I'm sorry my friend but why on earth would the k value be of any interest here? Molarity is to do with number. It is 6x10 to the power of 23 atoms - that's it and that is a mole. Stick that number of atoms in a liter solvent and you get a molar solution. Half that number in a lire is half molar. Half that number in a half liter is a molar solution and so on. The problems arise because different atoms are different weights. But that's easy to understand 10 cars are heavier than 10 bicycles
@ThinkingandTinkering11 жыл бұрын
No, I tried it lol. Then I realised it was a cold cathode light. So, thought it is bright it doesn't have nearly the same energy as xenon flash
@ThinkingandTinkering11 жыл бұрын
Too much to do lol - sulphur batteries have been on my mind too
@BorutPeterlinPhotography10 жыл бұрын
Hm... Could you please somebody confirm that PVP is POLYVINYLPYRROLIDONE? Thank you! Robert for president!
@ThinkingandTinkering10 жыл бұрын
I noticed a few posts from you that i seem not to be able to reply to - thankfully i can reply to this one - first point - don't shout please - caps is the text equivalent of shouting - PVP is polyvinylpyrrolidone at MW 100,000g/m. A polyol is a generic name for glycols - I use diethylene glycol but you can use other glycols. Red Copper oxide is best found from a pottery supply company as it is used in glazes
@BorutPeterlinPhotography10 жыл бұрын
Thank you! Sorry for asking such elementary questions. I'm a professional photographer, so you can also ask me which camera is the best for no money, as I'm asked quite a lot.
@ThinkingandTinkering10 жыл бұрын
Borut Peterlin no worries mate
@ThinkingandTinkering11 жыл бұрын
lol - it's by ratio of weight of monomer - otherwise you would be chucking tons in there - redo with monomer weight - aggregation - could be because of many things lack of process control but more likely from what you said about PVP ratios i guess insufficient PVP
@ThinkingandTinkering11 жыл бұрын
Say I gave you a bag of apples and a scale and the weight of one apple and asked you to tell me the number of apples in the bag - I'm pretty sure you could do it. It would be the weight of the bag divided by the weight of the single apple. It's like that with atoms. Molar mass is just the weight of 6x10 to the power of 23 atoms of that particular substance (or molecules) so though it seems to be a mass it isn't really it has nothing to do with density - it is just a number - hope this helps
@KyleCPM7 жыл бұрын
GReat Info Rob; Thank You for your pioneering and sharing of such critically useful methods and materials, with the rest of the world.
@ThinkingandTinkering7 жыл бұрын
cheers mate
@MYNICEEV11 жыл бұрын
Great video. I watched but only understood some of the information. But I was able to follow the process quite easily. I am looking forward to you using it as an ink. Do you have printer that you can use for these experiments? Or are you gingerly using your main printer? Thanks as always for sharing.
@ThinkingandTinkering11 жыл бұрын
Lol alway gotta go one better lol
@CPedersen201210 жыл бұрын
Absolutely brilliant. I spent more than 4 months working on this to not as good results...
@ThinkingandTinkering10 жыл бұрын
cheers mate
@ThinkingandTinkering11 жыл бұрын
Absolutely it would be good for iron cobalt bi metallic particles too
@wanisamohammed7504 ай бұрын
Thanks 👍😊 you, I am just need the grams please
@ThinkingandTinkering11 жыл бұрын
You certainly should you have the right approach
@ThinkingandTinkering11 жыл бұрын
I'm not sure I'd have to check
@ThinkingandTinkering11 жыл бұрын
The polyol synthesis is really useful mate
@ThinkingandTinkering11 жыл бұрын
Lol
@ThinkingandTinkering11 жыл бұрын
Cheers mate
@ThinkingandTinkering11 жыл бұрын
Cheers mate
@magnuswootton61815 ай бұрын
its the colour of the metal already!!!
@ThinkingandTinkering11 жыл бұрын
I have one ready lol
@ThinkingandTinkering11 жыл бұрын
Cheers mate
@ThinkingandTinkering11 жыл бұрын
Like it lol
@thewar2005 жыл бұрын
Amazing videos. I love them all What's the acid's name you show in that black plastic pack ? Thank you so much
@atharvah27052 жыл бұрын
Ascorbic acid
@ThinkingandTinkering11 жыл бұрын
I'll try sometime
@kiyannareynard-eu7ph6 ай бұрын
Obviously copper acetate is one of the few copper salts that are water soluble, I'd recommend avoiding touching it with bare hands. In pigment / painting terms, it's also called verdigris
@Bearfoot-e3e4 ай бұрын
What is copper dissolved in vinegar and salt?
