To be fair, when there's fire or explosions involved I suspect Neil doesn't require all that much persuasion :D
@DanielWillems19954 жыл бұрын
Its that damn white/grey curly hair, irresistible to Neil
@rogerc79604 жыл бұрын
Just don't tell him how highly toxic it is.
@whazzup_teacup4 жыл бұрын
Must be blackmailing
@arcanics19714 жыл бұрын
I have a sneaking feeling that Neil doesn't take too much persuasion.
@ezraclark79044 жыл бұрын
We don’t know what methods are necessary for persuading Neil, perhaps he likes treats, maybe it’s all reverse psychology, it’s an ongoing experiment.
@ChinnuWoW4 жыл бұрын
You need a Neil-detector made of Plutonium Oganesside
@metal_musician44584 жыл бұрын
Or the professor has proficiency in Persuasion
@5Andysalive4 жыл бұрын
depends on who pays for the metal.
@guythat7794 жыл бұрын
Tbf it does seem that the thing slowing down uploads is neil deciding if he wants to or not
@RafaelSCalsaverini4 жыл бұрын
"This metal is very expensive, so we're going to spend a significant part of our very small samples to teach the public about chemistry" This is very generous.
@olavl88274 жыл бұрын
Persuading Neil: Hey Neil, would you like to set something on fire?
@ThePlacehole4 жыл бұрын
Neil:
@stuehleruecker4 жыл бұрын
When i remembered right part on the chemical university burned to flames years ago. That was on time by the first periodic elements videos. Then since Neil never talks. Its strange.
@DFPercush4 жыл бұрын
@@stuehleruecker HMMM lol... but naw, that's just his stage persona. He gets chatty in the outtakes ;)
@LucarioBoricua4 жыл бұрын
@@ThePlacehole until it's a chunk of an alkali metal! Neil: [barely audible] Nice [Potassium explodes in a pond] Neil: [barely audible] Whoa
@pcfilho4254 жыл бұрын
Element: exists. Professor Poliakoff: I persuaded Neill...
@garethdean63824 жыл бұрын
"Now you wouldn't think you could get a gram of Francium, but I persuaded Neil..."
@MiniMackeroni4 жыл бұрын
"So anyway, I started persuading..."
@rtpoe4 жыл бұрын
@@garethdean6382 "And then we made some Francium Astatide - FrAt"
@abigaildavenport81953 жыл бұрын
i have to admit i want to know his tactic for this
@jorgepeterbarton3 жыл бұрын
@@abigaildavenport8195 what would be neills payment? What materials does he eat? Etc.
@MLG_17384 жыл бұрын
"For some reason Litetium is extremely expensive" *piece flies across the room*
@nasonguy4 жыл бұрын
I saw that too. According to google (!) lutetium costs $10,000 per KG. So realistically, that was maybe $30 or $40 that went flying. Don't get me wrong, I wouldn't want to lose $40, but it's not like they dropped $5000 worth of metal. Edit: So the density is 9.85 grams per CC. That sliver looked to be about a centimeter long, and pretty thin. We'll say a millimeter just to keep it simple. So that's .01 CC. So .1 Gram of Lutetium. .0001 x 10000 = 1. So more like $1 went flying.
@MLG_17384 жыл бұрын
@@nasonguy Really did your research 👏🏾 I forget that people advanced in years sometimes consider things more expensive than we would these days. To him that little sample was probably a big investment lol
@darnoc44704 жыл бұрын
@@nasonguy one seller (that i trust somewhat) sells a gram of supposedly 99,95% purity for about 10€. Sigma-Aldrich however, which is a supplier for analytical chemicals for many universities, sells a gram for about 600€ (lump) to 900€ (fine powder). I guess they took the Sigma-Aldrich prices as a general guide.
@nasonguy4 жыл бұрын
@@darnoc4470 Totally editing to completely rewrite my comment, haha. 10 euros a gram isn't too far off 10,000 USD per KG.
@darnoc44704 жыл бұрын
@@nasonguy Sorry, i didnt mean to correct you ;) I commented to explain why the prof said Lu was very expensive
@jacobesterson4 жыл бұрын
This channel, and specifically this series is criminally underrated.
@BigDaddyWes4 жыл бұрын
1.5 million subscribers is hardly small.
