Metal-Metal bonds and isolobal analogy

  Рет қаралды 56,375

Gate Chemistry

Gate Chemistry

7 жыл бұрын

Formula to calculate metal metal bonds in clusters and brief discussion on isolobal analogy.

Пікірлер: 153
@shabnamdan7898
@shabnamdan7898 6 жыл бұрын
Thank you for posting this video, this will be a great help. Your method of teaching is really great.
@christinemathew4116
@christinemathew4116 6 жыл бұрын
Awesome video Sir...it has so much cleared my concepts.
@educationtheonlyweapon5897
@educationtheonlyweapon5897 6 жыл бұрын
Excellent sir 👍👍👍your way of explanation is amazing Tq 😊
@Bittu_Chem
@Bittu_Chem 6 жыл бұрын
thank ypu so much sir. i am your regular video viewer.. it helps me lot. 😊👍👌💐
@swatisharma-nt7ws
@swatisharma-nt7ws 6 жыл бұрын
Thanks a lot buddy.... ice doing a good cause for d ones who can't go anywhere for coaching due to some circumstances.really thanks
@RAJPAL-gg2yu
@RAJPAL-gg2yu 6 жыл бұрын
thanks sir very useful sorry I started now preparing for June 2018 so now I started watch ur videos very usefull thanks alot😊😊😊
@debojyotimukherjee262
@debojyotimukherjee262 6 жыл бұрын
Sir you just fab...sir plz keep updating us.
@A_chem
@A_chem 3 жыл бұрын
Super explained 🔥🔥 I wish I get a chance to study organic chemistry 🙄
@chemistrywithsrinivassir8522
@chemistrywithsrinivassir8522 6 жыл бұрын
Excellent, thank you very much sir
@uddalokkar7124
@uddalokkar7124 5 жыл бұрын
Sir , how to find out B.O. in clusters like [ Re2Cl8] (2-) . It will be of great help Sir
@nehasinghneha3974
@nehasinghneha3974 6 жыл бұрын
Thankuu. Nice lecture
@ruchiipant3089
@ruchiipant3089 6 жыл бұрын
Thanku Sir...ur videos are awesome...Very helpful...Can you explain difference between isoelectronic and isolobal analogy...???
@sagar07wagh
@sagar07wagh 6 жыл бұрын
Very nice good job sir
@anjushakurian8180
@anjushakurian8180 5 жыл бұрын
Sir pls make videos on all the important topics of csir.bcz, your lectures are really helpful for understanding of topics clearly
@nehapandey4539
@nehapandey4539 6 жыл бұрын
your all vedios are very helpful sir thankyou so much
@nehapandey4539
@nehapandey4539 6 жыл бұрын
sir can u tell me a proper plan to prepare for csir june 2018 exam
@navjottaluja1871
@navjottaluja1871 6 жыл бұрын
Hey sir.. will it be sufficient to watch inorganic and physical videos provided by you for june net?
@aasthasingh9784
@aasthasingh9784 7 жыл бұрын
Thanks sir.... Plz upload video on jahn teller distortion
@prakashsaha1449
@prakashsaha1449 5 жыл бұрын
How can I calculate number of Terminal CO present in Fe2(CO)9 ?
@saldias7475
@saldias7475 7 жыл бұрын
Sir can u tell me how to know if a particular ligand is acting as a bridging ligand in cluster and how to find the no of bridging ligands
@deeh9260
@deeh9260 6 жыл бұрын
Thankyou so much !
@sadhguru2358
@sadhguru2358 5 жыл бұрын
sir please tell how to calculate number of bridged carbonmonoxide ligands in metal carbonyl clusters
@growpotential9016
@growpotential9016 6 жыл бұрын
Sir i like ur videos very much I have a question calculate no. Of metal metal bond and bridge ligand in complex Co3(CH)(CO)9 given complex follow 18e rule
@sautrickchowdhury89
@sautrickchowdhury89 6 жыл бұрын
very nice explanation...guess you were talking about Inorganic Chemistry by CATHERINE E. HOUSECROFT AND ALAN G. SHARPE
@Venki_Talks
@Venki_Talks 5 жыл бұрын
Can you please explain how to calculate Bond order in Nb6Cl12^2+
@aasthaaggarwal348
@aasthaaggarwal348 6 жыл бұрын
Sir please tell how to calculate bond order in metal halide clusters eg in [Nb6Cl12] 2+
@ankitaupadhyay3545
@ankitaupadhyay3545 6 жыл бұрын
what will be the structure of Mn(2-B3H8)(CO)4? NIDO, CLOSO OR ARCHNO?
