! I'll bet you figure out a way to recycle some massive chemical "waste" product in the future. The sparkplugs have iridium in them & I hear that iridium makes crucibles. I recall the annoyance you felt with magnet extractions though . Is it stupid to wire the sparkplugs into a sphere with a sparky centre like a fusion reactor? Do any chemicals require electrical arcs to form?
@TheComicChild6 ай бұрын
Strontium Aluminate seems neat with the whole " forbidden transition " energy state. Fluorenscence is ALMOST as neat as this cool aussie chemist on youtube.
@History_Coffee7 ай бұрын
The issue with cheap olive oil is it's often cut with if not almost entirely canola oil
@progamerr49997 ай бұрын
How can you even call it olive oil then?
@andrewlit22027 ай бұрын
Wonder how you can be sure it's pure... Maybe from a proper chemical supplier... Hmm....
@TheBaldingPied7 ай бұрын
@@progamerr4999 you lie
@ImCrimson7 ай бұрын
@@progamerr4999 Food fraud is rampant, and olive oil is among the most faked foodstuffs. Some estimates suggest up to 80% of the olive oils in stores do not actually live up to their claimed standard. Extreme droughts around the Mediterranean has caused supply to drop and prices to soar, which has attracted scam producers.
@hayuseen66837 ай бұрын
@@TheBaldingPiedYou're calling a question a lie which seems like you're replying to the wrong person
@give_anna_an_alt17446 ай бұрын
People have already said about the olive oil being a blend, but if you're wondering why it was turning solid at higher than normal temperatures, oils tend to congeal easier with heavier impurities, you generally see thid in old frying oil. Though because you were using heavier elements it was happening faster. Also based on that light yellow/cream color you may have been emulsifying the oil with any moisture in the air given how long at a time you were using the stir bar for. Not a chemist, speaking with my experience in culinary school and working in the food industry.
@gabrielsturdevant97007 ай бұрын
tom i just want you to know that everybody fully approves of your mustache
@jonathandomeraski72596 ай бұрын
I live off your uploads been around for 4 years and i remember you buying and making some of the ingredients used. I love you!!!
@actuallyasriel6 ай бұрын
"Potentially one of my biggest flaws is that I genuinely think that the science appreciates when you commit to a bit." I mean even if the science doesn't, I do!
@maudiusorelius17397 ай бұрын
I would love to see you make synthetic opal, its exactly half way between the last video and this one. All you need is water, ethanol, ammonia, and tetraethyl orthosilicate. It grows spheres just like the quantum dots, but the size is controlled by TEOS concentration.
@pacmanboss2567 ай бұрын
i have a 4 hour ride to the airport this is a solid 40 mins worth of it
@soundtrancecloud51017 ай бұрын
Are we 100% sure that is actual olive oil? "It's reliably reported that 80% of the Italian olive oil on the market is fraudulent." and that's Italy, Australia rate is probably near 96% lol
@ChrisWijtmans7 ай бұрын
yep get portogeese olive oil.
@nathanjeffs25097 ай бұрын
It’s usually still olive oil just not from Italy it’s cheap shit from North Africa
@alexphelps70427 ай бұрын
Only becasue EU is hyperprotective of region specific foods its not fradulent in the sense that its made of not olives, the distributers fail to disclose that it is imported or if it is made in EU they did not comply with all permits & regulation. A simlar thing is done to fancy cheese on the continent
@nathanp33667 ай бұрын
That doesn’t mean what you think it means
@nicholasneyhart3967 ай бұрын
Most of that fraud olive oil is real, it is just made in Morocco or Egypt most of the time.
@mina478797 ай бұрын
The science always works better when you change multiple variables at once. It makes it go faster
@butterw556 ай бұрын
14:15 This is the only channel I can get both selenium chemistry and "who fucking ripped ass in here?"
@corymiller33777 ай бұрын
Nile Red makes content for rich people in comparison to this program. E&I is out here repping the trailer park nerds messing around in the shed. Dont get me wrong i LOVE Nile Red. But the vibes here are TOP NOTCH mate! Thanks for explaining higher level chem in a down to earth way.
@mcanderson06 ай бұрын
techno selection was top notch. Most of the tracks we heard in this episode sounded like they were from Richie Hawtin's Minus label. Top grooves
@michaelchollet48687 ай бұрын
does melting test tube fall into the break glas category? at least it must count as a precursor....