@OmarBKar-sw1ij4 жыл бұрын
Hey shaco
@Rheenen4 жыл бұрын
This channel has almost 250 million total views. Don't know you can call that underrated
@koolaidman3244 жыл бұрын
He got knighted for this channel lol
@LunaticTheCat4 жыл бұрын
@@koolaidman324 That's amazing lol
@mreknijn4 жыл бұрын
I love these new videos on elements, especially the lesser known ones. They always turn out to have unique and interesting properties after all. Keep 'em coming!
@general_prodigy4 жыл бұрын
i doubt having a red colour from flame test and forming nitrides and oxides is an "interesting property"
@Postghost4 жыл бұрын
Easily the earliest I've ever been to a periodic video. It feels like an honor. In celebration I think I'll just binge the whole channel from the beginning again... been a few years since my last.
@periodicvideos4 жыл бұрын
Sounds like a good plan!
@brenokaiser15374 жыл бұрын
Met Poliakoff and Neil at Liysf 2019... I've been watching the channel ever since!
@turpialito4 жыл бұрын
Neil is such a pushover for marginally-controlled rapid oxidation reactions!
@hakanselsfors22324 жыл бұрын
What a cool coincidence! I am at this moment sitting isolated at the University Hospital in Uppsala Sweden. And I have been given a treatment with Lu177 wich is attached to a peptide (Tyr3 Octreotate) to form a compound to treat Neuroendocrine tumours. It has been used successfully in this application for many years. Neuroendocrine tumours are not very common so it is likely that it is not very well known as functioning application for Lutetium. Thank you for cool and interesting video as always! 😊
@higherperspectivephotography4 жыл бұрын
Best of luck with your treatment. Results so far with Lutetium theranostics products are very promising! I just made Lu-177 PSMA this morning at work, and we have some other Lu products coming on line as part of clinical trials. The Lu-PSMA is quite a sticky compound, so you have to be careful with handling (or risk having beta-emitting contamination all over the place). Interestingly, there are two commercially available types of Lu-177. Carrier Added (Contains Lu177m), and Non Carrier Added (just contains Lu177). The Lu177m has a half life of around 160 days, and so poses a bit more of an issue for waste disposal. We are currently using the carrier added product made by IDB in the Netherlands. We are looking to switch to the ANSTO (Australia) carrier-free product, as the waste handling is just that much nicer.
@touta26474 жыл бұрын
I used to work at that very ward in Uppsala. Indeed interesting and rare treatment, we had quite a few foreign patients receive it as well. We usually gave 4 treatments at around 2 month intervals. It is not a cure, but some patients respond very well and remain progression-free for years, and some can be re-treated by then. Bone marrow toxicity is the main limiting factor. Before therapy, a scan (often PET using 68Ga) is done to ensure that the tumors overexpress somatostatin receptors. This type of targeted therapy, using a radionuclide and a tumor-homing ligand (here, a somatostatin analogue) is called peptide receptor radionuclide therapy (PRRT).
@hakanselsfors22324 жыл бұрын
@@touta2647 Nice to hear from you! Yes I recognize everything you write. I have met patients from Ireland and Norway on my visits. For me, it has slowed down, or put a lid to the progression so to speak. Although I am back for a second round, it at least reduces the symptoms considerably. I am lucky to have a large uptake of 68ga so I can receive further treatments. Tack för att du svarade! Ha det fint!
@guitarest4524523 жыл бұрын
I wish you were my teacher when I was in school. I've learned so much from this channel alone. I work in refractory. I work with Chromium, Borax, Muradic Acid, Carbon, and mainly Graphite. It has given me a love for physics and chemistry.
@rodrigocastaneda843 жыл бұрын
Every video from this channel, is a delightful experience of nowledge. Professor martin is a chemistry rock star!
@xaviercastellanos494 жыл бұрын
Professor Poliakoff: "It was very boring, two colourless solutions mixing". Me, a biochemist: :(
@santicruz40123 жыл бұрын
As a biochemist student, i loled
@nobody8717 Жыл бұрын
Oh no! My saccharides are polymerizing!
@electronicsNmore4 жыл бұрын
Always highly informative. The color looks almost like fuchsia or magneta.
@RandyJames224 жыл бұрын
With a fuchsia so bright, you gotta wear shades?
@jorgepeterbarton3 жыл бұрын
Magenta and fuschia arguably the same thing idk. Magenta was just a renaming of fuschia after some lord but i guess it now means specific computer primary colour or printer ink now.