@yogeshmanitripathi8452
@yogeshmanitripathi8452 6 жыл бұрын
is there any video on sigmatropic pericyclic reactions
@priyankabansal9980
@priyankabansal9980 6 жыл бұрын
sir pls make a video on 18 electron rule as it has come almost in every gate nd csir queation papers
@priyankajalotra2300
@priyankajalotra2300 6 жыл бұрын
Sir I have asked you earlier to explain ionic strength.. How to calculate it.. We find it usually in the Csir net in some way or the other.
@ishikajha9355
@ishikajha9355 7 жыл бұрын
thanks.it is really helpful.sir plz upload video on orgel diagram nd tanabe sugano diagram.
@sakshimehta7787
@sakshimehta7787 6 жыл бұрын
sir can u please make a video on how much a ligand contribute and secondary in isolobal analogy can we a fragment which has 6 electrons
@bharathipendli4877
@bharathipendli4877 6 жыл бұрын
Is your videos and practicing questions are sufficient for preparing net?
@sdeb3333
@sdeb3333 4 жыл бұрын
In W2(OPh)6 the OPh group is bridging that is why it contributes 3 electrons..but how do we know that it is bridging from the formula?
@pragyamaheshwari7718
@pragyamaheshwari7718 6 жыл бұрын
Sir how to determine bridgeing ligands
@sivaramakrishna4249
@sivaramakrishna4249 6 жыл бұрын
Sir,how many metal metal bonds in {Mo2(OAC)4},could you explain.
@sapnabarad2739
@sapnabarad2739 6 жыл бұрын
SIR howmany electron that HPO4 contribute in [MO2(HPO4)4]-2
@sapnabarad2739
@sapnabarad2739 6 жыл бұрын
HELLO sir ...sir how many electron that OR contribute in Mo2(OR)6.. sir pls tell me
@nivasmane5747
@nivasmane5747 6 жыл бұрын
thank you sir
@devigag6647
@devigag6647 5 жыл бұрын
Tq so much sir... Sir plz tell me the valence electrons for some important ligands... I have my exam on tmrw sir... Replay me pls
@navyakalingapatnam8018
@navyakalingapatnam8018 6 жыл бұрын
sir,is there any video about chemical periodicity?
@sk-ml6ox
@sk-ml6ox 6 жыл бұрын
sir, plz explain , how to calculate bridging co or ligand
@sanjuktamishra7930
@sanjuktamishra7930 6 жыл бұрын
Sir how many electrons O2 and S2 contribute in neutral counting of metal clusters ?
@SantoshYadav-oh6ff
@SantoshYadav-oh6ff 6 жыл бұрын
Sir will u pls make a vedio on association dissociations and interchange of inorganic mechanism
@X_plore
@X_plore 6 жыл бұрын
Sir please make a video on Quantum Chemistry, specifically for perturbation theory.
@dhikshasharma8960
@dhikshasharma8960 6 жыл бұрын
Sir plzzzz answer the question of quantum of 2marks june 2017 .....it is 1d box in between 0,8 interval .....47 of series A ..plzzzzzzz it hardly takes 2 min
@gowthammanoharan2640
@gowthammanoharan2640 6 жыл бұрын
(16:14) It is Inorganic chemistry by Catherine E.Housecraft sir
@priyankabansal9980
@priyankabansal9980 6 жыл бұрын
thankyou sir...!!!
@sachukc
@sachukc 6 жыл бұрын
sir how can we find the coordination number of phosphorus in compound (PMo12O40)3-?? I mean compound -(phosphorus molybdenum 12 0xygen40)3- can you help me sir?
@jinpinh
@jinpinh 6 жыл бұрын
Thank u Sir...
@nikhilverma9256
@nikhilverma9256 7 жыл бұрын
thanks sir
@manjunath.haramagatti5962
@manjunath.haramagatti5962 6 жыл бұрын
How to calculate no.of bridge and non bridge carbonyl group in metal cluster?
