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What is Volatile Fatty Acid & Alkalinity | Sanjeet S Rawat | @ETPKnowledgeJunction
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Alkalinity and VFA is a very important test that gives information about the health of an anaerobic digester. With this test, we get to know the problems that may come in the near future, whereas by the time the problem is detected with the pH imbalance, it is too late.In any well functioning anaerobic digester, two groups of bacteria work together to degradade organic matter. Saprophytic bacteria or acidogens and methane formers or methanogens.Both groups of bacteria do different things but work for each other. If their is loss of coordination, then problems will start coming in the digester.saprophytes, they hydrolyze complex organic compounds and convert them into simple organic compounds. among these short chain fatty acids, acetic acid, propionic acid and butric acid these acids are called volatile fatty acids because they have nature of volatility at atmospheric pressure. As I mentioned earlier apart from the saprophytes there are also methanogens in the digester. Methanogens convert saprophytic waste, i.e. fatty acids into methane and carbon dioxide.In a stabilized and well-functioning disaster, methanogens convert fatty acids to metane as rapidly as they produced by saprophytes.Let us once again quickly understand who works, what and how. There are two types of bacterial groups found in digesters, saprophytes and methanogens. Saprophytes i.e. acid formers break down these complex organic molecules to form fatty acids and methanogens i.e. methane formers produce methane from these fatty acids.So before understanding this, we have to know that what alkalinity actually is ?
So the alkalinity or buffering capacity of a system is the ability of system's solution to prevent the massive pH change i.e., prevents the system from getting acidified. As the saprophytes break down the complex molecules, acids are released. this leads to a decrease in the pH of the system, and here the alkalinity of the system maintains the system's pH at an optimum range. So that methanogens can do their job properly. The volatile acids produced by the saprophytes dissociates and release hydrogen ions. and these free hydrogen ions gradually lowers the system's pH i.e., making the digester acidic. But the alkalinity of the system catchup these hydrogen ions and hand over to methanogens to maintain the pH. If the system becomes imbalanced, then the alkalinity starts dissipating gradually. And the pH of the digester starts falling. When the pH drops below 6.5, the methanogens are inhibited and the digester get out of control. Means pH drops rapidly. This is because the methanogens are not able to use the volatile acid effectively. And when the pH reaches 5, the saprophytes are inhibited and the digester becomes more acidic, and then no digestion process takes place. Methanogens have a very narrow optimum range for pH and temperature and also they reproduce much more slowly than saprophytes. Although saprophytes and methanogens never compete with each other, Rather they work together. But any situation that is favorable for saprophytes and not for methanogens lead the digester towards acidity. By monitoring the relationship between VFA and alkalinity, we can check whether VFA is increasing and alkalinity is decreasing. ph monitoring is a very old way of monitoring the digester, which is not quite right. Because a drop of 1 point in pH can disturb the alkalinity of the entire system And here then it will be difficult to bring the system back to normal. Because the change in VFA alkalinity relationship takes place long before the change in pH. The ratio of VFA alkalinity should be kept between 0.05 to 0.15 and if the ratio starts going outside the limit then understand that there is going to be a big mess.
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