Making Uranium

  Рет қаралды 172,303

Chemiolis

Chemiolis

Күн бұрын

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All information and procedures in this video are public data that can be accessed by anyone. Video purely for education and entertainment. Depleted Uranium has no known cases of illnesses or deaths associated to work exposure.

Пікірлер: 376
@Raven99991
@Raven99991 4 ай бұрын
The uranium play button will be such a cool project
@NuclearFury8
@NuclearFury8 4 ай бұрын
Maybe an enriched one that goes supercritical when you smash it
@noimnotarobotcanubeleiveit7024
@noimnotarobotcanubeleiveit7024 4 ай бұрын
Then place it in a slow neutron beam and convert into fissible fuel?
@Raven99991
@Raven99991 4 ай бұрын
@@noimnotarobotcanubeleiveit7024 yes
@somerandomuser5155
@somerandomuser5155 4 ай бұрын
Not necessarily uranium, Just make fluorescent glow in the dark
@Raven99991
@Raven99991 4 ай бұрын
@somerandomuser5155 no it doesn't have to glow uranium doesn't glow on its own. And the flex of having a URANIUM play button is pretty cool because most people think that uranium is the most radioactive thing even tho it isnt
@somethingforsenro
@somethingforsenro 4 ай бұрын
reminder that uranium-238, the most common form of uranium by far, has an extremely low passive radiation level. if you ingest it, you'll be at least a factor of ten more likely to die of heavy metal poisoning than of radiation poisoning. (lead isn't the only poisonous heavy metal, it's just the most common to be exposed to. uranium has similar effects.)
@somethingforsenro
@somethingforsenro 4 ай бұрын
addendum: arsenic, mercury, and the cadmium from cigarette smoke are all also poisons for the same reason as lead and uranium are!
@chadkline4268
@chadkline4268 3 ай бұрын
​​@@somethingforsenroall elements except the lightest in each group are generally toxic to life because they have similar chemistries, but not exactly the same. U238 is about 96-97%, U235 is about 3-4%. Nobody has ever demonstrated any useful amount of nuclear energy, excepting tiny amounts of current in a wire. Heavy elements have complex chemistry because of all the electrons and forms of bonds.
@joaovicentefazziocosta4733
@joaovicentefazziocosta4733 3 ай бұрын
I would like to eat some uranium
@hukaman88
@hukaman88 4 ай бұрын
Here before the nuclear safety guy does a reaction to the vid
@jesusdlh
@jesusdlh 4 ай бұрын
He don't claim to know everything that is nuclear but he can certainly share some knowledge
@frogz
@frogz 4 ай бұрын
and yet he still wont check out kreosan, i've asked like 30 times!
@vagesector6161
@vagesector6161 4 ай бұрын
same here
@twitterforandriod1560
@twitterforandriod1560 4 ай бұрын
what's hid channel @?
@panosrobs9749
@panosrobs9749 4 ай бұрын
Same
@lallomes
@lallomes 4 ай бұрын
honestly the scariest part about this was that you used HF ☠
@Very_Grumpy_Cat
@Very_Grumpy_Cat 4 ай бұрын
True. HF is some nasty stuff
@aaronclair4489
@aaronclair4489 4 ай бұрын
"I add a random excess of 48% HF" "a random excess of HF" uhhh
@Very_Grumpy_Cat
@Very_Grumpy_Cat 4 ай бұрын
@@aaronclair4489 what ever. He did not die
@kylejacobs1247
@kylejacobs1247 4 ай бұрын
In a glass container no less
@tonyflamingo3285
@tonyflamingo3285 4 ай бұрын
You kidding? Do you know how toxic water soluable uranium is?
@swampmonkey420
@swampmonkey420 4 ай бұрын
Nuclear chem is the whole reason Im back at Uni at 45. Great Video DO MORE!!
@Chemiolis
@Chemiolis 4 ай бұрын
Unfortunately not too much stuff I can do, but there are still some fun uranium things to try.
@davonitos
@davonitos 4 ай бұрын
​@@Chemiolis make a bomb
@johanea
@johanea 4 ай бұрын
Lol, you will come out from uni with purple hair, pierced all over and gender fluid with the pronounce zer / ze. Plus vote Biden.