@priyapriyu8435
@priyapriyu8435 6 жыл бұрын
Very nice
@sachukc
@sachukc 6 жыл бұрын
sir phosphorus nitrogen compounds and sulfur nitrogen compounds structures...can u give one class.it is well described in huheey .any other tricks to remember these structures..
@sunandinipaturi1332
@sunandinipaturi1332 4 жыл бұрын
Sir plzz calculate m-m bonds in [W2(oph)9]-3 and how can calculate when metal having a oxidation state .🙏🙏
@goonjthevoiceinside7574
@goonjthevoiceinside7574 6 жыл бұрын
Sir....You r simply amazing...... And ur way of explanation is perfect....
@shalukumari8280
@shalukumari8280 6 жыл бұрын
sir can u plz explain isopoly n heteropoly acids
@ParthFunJam
@ParthFunJam 6 жыл бұрын
Help me to solve the metal metal bond in [(C5H5)Fe(CO)2]2
@bharathipendli4877
@bharathipendli4877 6 жыл бұрын
What should I do for getting another 80 marks.
@jagatjotkaur4551
@jagatjotkaur4551 6 жыл бұрын
Sir,how to calculate bond order for (Re2cl8)2-, (Re2Cl6 (P(C2H5)3)2, and (Re2Cl4(P(C2H5)Ph2)4)
@KaleemKhan-lq6kf
@KaleemKhan-lq6kf 6 жыл бұрын
Thanks
@deepakvishwakarma-os5ph
@deepakvishwakarma-os5ph 7 жыл бұрын
awsom video
@pych23
@pych23 6 жыл бұрын
Sir, I just want to clear a doubt. Isn't bond order means no. of bonds between metal and not total M-M bond in the cluster? So, in case of W2(OPh) 6 we use 30/2 =15 then 18-15=3 i. e. Bond order is 3 though there are only 2 W so both will give same answer. I am having doubts please correct me if I'm wrong.
@kakalidevi2497
@kakalidevi2497 6 жыл бұрын
Is there any shortcut method to calculate the no of bridging ligand in metal complex ? It will be very much helpful for me if you solve the question no 25 from December 16 part a.
@kakalidevi2497
@kakalidevi2497 6 жыл бұрын
Is there any provision to buy the vedio?
@shabnamdan7898
@shabnamdan7898 6 жыл бұрын
Sir When there are two transition metals in a cluster than for the value of n we should take contribution of both the metals ?
@shabnamdan7898
@shabnamdan7898 6 жыл бұрын
Gate chemistry Okay. Thanks.
@ChemistryTadkaSachinshukla
@ChemistryTadkaSachinshukla 6 жыл бұрын
(Re2cl8)²- how many matel matel bond
@priyankagupta6575
@priyankagupta6575 6 жыл бұрын
Sir can you please a video on bio inorganic chemistry ?
@dhikshasharma8960
@dhikshasharma8960 6 жыл бұрын
Sir plzzz upload a video on mno rule for deducing skeltal electrons......m not able to get thru it from book .....this is given in every book.......nd i hv an intuition dis tym mno rule will cm.....plz plz plz plz upload before sunday
@finazkhan9382
@finazkhan9382 6 жыл бұрын
Styx code? What is it for BnHn
@pgboy5149
@pgboy5149 6 жыл бұрын
sir ..I tried to calculate..bond order of Re2cl8^-2...the way u tought..it is coming out 6..bt it has M-M &bond order = 4...how sir?
@alkasharma4161
@alkasharma4161 6 жыл бұрын
Manish Tripathi because it is follow 16 electron if u take 16 electron in place of 18 electron then get 4
@rahulbishnoi7948
@rahulbishnoi7948 6 жыл бұрын
sir plz give video for quantum chemistry
@thechemistsclub7471
@thechemistsclub7471 4 жыл бұрын
Great sir #thechemistsclub
@reshmapatil6659
@reshmapatil6659 5 жыл бұрын
Sir ur videos are very helpful n u explain very well but I feel ur voice is not clear n can't see what u write on board so if can work it on ,, other wise excellent
@bobbalisandhya4861
@bobbalisandhya4861 4 жыл бұрын
Plz sir make a concise vedio on reactions of carbohydrates
@abdevilliers7112
@abdevilliers7112 6 жыл бұрын
Sir please make a video on How to find bridged, terminal ligands in given compounds
@astammandal8824
@astammandal8824 6 жыл бұрын
Sir ,can you explain me why the bridge chlorine atom contributes 3 electron?