@AleK04513 жыл бұрын
@@jorgepeterbarton i always thought magenta was more purple and fuschia was more pink but now i have no clue
@nobody8717 Жыл бұрын
@@AleK0451 it all looks the same to me. deuteranopia.
@nancymencke69804 жыл бұрын
You are so lovely to listen to you. Not talking down to us and putting the joy of learning in our grasp
@ganrimmonim4 жыл бұрын
Truly fascinating thanking I must confess that even with my degree in Chemistry I hadn't heard of Lutetium, I was a bit of an organic specialist. Keep safe and well during these very difficult days.
@vitskotak38804 жыл бұрын
Personally I think this is one of the best videos on this channel. Niel performed beautiful experiments with the lutetium. It was a pleasure to watch. I really learned something new and exciting!
@HaR3man4 жыл бұрын
I’ve never seen someone love chemistry more than this man right here
@DoktorApe4 жыл бұрын
Lu-177 is used to treat a couple different types of cancer. The first image you show is for Lu-177 DOTATATE which is used to treat neuroendocrine tumors (commonly found in the pancreas or small intestine; what Steve Jobs had). Lu-177 PSMA is the agent used to treat prostate cancer. I believe, though I might be misremembering, that Lutetium is also used to dope scintillators used to detect gamma rays (like in PET scanners)
@TheArtichokeMan4 жыл бұрын
Thank you for all of your hard work, I very much appreciate this video series. Marvelous, simply marvelous.
@Thingsyourollup4 жыл бұрын
Just found your channel not too long ago and watched a ton of your videos. Some of them several years old. Wish I could have had a science teacher like you when I was in high school. I might have had a completely different career path. Glad to see you're doing well and still making new content. Happy holidays sir, stay safe!!!
@Vermoulian Жыл бұрын
I came here today because I read an article in the New York Times about a high-temperature superconductor developed using lutetium. If that goes anywhere this element may not remain relatively obscure for much longer.
@sillypoint22924 жыл бұрын
Woaahhhhh..... I'm craving for your videos! It's finally there 🔥🔥🔥
@WelchsFruitySnacks3 жыл бұрын
I love yalls videos. Cause you give tips and ins and outs of science. the bit "If you heat nitrates they'll give off nitrogen dioxide" is a super useful tip :D
@EebstertheGreat4 жыл бұрын
Somewhat unbelievably, this exact question of where lutetium (or rather lanthanum) appears on the periodic table just came up in my life yesterday, the same day this video was uploaded. I also find the argument somewhat academic, but in this case it was really about which arrangement of the periodic table to buy. So it could never be more relevant!
@andrewradford62673 жыл бұрын
Do love these educational nuggets. Always learning something new.
@codyhufstetler6434 жыл бұрын
You missed a big use of lutetium! I do some work involving lutetium in the form of LYSO (lutetium-yttrium oxyorthosilicate), which is a scintillator. For those unaware, a scintillator is a material that converts single high energy radiation particles to low energy bursts of photons (usually in the visible range). These bursts can be measured and analyzed to detect and measure radiation. As a scintillator, LYSO is very fast in terms of decay time (the speed of the "burst"), so it's used in PET and other high speed stuff where timing is critical. It's also incredibly dense (about on par with steel), so it can trap fairly high energies. Also, many scintillators can't deal with water vapor, or oxygen, or they're toxic, or carcinogenic, or have some other fundamental problem - but LYSO is basically inert, except for some very minimal background radiation. It also has relatively high light output, making it easier to read out and yielding a better signal to noise ratio than other options. Of course, LYSO has the same problem you had in this video... EXTREMELY high cost. If someone is using LYSO, you know there's a darn good reason, because that stuff does NOT come cheap. Not only is does it contain lutetium, it needs to be carefully grown into a perfectly clear crystal, which is... tricky, to say the least. It's not something you want to drop while walking across the shop floor.
@garethdean63824 жыл бұрын
Dropping it on a shop floor is why I have a teeny, tiny fragment of LYSO in my crystal collection. Fortunately, it was not me that broke the crystal.
@someastrophysicist78084 жыл бұрын
Lutetium actually has a major use in industry that was not talked about much that shocked me. Lutetium is a component of the LSO scintillator crystal, which is used for radiation detectors. It’s primary use is in PET and SPECT cameras, but is also used in X-ray astronomy. Anyways, I was surprised that the radiotherapy application was mentioned but not the use in PET cameras.