@ShikaTheDio
@ShikaTheDio 4 ай бұрын
@@Chemiolis can u make a mini nuclear 💣
@3AM_Ideas
@3AM_Ideas 4 ай бұрын
​@@Chemioliswhere did you buy this?
@MrApple-yw9vp
@MrApple-yw9vp 4 ай бұрын
I can finally add another video to my ''Blacklisted due to youtube' class action lawsuit
@petrolak
@petrolak 4 ай бұрын
Justice for Cody!
@Kenionatus
@Kenionatus 4 ай бұрын
Huh, there is/was a class action lawsuit around uranium videos?
@strapkins4999
@strapkins4999 4 ай бұрын
@@Kenionatusit’s a joke brother
@BackYardScience2000
@BackYardScience2000 4 ай бұрын
The Tetrafluoride is such a beautiful color. My sample of it looks so good sitting next to all the rest of the compounds in my collection. Great video! Thanks for sharing.
@captainchicky3744
@captainchicky3744 4 ай бұрын
does it discolor at all due to daughter nuclei forming or no
@Tunkkis
@Tunkkis 4 ай бұрын
​@@captainchicky3744 Over a _very_ long timeframe, sure. I can't imagine you'd be able to notice any change over a single lifetime.
@Arycke
@Arycke 4 ай бұрын
Hmm Uranium playbutton? Do ittt
@GregoryMcBride-qf7hx
@GregoryMcBride-qf7hx 4 ай бұрын
Don’t give him any ideas he still might want to have children someday 😂
@Hexane630
@Hexane630 4 ай бұрын
I’ll eat it.
@THYZOID
@THYZOID 4 ай бұрын
Uranium chemistry is so fancy! Great video bro
@swampmonkey420
@swampmonkey420 4 ай бұрын
Are you going to bake some thorium cakes with your cat ears for us?
@THYZOID
@THYZOID 4 ай бұрын
@@swampmonkey420 maybe UWU
@thesciencefurry
@thesciencefurry 4 ай бұрын
I just wish I could do a video about without the German government fucking me over :/
@puo2123
@puo2123 4 ай бұрын
Plutonium is better. More oxidation states
@GoldenEyes-rw6kp
@GoldenEyes-rw6kp 4 ай бұрын
​@@thesciencefurry I dont think that German government is interested by an amateur chemist isolating .20 grams of uranium metal just for the skill.
@mrgreenguy
@mrgreenguy 4 ай бұрын
I wish I could do this! But I don't think Australia would like that very much lol
@monika7063
@monika7063 4 ай бұрын
You made a nuke in your older video and austraila didn’t do anything, depleted uranium metal shouldn’t be a problem
@tomaszkarwik6357
@tomaszkarwik6357 4 ай бұрын
​@@monika7063that was not him. That was mark rober and kidnapped nirered. He was only trying to follow a tutorial
@monika7063
@monika7063 4 ай бұрын
@@tomaszkarwik6357 I refuse to believe that mr. green and nilered are two different people.
@tomaszkarwik6357
@tomaszkarwik6357 4 ай бұрын
@@monika7063 / unjoke, watch the video again. I was summarising it
@nilepink
@nilepink 4 ай бұрын
Dude, I can not emphasize how frustrated I am about this. I wanted to publish a video like this, but I had to stop it. Because they can fuck you over so fast here in Germany 😤 I HATE IT I HATE IT I HATE IT!!!
@ashW110
@ashW110 4 ай бұрын
For the moment I thought you are colliding two neutron stars or at least supernovae. But it makes more sens you just reducing a metal salt to metal. This is also interesting though. :D
@Chemiolis
@Chemiolis 4 ай бұрын
Next video I will be using a nearby neutron star for my synthesis
@Levent_Ergun
@Levent_Ergun 4 ай бұрын
I am not sure if I should watch the video or start downloading it immediately
@丫o
@丫o 4 ай бұрын
Why not both?
@hayliae
@hayliae 4 ай бұрын
Hello FBi. Yes, this guy. Take this guy!
@NatashaB2
@NatashaB2 4 ай бұрын
Love seeing this, I work with depleted uranium every day in my lab researching future nuclear fuels, so it’s super cool seeing the process to make the depleted uranium.
@davidfetter
@davidfetter 4 ай бұрын
Fertile uranium is a wonderful nuclear fuel in a fast reactor. I suspect you can make fuel with it in a CANDU or similar PHWR, but I'm guessing the codes to figure out where to place it and for how long might be a bit complicated.