@astammandal8824
@astammandal8824 6 жыл бұрын
ok. sir
@WOA09
@WOA09 6 жыл бұрын
sir can u plz solve question no.124setA june2016
@incredibleminds3322
@incredibleminds3322 7 жыл бұрын
sir, please upload videos on inner and outer sphere mechanism
@nargisjafriofficial
@nargisjafriofficial 7 жыл бұрын
Very nice explanation but can u give a list which will tell us the valence electrons different ligands carry...since organic students find difficulty in knowing the no.of electrons ligands carry like in this example OPh ligand
@nargisjafriofficial
@nargisjafriofficial 7 жыл бұрын
Ok...thank you
@chetnahasija9975
@chetnahasija9975 6 жыл бұрын
Nargis Parvaneh there is a pdf file available online.just type 18 e rule pdf you'll find a list of ligands there.Hope it helps
@nargisjafriofficial
@nargisjafriofficial 6 жыл бұрын
BK Chetna HASIJA Oh thank you so much
@brindhasubramanian7375
@brindhasubramanian7375 6 жыл бұрын
sir y we using 18 in formula
@vinod_10
@vinod_10 7 жыл бұрын
THAnks sir
@akshpreetkaur6932
@akshpreetkaur6932 6 жыл бұрын
sir same formula can be used for nitrido and carbido metal cluster??? but there is error by using this formula for nitrodo metal cluster
@akshpreetkaur6932
@akshpreetkaur6932 6 жыл бұрын
Ru6C(CO)17
@akshpreetkaur6932
@akshpreetkaur6932 6 жыл бұрын
sir plz rply??
@radhikakp2613
@radhikakp2613 6 жыл бұрын
sir i want a topic for my project..
@sivan9219
@sivan9219 7 жыл бұрын
Sir, good morning Am preparing like which of the complex obey 18 rule... In this question we can't remember the contribution of the ligands... And also in this video metal metal bond also need to know the contribution of ligands.. So pls suggest some important points it will help lot like me.. Thank you sir..
@sivan9219
@sivan9219 7 жыл бұрын
K sir.. Thank you
@piyushpattanaik1829
@piyushpattanaik1829 5 жыл бұрын
then tell one simplifying the example of tungsten having 4 in no.s and tell the bond order related to no of metal-metal bond in the cluster.
@indrajitmahto5113
@indrajitmahto5113 7 жыл бұрын
You are from which place??
@sk-ml6ox
@sk-ml6ox 6 жыл бұрын
how can we know no. of bridging and non bridging co ligand
@RahulGupta-ki1wt
@RahulGupta-ki1wt 6 жыл бұрын
Sir how many electrons RS group contributes in isolobal analogy. Question number 138 June 2014 B series
@chembasicsbysujitkumar3705
@chembasicsbysujitkumar3705 6 жыл бұрын
actually it contributes 7 elctrons as = 1+6 = 7 elctrons and so it is isolobal with Mn(CO)5 = 7 + 10 = 17 electrons as both of them are deficient with 1 electron
@MukeshSharma-mv6fr
@MukeshSharma-mv6fr 7 жыл бұрын
Great
@sudheer2643
@sudheer2643 7 жыл бұрын
Sir plz provide some more csir shortcuts for bits
@bobbalisandhya4861
@bobbalisandhya4861 5 жыл бұрын
Gd evng sir please make a vedios on photo chemistry
@habeebaunnisa9344
@habeebaunnisa9344 6 жыл бұрын
sir wi u please dicuss complete inorganic chemistry topics related to csir net
@sapnabarad2739
@sapnabarad2739 6 жыл бұрын
sir OR contribute 3 or 1 electron ,? i m little confused
@vishalsukhija7393
@vishalsukhija7393 6 жыл бұрын
Sapna Barad me also
@dixjain9635
@dixjain9635 4 жыл бұрын
Is H is isolobal to CH3???