@JonathanFosdickNano11 жыл бұрын
I just looked into it Li can be.. (LiCH2CH2CH2NMe2)4 *perfect* and without O2 around during reduction, it would make nice Li nanoparticles .. there was a paper and video I just remembered, showing a Li-ion microbattery being 3D printed in the US, University of llinois I think.. Wild, I think I understand how that could be built from scratch now :)) next one to figure out would be the new Li+/Sulphur/MWCNT types.
@JonathanFosdickNano11 жыл бұрын
Could Fe-Co convert an alternating magnetic field's energy and send it through graphene like other systems? That could work quite well I think ..nano induction o.O
@petevenuti73552 жыл бұрын
Do you know if you made Chevreul's salt instead? The complex has a similar appearance. ... the so4 got reduced to so3 instead of the copper to metal? How would one check in a kitchen lab?
@atharvah27052 жыл бұрын
Sir, why are we adding Ascorbic acid? I want to create this as mini project. Please help me. I need thorough explanation on this experiment and proper steps to success this. It is very important for me, please help.
@cedricproper5256 Жыл бұрын
Does the stirring magnetic field bear any influence on the reaction of the nano copper with regards to electrochemistry? I'm guessing that the insulating component would have some type of buffering effect which keeps the nanoparticles small as you have indicated earlier in this video. Could the magnetic stirring be reproduced without the magnetic field and produce the same results? Thank you for publishing this experiment. It has me wildly curious.
@JonathanFosdickNano11 жыл бұрын
It should, I reckon.. just want to say cheers for your VERY informative videos :)))
@JonathanFosdickNano11 жыл бұрын
I never went to college but for a year of graphic design LOL (now I think I should have been a chemist instead)
@JonathanFosdickNano11 жыл бұрын
Bimetallic nanoparticles... my mind's racing now ..talking about ideas sparking of other ideas :))
@NoahKainWhittington Жыл бұрын
Do you think an infra red laser would sinter it as well? Or is the flash the only method?
@JonathanFosdickNano11 жыл бұрын
I know the feeling, been thinking about them as well.. hahaha
@andreweden80413 жыл бұрын
Hi Robert, I love your channel, its a really great contribution to science in my opinion. I'm wondering if you have any thoughts on electrochemical processes for the manufacture of nano Galfenol. I've looked at some ways but wonder if you have or know anyone with practical advice. Cheers.
@mhatima597411 жыл бұрын
Hi Robert, sorry i am not polymer chemist, still i have got problem in calculating the mass of pvp for a given cncentration, i tried my best to calculate the mass of PVP using monomer mass that is 0.08 X 112.9g/mol which is 9g of PVP for 100mL, i'm right? do we use this calculation for all PVP, i mean no mater which k-value we use
@mhatima597411 жыл бұрын
Hi Robert, Quite interesting presentation, I tried to reproduce the first paper and I have got aggregated particles, any idea? in addition I would like to know the mass calculation of PV with a given concentration, for a given concentration of 0.8M, with a PV 30,000g/mal, for a 100ml solution, i have got 2400g of PV which is unbelievable.
@MYNICEEV11 жыл бұрын
I got two. Says he standing tall and swaggering. LOL LOL LOL
@MukeshYadav-yg4mk5 жыл бұрын
is there any indication that my agno3 is reduced or not if i m reducing it with only ethylene glycol
@Caybeats11 жыл бұрын
Hi Robert! Nice work! Can you do some videos for Electrolytes? For example, Ethylene carbonate (Lithium batterys) or somting similar?
@JonathanFosdickNano11 жыл бұрын
Cool!! Does the polyol method work for Cobalt?
@serkansevinc807110 жыл бұрын
Hi Robert I have done the similar rxn but ended up with yellow brown color but I added 1 gram Copper acetate accidentally and what should I add to make conductive adhesive after I get copper nano-particles Thanks
@ThinkingandTinkering10 жыл бұрын
hiya mate see the ink paint basics video Making Inks And Paints - The Basics
@permababy11 жыл бұрын
If you don't flash the solution, is the ink not conductive? If it's not this would be a cool way to make a PCB: spread the ink over an entire surface, for example over a piece of glass. Then transfer toner to the surface where the toner covers the areas you don't want to be conductive. Next flash the surface. The bare ink would become conductive and presto, your PCB is ready for use.
