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For BSc 1st year students-
An organic reaction mechanism is a complete, step-by-step account of how a reaction of organic compounds takes place.
The description of an organic reaction mechanism typically includes designation of the overall reaction type (such as substitution, addition, elimination, oxidation, reduction, or rearrangement), the presence of any reactive intermediates, the nature of the reagent that initiates the reaction, the presence of any catalysis, and its stereochemistry.
A common method for showing the progress of a reaction is a potential energy diagram, which plots the free energy of the system as a function of the completion of the reaction. The highest point along the reaction pathway, called the transition state, indicates how easily the reaction can occur.
carbanion is an anion in which carbon is trivalent (forms three bonds) and bears a formal negative charge (in at least one significant resonance form).
Formally, a carbanion is the conjugate base of a carbon acid:
R3CH + :B− → R3C:− + HB
where B stands for the base. The carbanions formed from deprotonation of alkanes (at an sp3 carbon), alkenes (at an sp2 carbon), arenes (at an sp2 carbon), and alkynes (at an sp carbon) are known as alkyl, alkenyl (vinyl), aryl, and alkynyl (acetylide) anions, respectively.
In chemistry, a radical is an atom, molecule, or ion that has an unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.
In chemistry, a carbene is a molecule containing a neutral carbon atom with a valence of two and two unshared valence electrons. The general formula is R-(C:)-R' or R=C: where the R represent substituents or hydrogen atoms.
Methylene is the simplest carbene.
The term "carbene" may also refer to the specific compound H2C:, also called methylene, the parent hydride from which all other carbene compounds are formally derived.Carbenes are classified as either singlets or triplets, depending upon their electronic structure.
Mechanism of organic Reaction parts -
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