@menkavishwakarma3449
@menkavishwakarma3449 6 жыл бұрын
Sir (Re(Cl)4(PMe2Ph) 4) + ma metal metal kitne hoga
@menkavishwakarma3449
@menkavishwakarma3449 6 жыл бұрын
(Re2(Cl) 4(PMe2Ph) 4) +
@kitymaurya3102
@kitymaurya3102 7 жыл бұрын
Sir plz provide the electrons contributed by the ligands commonly asked in CSIR NET .....
@VaishnaviDevi316
@VaishnaviDevi316 6 жыл бұрын
Shriver and Atkins very good book to refer
@chemistrylover2327
@chemistrylover2327 6 жыл бұрын
Sir please upload bio inorganic chemistry
@vishalsukhija7393
@vishalsukhija7393 6 жыл бұрын
How OPh contribute 3e, it only contribute 3 if it is bridging nd if it is terminal den contribute only 1e. Am i ryt sir?
@jagadeeshmanda2497
@jagadeeshmanda2497 6 жыл бұрын
Vishal Sukhija yes sir plz clarifie doubt
@vishalsukhija7393
@vishalsukhija7393 6 жыл бұрын
jagadeesh manda any lone pair containing ligand present on bridging position with 2 metal always contribute 3e, if metal is three then it will contribute 5e
@jagadeeshmanda2497
@jagadeeshmanda2497 6 жыл бұрын
Vishal Sukhija yes sir i agree with u
@Samikshn24
@Samikshn24 6 жыл бұрын
Sir please clarify the doubt....OPh contributes 3 e- only while forming bridges
@DrRKKadu
@DrRKKadu 6 жыл бұрын
Please solve M-M bond in Re2Cl8)-2 ?? By applying ur Formula.. I tried.. But m not getting correct ans
@DrRKKadu
@DrRKKadu 6 жыл бұрын
Ok sir
@vidyabisht2986
@vidyabisht2986 6 жыл бұрын
sir is in cluster cl contribute 3e????
@vidyabisht2986
@vidyabisht2986 6 жыл бұрын
is in evry cluster cl contribute 3e????
@vidyabisht2986
@vidyabisht2986 6 жыл бұрын
kkkkk sr...thank
@priyankagupta6575
@priyankagupta6575 6 жыл бұрын
sir what is structure of Me2C2B10H10?
@priyankagupta6575
@priyankagupta6575 6 жыл бұрын
its Arachno according to me ??
@priyankagupta6575
@priyankagupta6575 6 жыл бұрын
THANKS A LOT SIR
@priyankagupta6575
@priyankagupta6575 6 жыл бұрын
sir can we solve it with isolobal analogy? why?
Cluster Compounds - Crash Course
17:37
Gate Chemistry
Рет қаралды 23 М.
LMCT, MLCT and d-d transitions
26:25
Gate Chemistry
Рет қаралды 87 М.
Heartwarming moment as priest rescues ceremony with kindness #shorts
00:33
Fabiosa Best Lifehacks
Рет қаралды 38 МЛН
How Many Balloons Does It Take To Fly?
00:18
MrBeast
Рет қаралды 171 МЛН
Sigma Kid Hair #funny #sigma #comedy
00:33
CRAZY GREAPA
Рет қаралды 33 МЛН
ISOLOBAL ANALOGY (Simplest Trick) |  Solved Problems from Previous Years
17:43
Isolobal Analogy & related problems from csir-net exam
17:59
Priyanka Jain
Рет қаралды 27 М.
Inner Sphere Electron Transfer Mechanism
27:31
Gate Chemistry
Рет қаралды 49 М.
80 Year Olds Share Advice for Younger Self
12:22
Sprouht
Рет қаралды 1,4 МЛН
6 Levels of Thinking Every Student MUST Master
17:12
Justin Sung
Рет қаралды 1,3 МЛН
Ligand Contribution and 18e rule
16:35
Gate Chemistry
Рет қаралды 49 М.
Normal Spinels, Inverse Spinels and Mixed Spinels
20:55
Gate Chemistry
Рет қаралды 74 М.
ESR/EPR Spectroscopy - Vital Topic
37:06
Gate Chemistry
Рет қаралды 97 М.
Heartwarming moment as priest rescues ceremony with kindness #shorts
00:33
Fabiosa Best Lifehacks
Рет қаралды 38 МЛН