Phase rule in Hindi || P+F =C+2 or P+F = C+1 || Gibbs phase rule || lecture 44 of igneous petrology

.Gibbs phase rule: -
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The rule was proposed by American scientist J.W. Gibbs.
Identifies the degree of freedom in a system using the number of component and the number of phase.
In more simple words; it tells us how many intensive variables must be defined to work out the state of system.
Intensive variable extensive variable
…………………………… ………………………………
Temperature, pressure, volume, mass,
Density, composition enthalpy
A consequence of the laws of the thermodynamics for any chemical system in equilibrium,
P+F= C+2 / F= C-P+2 / P= C+2-F
F= degree of freedom
C= number of components
P= number of phases
2= constant
• Phase: -
..--..--..--..
Phase are mechanically separable verities of matter that can be distinguished from one another verities based on their structure, composition, state.
Phase on igneous rock system includes minerals of various composition, crystal structure, amorphous solids (glass) and fluid such as liquid and glass.
• Component: -
..--..--..--..--..--..--..
Chemical components are usually expressed as proportion of oxides.
The most common chemical components in igneous reaction includes SiO2, Al2O3, FeO, MgO, CaO, Na2O, K2O, H2O and CO2.
N. B: - all phase in the system can be made by combining components in various proportion.
Degree of freedom: -
..--..--..--..--..--..--..--..---..
It refers to the number of variances. Number of independent factors that can vary, such as temperature, pressure.
Without changing the phase F is equilibrium with one another.
crystallization_of_magma
• Crystallization of Mag...
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