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You can weld Stainless without argon purging. You just need to cut a backing band and properly tack it into place.
There are many different kinds of V-Band flanges. Standard V-band flanges are great because one size fits all. The standard machined steel ones that fit over the tube need to have the tube stick out on one side and recessed on the other, so the assembly holds itself together during assembly and doesn't leak so easily. Care must be taken during the welding process to minimize gap and accompanying weld distortion. Any inconsistent gap is going to cause distortion, since more weld metal = more heat distortion. Whatever gap you do have during fitment, keep it even by distributing your tack welds. Flanges with grooves in them are easier to weld, but there's no guarantee. The benefit of grooved V-band flanges is shallow assembly.
Marman V-band flanges are a stamped steel creation. Since they're made of steel tubing, it's easier to get a perfect fitment and equally perfect weld. Easily the best choice for most exhaust systems. As long as the flange doesn't glow red hot, you're in good shape.
304 Stainless steel is most corrosion resistant below 700F, 375C. As long as it's blue, you're home-free, life is good, and the steel isn't even trying. Once it turns grey, you're past 450C, 800F. That's fine, but it lets you know that you're making it earn its life.
--Sure, you can run 304 stainless steel to 1500F, 800C, Bright orange red hot. Avoid bombarding it with salt water during these times. It's not the end of the world, but you're in the realm of aging, instead of time-proof.
Marman and conventional V-bands are both great pieces if implemented correctly.