@brfisher11234 жыл бұрын
I believe LYSO crystals are radioactive themselves due to the presence of the long lived radioisotope ¹⁷⁶Lu which makes up 2.6% of all natural lutetium as pointed out in this video.
@TiSapph4 жыл бұрын
Lutetium is also an extremely promising candidate for optical atomic clocks, having many advantages over the current Al and Yb clocks
@PopeLando4 жыл бұрын
I own an Aluminium clock. It's not very pretty.
@TiSapph4 жыл бұрын
@@PopeLando Haha fair enough!
@Smart-Skippy4 жыл бұрын
Hehe. I'm from Perth West Australia. The paper on meteorites was from WAIT (Western Australia Institute of Technology)which is now called Curtin University. It was going to be renamed WAIT & C (Western Australia Institute of Technology & Computing). Lots of Hafnium in Western Australia. I didn't know it came from outer space... Then again, everything did. Love your videos guys. I've learned so much.
@keenanavers2714 жыл бұрын
It is a great nonmagnetic substitute for Yb. I am finishing out my PhD work in a lab that specializes in growing single crystals of lanthanide compounds. If you have a single crystal of YbFe5P3, and a single crystal of LuFe5P3( assuming both exist and have the same crystal structure) you can measure the heat capacity and/or the electrical resistivity of both and subtract the latter compound from the former compound. I am sure the professor can talk how the f-shell of Yb is one electron short (depending on oxidation state), while the f-shell of Lu usually has all 14 f-electrons. The hard part is actually growing the single crystals in molten In, Sn, Pb, Ga, Bi, Zn, etc at ~1000 C.
@Felixkeeg4 жыл бұрын
Carl Auer von Welsbach actually had some intersting inventions and even was founder of the brand Osram (which produce lights). Actually, it would be neat to see a series on the lives and inventions of 19th-20th century chemists.
4 жыл бұрын
Your chemistry videos are the best in the world
@arcanics19714 жыл бұрын
I learned in school that THREE people discovered it at almost the same time, the two named and an American chemist named Charles James. I also thought Welsbach was an Austrian. Not that these at all effect my enjoyment of the video. It's just rare that I can add something but details of this one stuck in my memory because it's number 71.
@andrewmorrow74724 жыл бұрын
Lutetium is also used in scintillating crystals in PET scanners (LSO and LYSO)
@Chamelionroses4 жыл бұрын
Your channel has always been so helpful. I am not able to get higher education but so enjoy sharing such fascinating info with family.
@knumbtummy4 жыл бұрын
Hope you have been safe, professor!
@fistifahid95704 жыл бұрын
In which university..
@salthesalad55214 жыл бұрын
Good work as always Martin these videos always bring a little spark of joy in my life
@Ranko_o3o4 жыл бұрын
Always a pleasure to see you cover another element!
@TheRabidDolphin994 жыл бұрын
Notifications for your videos brighten my day instantly :)
@coredumperror4 жыл бұрын
"Prostate cancer, a very unpleasant disease." Dr. Martin understating quite a lot, here. hehe
@sanjaymatsuda45044 жыл бұрын
6:00 Abundance is misspelled twice.
@swanurine3 жыл бұрын
Its funny how a chemistry professor at the top of his field still has a soft spot for pretty chemical colors
@graemepatterson4 жыл бұрын
2:02 "So we only had very small pieces of the metal" *yeets a piece of it off-screen*
@ptinvite79423 жыл бұрын
yeets?? a word not found in any of my dictionaries
@MayBuggsChannelYT4 жыл бұрын
love your vids! there very easy to understand for me, and I'm in 8th grade! thank you very much! I use these for school!
@rishavkumarmund26744 жыл бұрын
Everything in professor video is awesome which motivate us to love chemistry
@Rex1Mundi4 жыл бұрын
LuAG:Ce is also commonly used as a scintillator to convert synchrotron X-rays to visible light in a sCMOS (or CCD) camera for imaging.
@stefanmauhart63184 жыл бұрын
my one and only fav chemistry channel
@diewildemathilde44324 жыл бұрын
Just a little nitpick I have, Carl Auer von Welsbach was from Austria, not Germany
@SonofTheMorningStar6664 жыл бұрын
This is about chemistry. Not history.