@dalitas
@dalitas 4 ай бұрын
You make this nuclear chemist proud, love to see the uranium dissolve in organic solvents. solvent extraction is amazing.
@canadiangemstones7636
@canadiangemstones7636 4 ай бұрын
Nuclear chemist? Make vids!
@nayeem7359
@nayeem7359 4 ай бұрын
We need more inorganic chemistry videos 👏
@Atomic_Chemist
@Atomic_Chemist 4 ай бұрын
Specifically of uranium ;)
@joshp6061
@joshp6061 4 ай бұрын
Wow, nice result! I didn’t expect a very metallic looking product after you described your “heat it in the ampoule” method, but not bad
@Thunderf00t
@Thunderf00t 26 күн бұрын
molten lithium in glass is a hard NO! Liquid lithium is ferocious at destroying glass. It also mostly reacts with the glass to give lithium oxides and silicon.
@mernokimuvek
@mernokimuvek 4 ай бұрын
Nice priject. What would happen if you electrolyze a uranium or thorium salt solution?
@jordoncailifours4488
@jordoncailifours4488 4 ай бұрын
Great, we need more. Do thorium next.
@mikeydudek2885
@mikeydudek2885 4 ай бұрын
Saying depleted uranium isn’t so expensive is a bit misleading, depending on the application. Like with the above stated bullets made from depleted uranium. Those are crazy expensive and super hard to get. It could be more of a regulatory thing but I just know that you don’t see them everyday for a reason.
@LtKernelPanic
@LtKernelPanic 4 ай бұрын
Cool video. Sadly Cody's original video got him a visit from the feds.
@davidfetter
@davidfetter 4 ай бұрын
A video on what you did with all the waste from this would be awesome. Of particular interest would be what you did with what was left over from that "random excess of 48% HF." I have guesses at these things, but those are just guesses.
@Mobin92
@Mobin92 4 ай бұрын
Just pour it down the toilet. 👌
@scottanos9981
@scottanos9981 4 ай бұрын
​@@Mobin92Not my problem
@nerd1000ify
@nerd1000ify 4 ай бұрын
He neutralised it with potassium carbonate. End product will be potassium fluoride (KF) which is far less hazardous than HF. Small quantities could probably be disposed to sewer, so long as you can be sure there's no uranium still in there.
@dman5909
@dman5909 3 ай бұрын
You’re reaaaaaal close to 100k my man
@ZoonCrypticon
@ZoonCrypticon 4 ай бұрын
Depleted uranium, health issues and after-war diseases in the countries it has been used as armor-piercing mass projectiles in the documentary "Deadly Dust" (2007) from the German director and filmmaker Frieder Wagner.
@daniellassander
@daniellassander 4 ай бұрын
Yes Uranium is a heavy metal, where the health issues come from not the radiation. They say you shouldnt eat of a uranium glazed plate, that is also not because of radiation but due to uranium being a heavy metal and has a rather high toxicity.
@Tunkkis
@Tunkkis 4 ай бұрын
The thing is, the only meaningful alternative is a tungsten alloy, which also carries negative health effects.
@ZoonCrypticon
@ZoonCrypticon 4 ай бұрын
@@daniellassander The problem is not from eating eat, but from breathing it in. Thatfore deadly dust. Most of the anti-tank missiles produce a hot liquid metal jet, which oxidizes in the air , that is then spread via fine dust particles. All uranium isotopes are radioactive. If you breath it in , than multiple lung and blood injuries may occur. And the dust doesn´t vanish immediately after deployment.
@durshurrikun150
@durshurrikun150 4 ай бұрын
@@ZoonCrypticon Uranium is very weakly radioactive, it's its toxicity that is the danger
@ZoonCrypticon
@ZoonCrypticon 4 ай бұрын
A look at the uranium-based anti-tank ammunition the U.S. is sending to Ukraine Politics Sep 7, 2023 3:50 PM EDT (PBS News hour)
@oasntet
@oasntet 4 ай бұрын
I love all of the colors involved in the process. I wonder how each step fluoresces...
@buildingstories2470
@buildingstories2470 4 ай бұрын
Congrats you’re all on a list now
@CryptoFrenzyX
@CryptoFrenzyX 16 күн бұрын
Could you make enriched uranium pls?
