p-Iodonitrobenzene : Organic synthesis

[@ChemTalk]

Thanks for another synthesis, and nice job with the temperature control.

[@mahaveerkhadbeejbhandar1965]

Congrats for 5k

[@rabihalkaysi]

"Benzene Diazonium Bisulfate is formed and not the Chloride". Fantastic reaction. Thanks for sharing.

[@steakhousejohn5990]

Looks like you’re just about at 5k subs. Congrats!

[@ScienceWithJames]

Nice! I really like diazotizations.

[@iassejalranjitsinh6739]

Thank you sar 👍

[@ramamoothyramamoothy1854]

Sir if u use or not use for warm heating in this reaction sir...pls tell

[@UbaidsLab]

Great video!

[@Jose_Osorio]

Hi, from this experiment is it possible to separate the generated kHSO4 as a co-product?

[@anamoscardi8092]

Hi, thank you so much for posting such a nice video. I'm studying this experiment, but I'm having doubts about the mechanism. Could you make it available?

[@dimaminiailo3723]

There is an opinion that diazonium ion liberates a nitrogen molecule and forms carbocation which intercepts an iodide ion. Idk why this reaction goes much easier with the iodide salt only

[@petevenuti7355]

@@dimaminiailo3723 would iodine break up the deatonium benzenate (Bittrex) by the same mechanism. Sorry for my spelling.

[@dimaminiailo3723]

@@petevenuti7355 No it wouldn't. Iodide is a very good leaving group so the process is shifted to the side of quaternary amine what's used in the synthesis of Bitrex. What do you ask it for?

[@petevenuti7355]

@@dimaminiailo3723 mostly curious. Learning. Getting my intuition. I suggested Bittrex should have a phase transfer effect, at least if used that way it won't react with leftover iodine. Just to pick your brain, I'm looking for a way to synthesize a mostly hydrophobic ionic liquid, and quantanary ammonium is hydrophilic. Not it.. Know of anything not needed fluorine?

[@dimaminiailo3723]

@@petevenuti7355 You can add everything you want including fluorine, but the effect on polarity is pretty negligable. PTC don't need very weird groups at all!

[@Berghiker]

@6:18 The contents of the round bottomed flask was in the beaker and the potassium iodide in the seperatory funnel. Not the other way round. Why is the contents of the round bottomed flask clear in the funnel?

[@ggjndghj9946]

Why is iodobenzene not prepared in the laboratory, but p-iodonitrobenzene?

[@hugosantos5075]

Good video

[@ahmetselcuk1400]

Sandmayer 😊

[@synthesizer8026]

1:22 you need to get yourself a good funnel friend.

[@synthesizer8026]

@@vibzzlab I have one and a cheap pump on the way finally lol.

[@synthesizer8026]

@@vibzzlab yes, I got lucky finally lol

[@illya.ruslanovichshevchenk4106]

In this synthesis, nitrobenzene is not used or synthesised. Nitrobenzene, a nitrated derivative of benzene, is carcinogenic but p-nitroaniline and p-iodonitrobenzene are not.

[@parth4622]

Tlc

[@archit8157]

Nicely done but again organic synthesis?😑😑 Nonetheless,thx for subscribing...

[@archit8157]

No problem.... Always like your video🌟