Alkene + HBR + ROOR - Reaction Mechanism

[@TheOrganicChemistryTutor]

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[@Jeremy-sj3pr]

Can you please post a video for alkyne reactions with hbr and ROOR?

[@ndukanwankwo8393]

Wow explained nicely thanks

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Ty ...now this topic is as clear as glass for me 😁😁

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I'm that one dude in my class who likes Org Chem....

[@KNG8828]

well explained bro

[@hansenyang4014]

I've heard that the HBr/ROOR reaction only works for HBr but not other hydrohalic acids. Is this true? If so why?

[@bluehourcore]

this is due to the fact that the HCl bond is too strong to be broken to produce free radicals ( bond energy is 430.5 KJ/mol) while the bond energy of the HBr bond is 363.7 KJ/mol. In case of HI, although the H-I bond is broken pretty easily via homolysis, the iodine atoms so produced immediately react to form iodine molecules instead of attacking the double bond of the carbon atoms in alkene.

[@cdietrich3252]

What would be the mechanism for 2H-Br + H202 -> Br2 + 2H20 ? If the solvent is ethanol

[@aileenchalen3742]

Why doesn’t RO-Br form ? 5:37

[@kanishkraj2709]

Because we want Br• radical for our next step, where it attacks the alkene. Some of the R-O• and some of the Br• do combine to form R-O-Br, but that is not required for us at the moment for the reaction. Hope it helped

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Suggestion for A video; please make chemistry videos from the syllabus of IIT JAM exam.. One of the toughest exams in India.. Please..

[@kevinkantize844]

@Organic Chemistry Tutor, is there not an enantiomeric mixture when alkenes reacts with peroxides just as there was with HBr.

[@taradhippayom8495]

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[@epicentertainment5658]

Sir you are explaining about morkonia and anti morkania rule

[@tawneeens436]

Markovnikov and anti-Markovnikov rules and yes, the more substituted / less hydrogenated carbon gets the Halogen in Markovnikov fashion ( not in presence of peroxide’s ROOR )

[@Sanjay-hh9xl]

Hi guys