@danchaplin29116 ай бұрын
years watching this channel, never seen this man once follow his own advice and not fuck everything up for no reason, so fucking awesome
@MalinCruceru7 ай бұрын
you planning to get the platinum and/iridium from them sparkplugs aren't you?
@Flesh_Wizard6 ай бұрын
I smell an extraction coming. My lungs are burning
@DaylightRobbery18245 ай бұрын
CdSe QDs were part of my graduate school research (before I ALSO gave up and went to another lab). The selenium precursor is an absolute bitch to make and we had the same issues with agglomeration. I wish I'd tried the ultrasonic bath method... Maybe that would've been more successful. Our solvent was plain old DI water. I could manage to make yellow QDs, but they were highly unstable and ultimately would ultimately lose luminescence over a few days.
@TheDemocrab7 ай бұрын
Oi mate I'm also in Australia and have 3 olive trees in the backyard that grow a shittonne of olives we never do anything with so if you ever wanna try this again but with an extra step of "Make yo own dang olive oil so you can also eliminate impurities" then feel free to chuck me a pm or something. or fuck, even if you just want some olives to go in the box with the spark plugs so that you can then one day pass on the Nokia box of sparkplugs and olives to a relative in the future.
@justinbrooks23516 ай бұрын
TiL that EVOO is a solvent. Was finally able to get the funk out of the French press I forgot coffee in and boiling water couldn’t clear. Thanks m8 for being a role model for kitchen cleanliness.
@dameygamey91677 ай бұрын
Just a tip, olive oil is yellow so be careful
@steadfasttherenowned24606 ай бұрын
It just dawned in me he was saying "source" not "sauce" i thought he was gonna make a selenium sauce with oliveoil for a second there.
@Zuel1226 ай бұрын
Ugh, I remember doing CdSe quantum dots in aqueous solution and how difficult it was to get one successful run and all the failures also glowed red. And here you are with so many more, new ways for things to go wrong compared to what we dealt with. The paper we were using left out some important info on reagent amounts which is what our problem was, but like you pointed out, you have so many things that could be causing failure.
@ChirpysTinkerings7 ай бұрын
I think it may be the paperclip causing the issue, maybe the iron from the paperclip, or the nickel reacting with the elements. (they're usually nickel coated so it prevents it from rusting over time) For my setup, I took some of the ptfe tubing and shoved an iron rod in it with the ends rounded over and then used a torch to heat the tubing while twisting it to close the ends off around the iron bar and melt it to seal it up and encapsulate the iron bar inside the teflon tubing.
@_Higgs7 ай бұрын
Doctor Physics is back like benzene!
@gfhrtshergheghegewgewgew17307 ай бұрын
remember carbon tet? it's BANNED
@gabrielscott2397 ай бұрын
I think the oil probably started polymerising at that temperature which is why it went solid
@UniverseUA6 ай бұрын
Excract iridium from the spark plugs
@billbillson31297 ай бұрын
Hearing "Australian dollarydoos" made me lol. Thanks for making and sharing with us!!!
@crimson5pheonix4 ай бұрын
Don't know if it's been said, but the type of oil you should probably be using is light oil (unless it's called something else in Australia). Virgin olive oils are pressed to maintain the olive flavor, but those flavors tend to decompose at relatively low temperatures. Light oil strips out a lot of what makes olive oil *olive* oil instead of just oil, and can survive at much higher temperatures, and just has fewer impurities in the first place.
@MySuperhappyfuntime7 ай бұрын
Platinum group metal recovery from spark plugs?
@internetuser89227 ай бұрын
Exactly what I was thinking.
@stasi02387 ай бұрын
Bro would do something to get negative yeld in that recovery.
@stasi02387 ай бұрын
Platinum would get out of his safe to lessen the yealds
@benjaminvisser39705 ай бұрын
I know absolutely nothing about chemistry or any of the things this man does but I have been binging his videos all day
@CNGboyevil7 ай бұрын
0:11 I like my women like I like my quantum dots
@rogergriffin98936 ай бұрын
Wow! What a privilege to have been allowed to follow your channel and your progression of learning over time. I've always loved your offbeat sense of humor, mate. And the way that you constantly push your boundaries. Safely, heh heh heh, always safely, of course!
@MrTylerStricker7 ай бұрын
Finally, a better way to absorb Cadmium into the blood stream!
