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When observing igneous rocks,
Intro
Biotite and hornblende are two of the most common dark coloured minerals typically found in igneous rocks. To distinguish between them, we observe them as thin sections under the petrographic microscope.
Hornblende
Under plane-polarised light, hornblende exhibits moderate relief, and cleavages at 60-120 degrees in basal sections. While it does have moderate to strong pleochroism, it is typically masked by it’s strong green to green-brown colour.
As we turn the stage, we can see oblique extinction occurring between 10-25 degrees, and note that basal sections will show symmetrical extinction.
The medium to high birefringence (with interference colours of the upper 1st and lower 2nd order) increase with increasing Fe-content, and depending on oxidisation. The strongly anomalous interference colours are often masked by the strong colour of the crystal.
As for twinning, the green hornblende has simple twinning, while the less common brown hornblende has lamellar twinning.
In hornblende, pleochroic halos may form around radioactive inclusions such as zircon intrusions. Biotite and hornblende may occur together in intermediate plutonic rocks, granites and high-grade rocks. Paragenesis can be used to explain why biotite crystalizes out earlier and this explains why it is sometimes rimmed by hornblende.
Biotite
Under the PPL, biotite displays typical mica habit, cleavage and birefringence but extreme pleochroism, which increases in intensity with increasing iron content, or may be weaker if Mg-rich. It has moderately high relief and platy crystals resemble prisms that show one set of well-developed cleavage traces. However, if the section is orthogonal to this, biotite will appear structureless and brown.
Like hornblende, the interference colours that would be seen under XPL are generally masked, though with only brown - not green. The richer in iron, the stronger the pleochroism tends to be. It has 3rd order birefringence which tends to be dulled by the natural brown colour. Extinciton occurs parallel to the single cleavage.
Unlike hornblende, biotite shows no twinning.
Conlusions
While it may be tedious to identify these minerals in hand specimens, the plane and cross polarisers of the petrographic microscope highlight the fundamental differences between them, allowing clear and confident sample assessments to be made in Earth Science laboratories.