@ThinkingandTinkering11 жыл бұрын
good idea - but this is what light forge are doing but with copper oxide instead of copper as xenon flashing reduces the oxide to copper and you don't have the same stability problems with copper oxide inks
@lendasock8 жыл бұрын
Hi Robert, I am really interested in making this. However I was wondering if it was safe to put on skin? Also I wanted to know if you could create a circuit with your body with this substance. i.e. have a break in the circuit that you could put your hand over to close the circuit? Thanks!
@ThinkingandTinkering8 жыл бұрын
i don't know how safe it is i have never tested it - i would wear gloves personally
@markhodgson23484 жыл бұрын
Hi Rob I realise this is a old video, but I'm trying to find "PVP" on Ebay I have got the other items no problem, thank you
@charliejames22984 жыл бұрын
I Believe PVP is an abbreviation of " Polyvinylpyrrolidone" if you search for this in Ebay you should get some meaningful results
@zine2hamster9 жыл бұрын
How exactly can one make ink from the collected copper nanoparticles? do you have to mix it with a liquid or something?
@ThinkingandTinkering9 жыл бұрын
zine2hamster I have a few videos on inkmaking in the youtube playlist - have a look at them
@MYNICEEV11 жыл бұрын
That smee all over. LOL.
@muralidharreddychalla38778 жыл бұрын
can produce this copper ink for commercial purposes
@ThinkingandTinkering8 жыл бұрын
+muralidharreddy challa I suppose you could if you wanted to
@mshigaev15645 жыл бұрын
за статейки спасибо.
@jefffrusha654810 жыл бұрын
How did the sintering go? Might look at using an electronic flash, which I've been seeing used with electroconductive ink, after watching your video
@jefffrusha654810 жыл бұрын
Sorry. Just changed settings and now I see the flash-sintering info. Planning to follow this setup, rinse the copper, and try water-soluble paste flux as the ink base, then flash it and see how it does, as well as sticking to the blank pc-board.
@ThinkingandTinkering10 жыл бұрын
Jeff Frusha cool - i have to do the demo on this - been a bit busy of late
@angelabehrens30918 жыл бұрын
Molecular weight of your PVP?
@ThinkingandTinkering8 жыл бұрын
130,000
@agentbertram47697 жыл бұрын
Most interesting... As always Rob. We are in your debt.
@ThinkingandTinkering7 жыл бұрын
glad you liked it mate
@navishkotwal8 жыл бұрын
can we use polyethylene glycol if diethylene glycol is not available? if yes can we put the same quantity ?
@ThinkingandTinkering8 жыл бұрын
+navish kotwal you can certainly try it
@JonathanFosdickNano11 жыл бұрын
Li? :)
@muralidharreddychalla38778 жыл бұрын
can we use copper nitrate trihydrate instead of copper acetate and citric acid inplace of ascorbic acid
@ThinkingandTinkering8 жыл бұрын
+muralidharreddy challa it makes sense - so give it a go mate
@muralidharreddychalla38778 жыл бұрын
+Robert Murray-Smith. actually it didn't work, resulted in a dark blue solution and that's it no reaction is taking place
@ThinkingandTinkering8 жыл бұрын
+muralidharreddy challa well there you go - you have your answer - though if it is dark blue sounds to me like your concentrations were way to high and i am guessing the reaction conditions weren''t particularly well controlled. Did you try copper (II) nitrate and ascorbic acid? copper (I) nitrate? - it might be the citric acid is just a stabilising agent and you might have to add an additional stronger reducing agent?
@mauriliosantosjunior11 жыл бұрын
Great work. Thank you...
@editthlh8 жыл бұрын
Thank you
@pluizenbol677 жыл бұрын
Is this ink suitable for electroforming?
@ThinkingandTinkering7 жыл бұрын
worth a try
@6969smurfy11 жыл бұрын
2nd :)
@localbroadcast8 жыл бұрын
sweet i knew I ordered that PVP for something!!
@ThinkingandTinkering8 жыл бұрын
+localbroadcast lol
@localbroadcast8 жыл бұрын
hey do you have any advice on how to predict what will be substituted by what, like in your video of copper sulfate iron chloride blender thing?
@ThinkingandTinkering8 жыл бұрын
+localbroadcast pauling's scale will help mate
@localbroadcast8 жыл бұрын
thanks a billion.
@Alonkr7 жыл бұрын
Where do you find PVP at 100,000g/m? I can find 40,000g/m everywhere, and 1,300,000g/m sometimes....
@ThinkingandTinkering7 жыл бұрын
i just searched a few chem houses - no one in particular