Oxidative addition reaction in Organometallic chemistry|Reductive elimination Csirnet|GATE in hindi

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Mam, your lecture is very helpful. You up lode all previous year questions regarding organometallic compound in a single step. Thank you mam.

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38:30 does b & c can eleminate as they are cis at each other?

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Thank you ma'am. This video is really very helpful in understanding oxidative adddition and reductive elimination.❤❤❤❤❤

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Explanation is soo good mam

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Thank you so much for clearing the consept from basic ..

[@madhusmitakar2638]

Thank you mam ,this video is very helpful for me

[@Abhishekkumar-wu3bz]

Mam b-c aapas me cis nhi hain kya? Unko v to eliminate kia jaa skta tha As a-b and others ko kiye🙏 38:30 Pls reply mam🙏

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Yes you are right they can .... But they are not in the same plane

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good morning mam..I have one question..In your organometalics series how many lectures are made for iit jam?

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[@shinchandoremon5189]

Mam why polar molecule give trans addition not cis addition ?

[@vikasanand4610]

Mam why not addition reaction in d9 when it is in d8 and d10

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Mam reductive elimination me jo example batai hy usame b and c bhi eliminate ho skte hy

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Is d10 give oxidative addition reaction

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Di aap coordination kbse start kr rhe ho... gate tak ho jayega??

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Ma'am ye last video h organomettalic compound ki???

[@pjahamed]

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[@ashaam9496]

In example of reductive elimination, is it possible to eliminate b-c🤔🤔

[@djchemistrykajal]

Thnku mam Mam b and c bhi aapas mai cis honge ???

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Nice teaching mem...

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Ma'am ye IIT jam k liye hai kya oxidative and addition reaction

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Thanks a lot mam...🤗

[@B.Ed_B.Sc_M.Sc.Chemistry_SET]

Thank you very much mam 😊

[@gamingnitish143]

These reactions have nothing to do with stability criterion??? 16 e or 18 e rule?

[@mursalimkhan8753]

Mam, can you please explain... what is the reason behind electron donation power of alkyl group is more than aryl group in case of phosphine?

[@aman-kr]

+I

[@akashghosh526]

Most probably involvement of lp of P in conjugation with ph grps, lesser available to donate

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Main net clear kese kare experience share kijiye na please

[@4sacademy487]

Mam 38.53 min pr b and c cis ligands nhi hai kya??

[@AnjaliSharma-ym1rm]

Mam at 38:52, kya -COCH3 remove ni ho skta??

[@krish.bhashyam]

We are talking about reductive elimination, generally in RE,charged species(especially Sigma donar ligands such as CH3,H can participate, not pi acceptor).... now if we go conceptually, on RE oxidation state have to be decrease by 2 units right? In example metal has +4 charge,so on removing 2 CH3 it will go to +2....if we remove CH3 and co, charge will decrease to+3 since the co is neutral ligand... this is conceptually violates RE,so CH3 and co elimination not possible. Extra information : On the other hand in general pi acceptor ligands form strong bonds with metals as they involve in pi back bonding with metals,so elimination is not that easy, hope your doubt will clear.

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Well explained

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Organometallic Chemistry by BD Gupta

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Ma'am does different mechanisms like free radical, Sn2 or ionic in oxidative addition, change the nature of the products formed??

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Mam please tell about bridging ligand and how to calculate

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kya koi bta skta h ki jitna yha p krwaya h OMC ka kya utna sufficient h net k liye?

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In O.A. rxn, total electron count should remain same bcoz metal ki oxi. state increase kr jati hai?????

[@Zarlalaedits]

Nope.. The number of Electrons are increased by two units as the upcoming ligands bring that two electrons with itself. The upcoming ligands make two bonds with metal center which need 4 electrons but they have only two so metal atom provides them that 2 electrons and get oxidized. I hope you got it.

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Thanks di

[@9971708062]

alkoxide is better EDG so why methyl behaving as better than methoxy

[@sukanyasarkar6625]

How the electron is increasing after oxidative addition ? There is +2 charge on Pd. The electron count should be same .

[@Zarlalaedits]

Look at the who system dear, the upcoming ligands bring two electrons with itself and they are counted. There is the formation of two new bonds which need 4 electrons, two are provided by the metal (by getting oxidize to +2) and two by the upcoming ligands so the whole complex is increased by 2 electrons.

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Mam, Usually alkoxy groups show more electron donating powr than alkyl grop.ryt? . but here donation in phosphene, order is alkyl>aryl>alkoxy... how?

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electron donating capability of phosphines is based on electronegativity of the groups attached to P. more electronegative group attached = less donating ability of that phosphine

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