4 жыл бұрын
@@SonofTheMorningStar666 Chemistry is history in big parts.
@diewildemathilde44324 жыл бұрын
@@SonofTheMorningStar666 No, if it were solely about chemistry the history of this elements discovery would not have been covered. It is about the history of chemistry, where they have made a mistake that I pointed out, or do you have a problem with that?
@SonofTheMorningStar6664 жыл бұрын
@@diewildemathilde4432 Ouch! In a bad mood? My answer is no and my comment was ment to be lighthearted.
@kriki1894 жыл бұрын
@@SonofTheMorningStar666 Still, if you are stating anything, and some parts are not true, simply it loses relevance
@shkotayd97494 жыл бұрын
The Professor is most effective at persuasion!
@JayakrishnanNairOmana3 жыл бұрын
If I never knew him and saw him at a supermarket, I would have probably guessed him to be a chemistry professor
@bluelight26814 жыл бұрын
Im so happy to see you well!!
@rreinehr14 жыл бұрын
I swear to the almighty chemistry gods, I was just reading the Lutetium Wikipedia article. Freaky...
@32161004 жыл бұрын
That's why they chose to make this video.
@danielkron25134 жыл бұрын
It's called Baader meinhof phenomenon, aka the frequency illusion
@rbrucebicknell50384 жыл бұрын
Plate of Shrimp (Repoman reference)
@555fire...4 жыл бұрын
@@danielkron2513 more likely google using your data
@rreinehr14 жыл бұрын
@@danielkron2513 yeah I understand that, but I was at the time literally just (as in closed chrome and opened KZbin) and boom top of the new sub videos was this. Perfect timing.
@ChemicalForce4 жыл бұрын
I also plan to make a video about lutetium!
@Yian.3 жыл бұрын
I enjoy learning these facts.
@zbs83344 жыл бұрын
I am so happy you are still alive!
@JOpethNYC4 жыл бұрын
Keep the chemistry coming 👨🔬⚛️🧪⚗️ I use some of your content to help me teach chemistry and physics.
@fail0r4 жыл бұрын
Auer von Welsbach was an Austrian chemist. The big chemistry lecture hall at University of Vienna is named after him.
@RaExpIn4 жыл бұрын
Dissolving the decomposed nitrate should form the chloride, when reacted with hydrochloric acid, which could have been used to get a strong flame color.
@cellogirl11rw554 жыл бұрын
Oooo! I love that color! Very pretty! Thank you for sharing!
@rtscuycjkk Жыл бұрын
Another potentially game changing future application: Ambient Superconductors.
@عبدالكريمراشد-ح1ف4 жыл бұрын
Thanks so much Professor for explaining , very useful information's my regards.
@vj.joseph10 ай бұрын
30 degree angle holder for the bunsen burner can be made for tilted test tube observations.
@GIRGHGH4 жыл бұрын
I would have liked to have heard more of it's physical properties, even if it's not particularly spectacular.
@GIRGHGH4 жыл бұрын
@MichaelKingsfordGray Plenty of people know my name, it's just a privilege. One that evidently is not worthy of you, sir. Why are you getting combative to a stranger just expressing a suggestion on an educational video?
@adriangaleron32933 жыл бұрын
"My personal feeling is that...🥁 This is not a terribly important point" Please be the president of the planet!! I love when non important debates are totally ignored.
@barkinghampalace50324 жыл бұрын
This guy and his hair are global treasures.
@stephan52794 жыл бұрын
I like your videos, which often give me inspiration for my work. But I have just a little remark: Carl Auer von Welsbach was not a German, but an Austrian chemist... and yes... There is a difference...
@Samihamcat4 жыл бұрын
Love you professor Poliakoff
@annette_lu4 жыл бұрын
I have a newfound appreciation for my last name
@jimastra84883 жыл бұрын
I hope everyone is okay. I miss them
@AD-bs6kf4 жыл бұрын
Happy to see everyone safe and healthy
@ProbablyShubham4 жыл бұрын
They uploaded finally! I'm so happy! Made my day.
@vernonbrechin42074 жыл бұрын
Thank you for that description and illustrations. It makes me curious regarding the where in the light spectrum that red emission is and what the chemical dynamics were in that flame.
