Any energy change can be decomposed into contributions from heat and work. This fact is important enough that to be labeled the First Law of Thermodynamics.
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@zulqarnainchaughtai2 жыл бұрын
I wonder why the academic channels which explain concepts in depth go underrated on KZbin.
@PhysicalChemistry2 жыл бұрын
Probably for the same reason that novels sell more copies than textbooks. It takes much more work to follow a lecture than to watch a music video.
@borutoxg_272 жыл бұрын
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@scienceidisolated66592 жыл бұрын
YOU EXPLANATION IS AMAMZING .
@PhysicalChemistry2 жыл бұрын
Thanks!
@abcd0038 Жыл бұрын
Sir if we heat an liquid and as a result volume increases.thus we can say that the ∆u=q-w.
@abcd0038 Жыл бұрын
Since +q is because of transfer of energy into the liquid.
@abcd0038 Жыл бұрын
-w is because of the expansion of liquid when heated.since w=-Pext . (∆v),vf is greater than vi as it is expansion process.so w =-p∆v
@abcd0038 Жыл бұрын
Is it correct sir?
@PhysicalChemistry Жыл бұрын
Well, I would say ΔU = q + w, probably because I'm using a different sign convention than you are. But yes, the first law of thermodynamics always holds, including for heating liquids.
@PhysicalChemistry Жыл бұрын
Yes, the sign of q will be positive when a liquid is heated, because energy is transfered into the system in the form of heat. (But q always shows up with a positive sign in the first law, ΔU = q + w.)