Inner Sphere Electron Transfer Mechanism

Talk about Inner Sphere mechanism and how to differentiate b/w inner and outer sphere mechanism.

[@kirubabowneeth3928]

Main plus point of ur lecture is ,you teach in English...so that people all over India gets beneficial...tq....tq so much sir

[@dipikadipika5626]

Even our teachers never explain the topic so beautifully.. U r gr8

[@nargisjafriofficial]

God bless you... inorganic is becoming interesting for me now...👍👍

[@illandulasathish6034]

I love uvr teaching with patients....😍😍😍

[@kirubabowneeth3928]

Tq sir...no professors taught like u..now...i hav good idea about this topic

[@nehapandey4539]

Thankyou sir for thorough explanation of coordination complexes...i follow all your vedios for clearing all my doubt in all the inorganic topics i am totally following what you guide and told for the preparation of csir net exam for june 2018...i hope following you dedicately will get me through csir i had no one to guide so i strickly follow what you say

[@chaithrakg2285]

Thank u very much sir. U are helping me a lot. Thanx a lot

[@orbitclasses194]

It was very helpful ☺️

[@bainisrilatha256]

very helpful thank you so much sir

[@titaniumarmy3863]

Sir Co(CN)5 3- is a low spin complex and there is one eg electron.How this compound would be Inert, I think it should be labile.

[@shikhabhandari2451]

Co+2 = d7 and CN is strong field ligand so it pair up all the 6e in 3 subshell and and the 7th e in 4th subshell still 1 is left due to which it is labile

[@homemadeanimates2872]

@@shikhabhandari2451 i think Co CN6 will have charge 2-

[@Aakriti_kiaan]

(Co(CN)5)3- is co-ordinatively unsaturated than how it can be inert??

[@BioML]

sir u said 4d and 5d all the metals form inert complex due to huge size so Mo should have been inert right?

[@sandipbiswas2868]

The reaction between (Fe(CN) 6)4- and (Fe(bpy)3)3+ proceed via inner or outer sphere mechanism? Please let me know

[@javidahmaddar9761]

sir co+3 are low spin with most of legands except F,CL,Br etc. but here is only one cl .so can it b high spin or low spin

[@beautykumari8849]

Sir what is the mechanism of the reaction between [Fe(CN)6]4- and [Fe(bpy)3]3+

[@vijaybahadur751]

Thanks sir for making these vedios

[@chemspark9813]

thnk u so much for video:-)

[@varshakhandelwal9379]

Ur way of explaining things is really good.. Plz also explain what to study in cyclic polyene complexes.. I m really confused..

[@kanikalalit1153]

i have a doubt that after the removal of cl shouldnt there be +3 charge over the complex

[@shwetaraut1535]

Thank you soo much sir

[@BalamuruganM-wk1di]

Since Mo is in d1 configuration it is inert becoz it is 4d element .In labile and inert complex video u told that 4d& 5d element better interaction with ligand (strong bond).so Mo complex is also inert , Fe complex also inert so it under go outer sphere. it is correct or not?

[@fieryelektra2692]

You are soooooo good at explaining! I just love how simple u make it. Can u recommend a guide or textbook where these concepts are explained simply? Also, can you make a video on complexes reaction mechanisms (Associative, Dissociative, Interchange, Eigen-Wilkins, Solvolysis, etc) and their according rate laws. Thanks!

[@jyotibhatt8117]

Thank u sir.

[@sudheer2643]

Thanks a lot sir

[@kironhazarika8547]

Thank you sir...

[@yenugunikhil9862]

Sir, since Mo is in 4d series. Therefore it's complex is inert right.

[@supriyabodake4366]

sir can you please make a vedio on pericyclic reactions related to only reactions which have steriochemistry of product

[@monikayadav7376]

Thanks to you..😀

[@Owias_Rahman]

How can we enhance the lifetime of successor complex? Anyone can answer

[@pragatiswain6914]

Big thumbs up!😄

[@sadiaanjum9813]

Sir Molybdenum belong to 4d series transition metal... All 4d and 5d transition metal Complexes are always inert... Is it true plz rply....

[@sapnabarad2739]

Sir, your teaching is Awesome...your all videos are very very helpful ..Thank you very much sir

[@srabanighosh6746]

Thnks a lot sir...