@George_Soros.
@George_Soros. 3 ай бұрын
I’m learning
@ootman4687
@ootman4687 4 ай бұрын
A fuel cell play button or if we're really trying to get a friendly knock from your friendly fbi agent make a nuclear reactor play button.
@thesciencefurry
@thesciencefurry 4 ай бұрын
That's exactly what I wanted to make a video about aswell. But I don't because the police would probably come by and take all my equipment and chemicals :/ Idk how it is in the netherland or with your qualifications.
@Atomic_Chemist
@Atomic_Chemist 4 ай бұрын
So did heating the UF4 make a difference between unheated?
@CaptivaLP
@CaptivaLP 3 ай бұрын
I would love to see a video where you are making enriched uranium
@PrabhashwaraRavihara
@PrabhashwaraRavihara 3 ай бұрын
Please make a video about How to make Pure Radium, Even though It isn't cost effective! I'm so exited about it! please ! Please! Please!
@1.4142
@1.4142 4 ай бұрын
An enriching experience.
@ElectroXa
@ElectroXa 4 ай бұрын
would displace the chlorine work instead of converting UCl4 to UF4 ? for example, would UCl4 + 4 Na ---> U + 4 NaCl work or not ?
@spiderdude2099
@spiderdude2099 4 ай бұрын
I’m hopefully gonna land a job doing radiochemistry. Sounds like a lot of fun
@Moritz___
@Moritz___ 4 ай бұрын
Pls do a cleanup second channel type video. Feels relevant for that one Noice
@dominiktrzmielewski9164
@dominiktrzmielewski9164 3 ай бұрын
Why don't you simply use borax with na2co3 as reductive agent directly on UF4?
@mortlet5180
@mortlet5180 4 ай бұрын
Well done and congratulations on graduating to real (inorganic) chemistry! So what difference (if any) did the pre-drying step make, and could you measure the shiny piece's density for a crude indication of purity? TL;DR Metallic U really does react incredibly quickly with H2O and O2 *AND* N2 gases, such that attempting to cast or re-melt it without a continuous flow of Argon cover gas (or, at a minimum, vaccuum sealing with a very large excess of Li metal and covering the reaction mass in 2-3cm of liquid Li-Na-K-Cs with a suitable flux mixture on top), usually results in a fairly poor yield of multiple small corroded pieces of metal; though even in the best case, where a single metallic mass is obtained, it will be riddled with numerous defects, slag inclusions and poor porosity. Getting to a solid block of metal that at all resembles the common metallic element samples, is most easily done by cleaning, washing and drying the obtained U granules/shot under an inert atmosphere or under vacuum and then re-melting everything into one solid piece (only using inert and oxide free materials in contact with the U, such as Oxygen Free Copper or Tungsten).
@hrisigyuchanov3523
@hrisigyuchanov3523 3 ай бұрын
How did you end up buying from a Bulgarian pottery store ?
@nickpekor4450
@nickpekor4450 4 ай бұрын
I love uranium chemistry so much.
@RittifiHffjdidi
@RittifiHffjdidi 2 ай бұрын
Wouldn't electrolysis of Uranyl Nitrate solution also work?
@335mati
@335mati 4 ай бұрын
Photolytic chlorination of chloroform to carbon tetrachloride next please
@markiangooley
@markiangooley 4 ай бұрын
Depleted uranium is pretty much 238U, which has a longer half-life than the other isotopes! Better for a collection! (Though for most isotopes there’s little practical difference.)
@rocketlauncher6207
@rocketlauncher6207 4 ай бұрын
I think we can safely say that Chemiolis is the Nuclear Chemical KZbinr
@liamanderson6424
@liamanderson6424 3 ай бұрын
Doesn't HF degrade your glassware??
@robinalemon
@robinalemon 4 ай бұрын
Question here: he clearly has all the compounds and precursors for several drugs, for example Methamphetamine, @chemiolis are you sometimes tempted to try and make these compounds?
@mechanicbasic
@mechanicbasic 4 ай бұрын
Do Methaqualone!
@KeremYesilirmak
@KeremYesilirmak 2 ай бұрын
UCl4 looks yummy
@markpeene4757
@markpeene4757 3 ай бұрын
Sugestion can you synthesize a schiff base (primary amine with a ketone or aldehyde) some of them smell really nice
@talavs-jekabsriekstins578
@talavs-jekabsriekstins578 4 ай бұрын
More uranium chemistry! We want more! More! More!