@DUKE_of_RAMBLE7 ай бұрын
20:22 😭 As you can see, I'm very sad that you *didn't* say: _"She'll be right"_ DAMN YOU for enunciating your words and robbing me of this! 😅
@guytech73107 ай бұрын
Test the PH value of the Olive Oil, On a cooking oil acidic scale, virgin Olive Oil is 6.6. Canola is about 0.071. Bee wax is listed between 17 & 36. I suspect the acidic level contributes to the formation of CdSe. Another option, might be to bubble some hydrogen into the oil, but you might get quantum dot margarine! Not sure how you make Olive oil more acidic, maybe add oxalic acid. Another option to try is linseed, which I think more acidic than Olive Oil.
@ni_wink846 ай бұрын
I know zero, zip, nada, even nada 3 about chemistry, I know some elements and that’s about it, and that being said it’s a lot easier to follow your videos and understand them than a lot of other people on KZbin that do this, awesome videos !
@TheBooker667 ай бұрын
22:53 You mentioning your PhD is on fluorescence is funniest shit ever.
@TheDarkmaster21606 ай бұрын
2:15 Obi-Wan: "That's... why I'm here"
@SC-RGX77 ай бұрын
Australian man goes wild again and creates quantum dots that spawn Kangaroos from the 4th dimension.
@enderepsilon5 ай бұрын
"because why not" he said fucking around. Little did he know, he would soon find out.
@senorjp217 ай бұрын
There are suspicions that many olive oils are adulterated. So, getting a source with a paper trail is reasonable for research purposes
@FowlerAskew7 ай бұрын
I was working on a product once and ran across a paper detailing a non-invasive level sensing method for a container of liquid by measuring the resonance of the container. It was from a Spanish university and they were experimenting specifically to measure vats of olive oil
@eskilfloden31777 ай бұрын
Now do it with palm oil
@jongmassey7 ай бұрын
Are you aware of this recent technological innovation called a hat?
@RenderprismАй бұрын
Citing the exact supplier of your reagents is important for repeatability (which is necessary for academic science), but the clever scientist tests to see if they can do it better/cheaper
@jaimeortega49407 ай бұрын
Problem is most "olive oil" these days simply isn't. It's a blend of different oils.
@duxangus7 ай бұрын
Slop oil 😞
@guytech73107 ай бұрын
@@duxangus Oh No, not those "Stop Oil" Morons again! /sarc
@pedroff_17 ай бұрын
Many places have laws that force mixed oils to be disclosed as so. As for olive oil fraud, AFAIK, what happens is more kn the department of selling hot-press oil as cold-press and the likes
@dermeister87876 ай бұрын
17:10 My guess is hydrogen selenide formed during the dissolution saturated the olive oil fatty acids!
@aquaakya7 ай бұрын
Bisexual quantum dot lighting
@gbjsyzftbcacjyfubjygkgcjae31825 ай бұрын
background music for this video sounds like the bgm for a 30 minute flash platformer with primarily simple, dark, greyscale visuals that i would've played in 2017
@mahin3007 ай бұрын
FUCK I LOVE SCIENCE AND THE INTERNET YESSS
@nommy85997 ай бұрын
Why are you shouting?
@mahin3007 ай бұрын
@@nommy8599 EARS STILL RINGING FROM EXPLOSIONS & IRE
@homocapensis78547 ай бұрын
Saludos desde colombia sur america, un hincha al otro lado del mundo,muy valioso tu trabajo.
@MidFlyer7 ай бұрын
would be cool if you explained what quantum dots are, their potential usage, why they might be important and so on.
@christoffer65277 ай бұрын
4:42 I had a neck burn like that many years ago. I was shirtless so it was all over shoulders, upper back and neck. It was terrible 😂
@monaarch56087 ай бұрын
My Gen Chem lab the past 2 semesters has been making carbon quantum dots!! In the fall a lot of our lab groups are going to be working with the professor to publish our work!!!
@frankmunster64837 ай бұрын
Hi Tom, I haven’t seen that much Alkyne chemistry on KZbin and german Wikipedia says that propiolic acid forms an explosive silver salt. The synthesis seems alright so maybe you’d want to check out that molecule :D
@memejeff6 ай бұрын
Great video. Love to see science youtubers make new cocktails like quantum shots with cadmium.
@timothywaters82497 ай бұрын
I started listening to Aphex Twin again, thanks to you, Tom. Come here to learn, enjoy the music...