[@sofiagupta1506]

Sir thanks 🤗

[@Monikasingh-jo8zc]

Sir one thing I didn't get is that from which complex to which complex the electron transfer is taking place.........pls reply .....m getting vry mch confused Thnks

[@abhishekgarg8964]

Sir,is pentacynocobalt(2) u discussed is stable. and if it is then it should be labile.

[@abhishekgarg8964]

7:00-7:30

[@ksatish6258]

thnk u so much sir

[@AjaySingh-sm8hb]

thanks sir

[@NG-xk7fc]

Mo(CN)6 is inert or labile u said in labile and innert complexes video that 4d and 5d are inert

[@as-bw6sr]

Thanks sir good goodies

[@vijaywankhade1904]

Thanks bro

[@mukeshagrawal9351]

pls give a thorogh explanation of tanabe sugano diaram

[@kuldeepchoubisa9909]

sir please can u tell me why [co (nh3 )]2+ is high spin complex though nh3 is strong ligand....sir cfse of this complex was asked in gate 2017 .. sir plz rply

[@kuldeepchoubisa9909]

sorry sir complex was [co( nh3)6]2+

[@deblinamallick6536]

What is about rate of this reaction??

[@kuldeepchoubisa9909]

thanx sir

[@kanikalalit1153]

Can u make a video over inorganic hyrolysis in case of metal complexes

[@madhuriborude7890]

Can you explain one electron tanfer reaction

[@somya_347]

Thanks

[@dhrittimisra5800]

In the video of labile and inert complex you wrote d7,d8,d9,d10 complexes are labile. But here in the example of [Co(CN)5]^3- and [Fe(CN)6]^3- why the cobalt complex is inert? Can you please explain?

[@AshwaniMauryaAM]

Cobalt complex is labile here

[@titaniumarmy3863]

I have the same doubt as that of yours.

[@titaniumarmy3863]

See gate chemistry reply to subham Singh where he rectified his mistake.

[@yesimbasak2498]

i thought the same thing, it should be labile because Co has oxd state +2, so it is d7, but eventually again inner sphere mechanism takes place.

[@masterharwindersingh4479]

Tnqqqqq sir ....

[@dhikshasharma8960]

I have two questions...1. If there are two bridgin ligand which ligand transfers the elec....( as in 17 -18 min) 2. If along with inner nd outer options 3rd and 4th option of self and cross rxn comes....self toh we knw bt how do diiferentiate self cross with outer .....

[@gtmkumar34]

thanks

[@smaranikabardhan7985]

Thnks

[@KaleemKhan-lq6kf]

Tanks

[@jonmonisarma1256]

Sir i just watched the video on outer sphere mechanism. There you described clearly that except 3d metals, all 4d or 5d metals form inert complexes because those d orbitals are more diffused, so can interact strongly with the ligand orbitals forming inert complexes. Than following strictly to that explaination will only give us the idea that [Mo(CN)8]3- is an inert complex and it is not labile because there Mo(V) has a 4d1 orbital.

[@yogi5752]

if you mention the source of videos i.e. which textbook or which website that will be very nice

[@deekshasaini9607]

helpful....

[@shashwatmadan5227]

Right!!

[@maayurir4964]

Sir please tell what are the things I've to know before watching inner sphere electron transfer mechanism. Bcoz I'm not able to follow, even I watched labile and outer sphere electron transfer mechanism. Thank you for your explanation.

[@maayurir4964]

Thank you sir. I'll do it.

[@yogiyogi5220]

At 11.05 (1.) The Fe and Mo complex you said is reacting through outer sphere mechanism. I think this is because Fe complex has d-5 system so it is inert, and Mo complex is higher transition element so its outer d-orbital can effectively overlap with its ligand forming a stronger ionic metal-lignad bond therefore it's way too almost inert in reactivity. And thus it follows outer sphere mechanism. (2.) 👉👉The Co complex and Fe Complex at 11:05 only you said showing inner sphere charge transfer mechanism. "" It has to be"" because I think [Co(CN)5]^-3 is labile complex as it has d-2 system. Correct me if I'm wrong. One of your subscriber.

[@vishalsukhija7393]

Bro i think it is not d-2 system it is d-7..

[@vijayamaurya2991]

Vishal Sukhija yes itsd7 BT d7 also labile not inert. then how inert??

[@vijayamaurya2991]

Yogesh Dubey in Co case it is in d7 which is labile and in case of Fe its in d6 low spin which is inert ..so the reaction happens.