@Jim1971a
@Jim1971a 4 ай бұрын
To make uranium I think you need a supernova.
@ZeL-iq5sf
@ZeL-iq5sf 4 ай бұрын
Cody's lab made it from ore before but the video was taken down
@missyclark6732
@missyclark6732 3 ай бұрын
Stewy griffin is looking for his uranium lol 😂
@freakcascade6809
@freakcascade6809 4 ай бұрын
Just what I needed thank you!
@KobyAustin1
@KobyAustin1 3 ай бұрын
I got to see this before the government makes him take it down!!
@eringotkilled
@eringotkilled 4 ай бұрын
its strangely terrifying to me how much of the process really is straight up homestuck green
@StarDust-zo8gd
@StarDust-zo8gd 3 ай бұрын
HF - Hydrogen fluoride at high levels or in combinations with skin contact can cause death from an irregular heartbeat or from fluid buildup in the lungs. Even small splashes of high concentration hydrogen fluoride products on the skin can be fatal !
@placeholder-k9n
@placeholder-k9n 4 ай бұрын
It's videos like this that make me question why I didn't get into nuclear or chemical engineering.
@anttikangasvieri1361
@anttikangasvieri1361 4 ай бұрын
I like the title, very nice.
@Gunbudder
@Gunbudder 4 ай бұрын
i feel lucky because i can just go outside and literally pick uranium ore up off the ground where i live, but also i feel cursed because there is radon gas everywhere and everyone has a radon gas system that vents their basement every day lol. background radiation here is an extra chest x-ray per 80 years (give or take)
@alexpotts6520
@alexpotts6520 4 ай бұрын
Is there a way of isolating the metal that doesn't use bone-hurting juice? (And if you *are* using HF, shouldn't you be doing the reaction in a plastic or passivated-metal container, rather than glassware?)
@thesciencefurry
@thesciencefurry 4 ай бұрын
I researched it a bit and I think the fluoride way is the easiest (unfortunately), Going with UCL4 works too but you need to do the reaction with hexachlopropene which is a bit more complicated. Wikipedia says you can also react calcium and UO3 but I don't think that happens at any reasonable temperature and speed.
@clairewithbanjo4992
@clairewithbanjo4992 4 ай бұрын
Delicious,there’s nothing like home made
@rian0xFFF
@rian0xFFF 4 ай бұрын
Next video Uranium enrichment, pls
@SamsulUdin-f5n
@SamsulUdin-f5n 2 ай бұрын
No anti radioactif googles??
@Drsteezymcgee
@Drsteezymcgee 4 ай бұрын
10:07 cracked me tf up lmfao
@voodoochile7581
@voodoochile7581 3 ай бұрын
Is that not dangerous?
@bromisovalum8417
@bromisovalum8417 4 ай бұрын
fascinating material, nice work!
@ConcreteBombDeep
@ConcreteBombDeep 4 ай бұрын
Do you not think you created more Uranium oxide than Uranium metal? It's just that your kiln barely gets to the temperature than Uranium would melt and it's not under an inert atmosphere. I studied how one might do this in a home lab and the part that seems the hardest to overcome is building the furnace suitable for such a project and then having a big enough amount that the slag can be easily separated from the Uranium metal.
@Chemiolis
@Chemiolis 4 ай бұрын
Yeah there’s definitely a bunch of oxides. In the future I want to get a smaller furnace that can go a little bit higher in temperature. This one is really unnecessarily big and it takes a long time to even heat up, got it off an auction. And the radiative heat is of course crazy when opened.
@erpetek
@erpetek 4 ай бұрын
Thank you, very useful video.