@p911c323 жыл бұрын
Auer von Welsbach was an Austrian, born in my town Vienna, and beside this element heavily involved with the discovery of Neodym, Praseodym and Ytterbium... as I just learned
@allyourcode Жыл бұрын
We need a video about the new room temperature super conductor.
@cronachedaroma4 жыл бұрын
Prof. You are the best!!!
@mixedboi4 жыл бұрын
Thank you so much for what you do.
@moonboogien89084 жыл бұрын
This week in "persuading Neil"
@glenmartin24373 жыл бұрын
Do not ever remember handling this in the laboratory. Thanks for the video.
@giordy90134 жыл бұрын
A new video of an element, thanks guys 😍😍
@-Juney- Жыл бұрын
Lutetium has always been my favorite element.
@strongforce23154 жыл бұрын
2:08 a piece jumped away
@CristiNeagu4 жыл бұрын
There goes $10... (Probably not. Lutetium is expensive at $10,000 per kg, but i doubt that piece weighed 1g.)
@Olhado2564 жыл бұрын
@@CristiNeagu Wow, I'm putting "1kg of Lutetium" on my Christmas wishlist. You never know!
@charliekilleen56004 жыл бұрын
Didn't the symbol for copernicium get chosen to be Cn to avoid confusion with the cyclopentadienyl ligand (commonly noted as Cp) in organometallic ccomplexes?
@garethdean63824 жыл бұрын
Yes, in fact this was the bigger factor, but new element names take into account any and all conflicts that may arise.
@whatelseison89704 жыл бұрын
Although Copernicium probably decidedly lives in the realm of inorganic chem, I agree that still makes a whole lot more sense than people confusing it with a name that was never actually used by anyone but some old timey Austrian.
@Bobaganusche724 жыл бұрын
Lu-177 is not just for prostate cancer, but many neuroendocrine tumors. For example, the drug Lutathera has had many successes in treating aggressive pancreatic cancers.
@gmc97534 жыл бұрын
If this is the office they give to a knighted professor, imagine what they give to new ones!
@digitalbookworm56784 жыл бұрын
Something tells me he's a bit of a hoarder. 😏
@iabervon4 жыл бұрын
This is his home study. I think it's probably what he got as a new professor and hasn't felt the need to change since.
@garethdean63824 жыл бұрын
They get a broom closet. If they're lucky the brooms are moved out first.
@jfbeam3 жыл бұрын
This is his home office. Look at older videos for his university office. (bigger, but full of stuff, too.)
@jjhhandk39743 жыл бұрын
If you doubt this mans credentials, just look at his hair. Genuine chemist
@HotelPapa1004 жыл бұрын
The red (magenta, rather) flame colour was already visible when heating the Lutetiumnitrate in the test tube (3:34). The glass was probably contaminated at the outside.
@Eddie420234 жыл бұрын
Ask some of the Deep Sky Videos cast members about Cassiopia. Also, I've always envisioned a ballista as a catapult-sized crossbow.
@GZxuanChannel-nx9vi4 жыл бұрын
AMAZING Remake Lutetium Video, Have A Safe Day!!!
@RandyJames224 жыл бұрын
Thank you, Professor!
@danstone8783 Жыл бұрын
If there was a Lutetium filament in a vacuum tube heated with electricity would it give, even momentarily a nice red light?
@AlonsoRules3 жыл бұрын
No greater honour than naming an element
@LunaticTheCat4 жыл бұрын
Yay, a new video!!!!
@loho11254 жыл бұрын
I rewatched the video about the undolliods (that is most probably spelled wrong) and wondered if you could use the resulting spheres as a catalyst because of their high surface area and convenient size. What does everybody think about this?
@pranav63524 жыл бұрын
Finally after a long time
@redthorne28363 жыл бұрын
I have been looking for the paper version of that exact table of the elements shown in the beginning. I used it in high school and have always wanted to get another. Any ideas who makes it?
@nurlatifahmohdnor89392 жыл бұрын
Rawa Island was discovered by T. M. Archibald. Page 706 L. S. D., £. s. d., or l. s. d. = (in Britain, esp. formerly) abbrev. for librae, solidi, denarii. [L: pound, shillings, pence]
@nurlatifahmohdnor89392 жыл бұрын
Ly -sergic Diethylamide L. S. D.
@felixgrosjean91764 жыл бұрын
This man is the perfect solution to have a peaceful day