[@aseshdas3328]

Write out mechanism for the inner-sphere electron transfer reaction between [Co(NH3)5SCN]2+ and [Cr(H2O)6] 2+ that produces the pentaaquo-Nthiocyanatochromium(III) cation as one of its products.

[@orbitclasses194]

Innner sphere mechanism

[@parujamwal2112]

plz make on Marcus theory

[@jyotirajput9456]

Sir pls make vedio over molecular term symbol also

[@sowjanyap5307]

Sir Please teach spectral behaviour of Metallocenes thank you

[@dipankipal447]

Sir can you please make a video some solving questionsb about Kramer's degeneracy

[@sachinchandran7836]

Sir bioinorganic class pls...do you have any simple method to learn this topic easily ...important parts only sir.pls try if u have time sir...

[@shaswatvikramgupta]

How [Co(CN)5]3- is inert,if there is d7 electrons .

[@shaswatvikramgupta]

Gate chemistry ..11:08 in exception case

[@chemspark9813]

how will be (CO(CN)5)3- inert? didn't get it plz reply sir

[@chemspark9813]

Gate chemistry but sir here co is in +2 os

[@chemspark9813]

how can be both inert togather sir

[@chemspark9813]

Gate chemistry thnk god thnk u so much sir it was very confusing now all Clear happy

[@jyotiyadav2387]

[IrCl6]²- + [Cr(H2O)6 ]² Which mechanism will it follow?

[@deebikabaskar2067]

It follows inner sphere mechanism without ligand transfer. It's an exceptional case

[@titaniumarmy3863]

Ir4+ is low spin d5 system(inert) and cr2+ is high spin d4 system(labile). Thus inert -labile combination may lead to inner sphere mechanism.

[@Supdada]

Hello sir this is PRATHAP. End of the video jus tell reference book which u refered...

[@Supdada]

OK sir... Thank you

[@feelingofheart1370]

[Co(CN)5]3- how inert

[@INFOGUIDEBENGALI]

video is not playing

[@KripasindhuKarmakar]

Target : Inorganic Coordination

[@anuradharathinavel9938]

Sir it will be useful if you teach us ligands field theory...

[@anuradharathinavel9938]

@@gatechemistry I'm learning many concepts only from your lectures. You are a wonderful teacher. Thank you very much for your reply

[@chemysteryassets]

Sir if u don't mind , my teacher explained that [Co(cn)5]3- is labile in nature , muje lgta apne galti se inert bol dya use

[@chemysteryassets]

Sir I think d8 also inert bcz here z effective increases in d8 and metal ligand bond will be stronger

[@chemysteryassets]

OK OK

[@madhu-tn5cx]

Gate chemistry but u write Co(CN)5/3-as inert how ?

[@sayareddykatta6404]

Eg have 0 electron is inert

[@madhu-tn5cx]

no sir eg have still one electron present after pairing in case of Co(CN)5 3-.....den how inert

[@abhishekraj2194]

Marcus theory only apply for outer sphere mechanism

[@navjottaluja1871]

Fe and Mo dono ke complexes coordinately saturated hai islie there is no scope of inner sphere to take place.

[@abhishekraj2194]

plz teach important topics of physical chemistry also

[@abhishekraj2194]

thanku sir u teach ossm

[@minakshiverma9978]

Plz solve the qustion radial nd angular part.. nd also explain the thry...plz

[@minakshiverma9978]

Thanku i am wi8ing for ur video ??

[@shivprashan6940]

Mo(CN)8 is not labile .. because Mo is 4d element so high z effective .. so its inert.. inert and labile complexes concept is only for 3d metals in +2 and +3 oxid state.

[@simranahuja825]

👍🏻👍🏻yss

[@randomgyan6584]

Thanq sir.. Can u please solve some important questions on inner and outer sphere mechanism which can come in jam 2018 so that we can have a little idea about what types of questions are generally asked regarding to this topic.

[@abhishekraj2194]

being a chemistry student with bio background it's little difficult to understand physical chemistry

[@abhishekraj2194]

very thankful to u

[@abhishekraj2194]

sir when u will teach physical chemistry

[@abhishekraj2194]

thanku sir

[@KaleemKhan-lq6kf]

Is basis pe questions

[@manishayadav6247]

Sr thodi voice mai clarity kam h. Perhaps understandings is imp. than language. I thik if u use hindi we can better undestnad. Bcz ur voice is not clear.

[@dhurveintertainment.2680]

sir Plese hindi me upload kijiy n

[@bainisrilatha256]

very helpful thank you so much sir