Practice drawing SN1 vs SN2 reaction mechanisms and products with more than 9 examples

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Visual Learners

Visual Learners

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SN1 vs SN2 reaction mechanisms wand products with multiple examples
Carbocation rearrangement
Racemic mixture
Inversion in configuration
• How to think through a...
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Пікірлер: 25
@dijunwang4831
@dijunwang4831 Жыл бұрын
Another question I have is at 20:30, when we deal with the resonance structures, do we need to consider the matter of trans or cis for the double bond? For example, the chlorine leaves and the methyl group is on the plane. But can it form a cis (Z) in the double bond? Thank you :)
@russelwagner659
@russelwagner659 2 жыл бұрын
For the 6th problem (11:50), once the Cl leaves, why can't you shift the charge over from the adjacent methyl? Is it because it's an Sn2 reaction?
@herosr719
@herosr719 Жыл бұрын
Yes sn2
@rahaelj.3437
@rahaelj.3437 2 жыл бұрын
For the problem with the secondary allylic and the H20 at 18:28 I'm confused as to why the whole chlorine group doesn't leave...? Wouldn't the that whole bond attached to the chlorine leave as well?
@visuallearners1832
@visuallearners1832 2 жыл бұрын
It does. The remaining bond is actually methyl that was coming out of the page in the reactant. It becomes planar once carbocation is created.
@rahaelj.3437
@rahaelj.3437 2 жыл бұрын
@@visuallearners1832 OHHH okok I see what you mean! Thank you so much! This vid was really helpful :)
@ammar-c9u
@ammar-c9u Жыл бұрын
what software do you use bro?
@visuallearners1832
@visuallearners1832 2 жыл бұрын
You are correct. Since it uses acetone (Aprotic) as solvent it will do SN2. So no rearrangements and carbocation formation.
@russelwagner659
@russelwagner659 2 жыл бұрын
Ok, amazing video by the way. EXTREMELY helpful
@dijunwang4831
@dijunwang4831 Жыл бұрын
Hi Sir. Thanks for your video. I have a question at 16:50. Why do we have to draw a flipped configuration at this point? It seems that we don't need to consider stereochemistry because chlorine is on the plane :)
@visuallearners1832
@visuallearners1832 Жыл бұрын
Since it is SN2 you will need to flip chirality. You can draw the product however you want as long as it has flipped chirality from the reactant.
@dijunwang4831
@dijunwang4831 Жыл бұрын
@@visuallearners1832 Thank you Sir!!! I think you explain a lot of important details that didn't appear in other ochem videos I've watched. Gratitude beyond words Sir!!
@hassaniqbal8009
@hassaniqbal8009 2 жыл бұрын
Very helpful thank you soo much
@yeabsiradessalegn2181
@yeabsiradessalegn2181 2 жыл бұрын
Thank you so much 🙏
@mykateha0297
@mykateha0297 Жыл бұрын
Thank you so much, it helps a lot🙏
@mykateha0297
@mykateha0297 Жыл бұрын
22:05 it's 2° right? Can we make it to be 3°??
@visuallearners1832
@visuallearners1832 Жыл бұрын
It is secondary and benzylic. You cannot rearrange it to 3 as there is a benzene ring on the left side.
@lintamariajoseph5354
@lintamariajoseph5354 8 ай бұрын
Sorry i dont understand on 11.10, where the chirality, like its attached to 2 methyl groups, its the same
@MadiaZab
@MadiaZab 2 жыл бұрын
Thank you for a very helpful video. For the very last example with SN1 reaction, how is that a chiral center after Br leaves?
@visuallearners1832
@visuallearners1832 2 жыл бұрын
It will eventually make a chiral center once nucleophile attack. So you should treat as such once carbocation created in order to get correct stereochemistry.
@herosr719
@herosr719 Жыл бұрын
Hey why is I replacing cl Cl is a bad leaving grp right
@visuallearners1832
@visuallearners1832 Жыл бұрын
Both Cl and I are good leaving group. Relatively, I is a better LG then Cl. However, the driving force of this reaction is solubility. NaCl and NaBr do not dissolve in acetone, whereas NaI does.
@herosr719
@herosr719 Жыл бұрын
@@visuallearners1832 oh
@atdr-q9z
@atdr-q9z 3 ай бұрын
pls upload a pdf of thiss
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