@AnonP2X3YZ
@AnonP2X3YZ 4 ай бұрын
Episode 2: Enriching Uranium
@Tylerx-z
@Tylerx-z 4 ай бұрын
Episode 3: building the bomb
@Quinazolinking
@Quinazolinking 4 ай бұрын
Are you uranium because I'm Iodine and if it was up to me I would rearrange the periodic table around and put U and I together 😻
@Raven99991
@Raven99991 4 ай бұрын
Daammm nice
@antonyanexen7080
@antonyanexen7080 4 ай бұрын
Yo we getting out of the reactor with this 🗣🗣🗣
@jozsiolah1435
@jozsiolah1435 Ай бұрын
When a missile is turned toward the Earth on the Moon, the Uranium starts to boil. Water doesn't boil on the Moon at 200 degrees, it evapourates. After a nuclear explosion, the movements of the tetra molecules can be speeded up by making earthquake, the cutter blades such as Titanium tetra oxyde will have a faster movement in the body, and a 2 cm long blade can form, 50x sharper than the razor blade. Its movement is similar to the boiling water in a dish. Boiling is caused by the oceans for water, for uranium the amount of uranium in the Earth's crust causes its boiling. If the Uranium is alloyed with diamond, its moving capability will be faster because of the amount of coal under the ground. The moving capability f the deltaeder oxygen is 0, because there is no oxygen belw the surface. The most dangerous nuclear molecule doesn't have a name, that's the combination of the deltaeder and the tetraeder. It is formed, when an explosion proof highway is hit by a warhead, and the rezonance of the concrete creates it mechanically.
@shakaibsafvi97
@shakaibsafvi97 4 ай бұрын
Excellent video.... how about reaching critical mass ??? :D
@Shonty_on_gfuel
@Shonty_on_gfuel 3 ай бұрын
"I'm Tyler folse, im a nuclear engineer with a little over 10 years of experience in the commercial nuclear power industry from engineering operations to emergency response, I don't claim to know everything there is nuclear, but I can certainly share some knowledge"
@juslitor
@juslitor 4 ай бұрын
not an insignificant chance of having a slightly contaminated vacuum pump now.
@deatheternal720
@deatheternal720 4 ай бұрын
such a pretty blue
@runed0s86
@runed0s86 4 ай бұрын
You can get real raw uranium from ruggles mine in New Hampshire USA.
@yume2727
@yume2727 4 ай бұрын
Blud bouta summon em glowies 😩😩😩😩😩
@blg53
@blg53 4 ай бұрын
Did you just add hydrofluoric acid to a glass beaker? :(
@justme1174
@justme1174 4 ай бұрын
am i legally allowed to watch this?
@Salt_and_Peroxide
@Salt_and_Peroxide 4 ай бұрын
great video man
@billynomates920
@billynomates920 4 ай бұрын
'self-sharpening' as well, apparently
@heypbolon1941
@heypbolon1941 4 ай бұрын
Anyone seen bug at 4:08?
@Crimetvuk
@Crimetvuk 15 күн бұрын
Two, a cat and a dog.
@canonicaltom
@canonicaltom 4 ай бұрын
Make a full-size play button! :D
@radov22
@radov22 3 ай бұрын
keep doing centrifuges until you have 99.99999% purity, that's where the magic begins
@BxBxProductions
@BxBxProductions 4 ай бұрын
can you make uranium play button fuel rod
@daveduna1
@daveduna1 4 ай бұрын
I have absolutely no need for that radiocode, but I still kind of want one. But I have no use for it ha. I can't justify it.
@ioanbota9397
@ioanbota9397 4 ай бұрын
Its interestyng this video
@fenzo4939
@fenzo4939 4 ай бұрын
thanks
@Side_Cuber2521
@Side_Cuber2521 2 ай бұрын
hey! your gonna get Uranium Fever
@DenshyOwO
@DenshyOwO 4 ай бұрын
Cool, now build an M829 projectile out of it
@嘉靖郭
@嘉靖郭 4 ай бұрын
Good job!amazing!
@phobos1963
@phobos1963 4 ай бұрын
Dang, 2 fluorine atoms away from enriching it
@Kargoneth
@Kargoneth 4 ай бұрын
Careful.
@captainchicky3744
@captainchicky3744 4 ай бұрын
wait oml fluorine chemistry too wow
@madent2103
@madent2103 3 ай бұрын
2021 exam had the same formula 😂 2:25
@chanheosican6636
@chanheosican6636 4 ай бұрын
After cody yes depleted uranium is much better.
@chemistryofquestionablequa6252
@chemistryofquestionablequa6252 4 ай бұрын
There’s a chemical enrichment process called “CHEMEX” but it’s probably best to avoid trying that without the proper licensing.
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Пришёл к другу на ночёвку 😂
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The Thought Emporium
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