Crystallites (grain) size from XRD data using Scherrer equation - 09

Reference paper:
www.sciencedir...
In this video, I have shown the method for the calculation of crystallite (grain) size from XRD using the Scherrer equation. For more videos, Please subscribe to NanoWorld. If you have any questions, feel free to ask me in the comment section below.
#NanoWorld
_______________________________________
For more updates follow us on,
Facebook: / fascinatingnanoworld
Twitter: / nanoworld8
Instagram: / nanoworld85
Contact: [e-mail]
______________________________________
Interpretation of SAED pattern | estimation of d-spacing & (khl) values
• Interpretation of SAED...
How to put a scale bar on SEM & TEM images (SEM/TEM data analysis)
• How to put a scale bar...
No valid atomic position available (Rietveld refinement through X’pert Highscore)
• Fixing of valid atomic...
Negative intensities in scan data points (Rietveld refinement through X’pert Highscore)
• Fixing of Negative int...
Indexing XRD peaks with Miller indices (hkl) values using X’pert Highscore software
• Indexing XRD peaks wit...
How to plot JCPDS card with the XRD data using OriginLab software
• How to plot JCPDS card...
XRD data analysis using X’pert Highscore software
• XRD data analysis usin...
Deconvolution of photoluminescence PL spectra (PL peaks fitting)
• Deconvolution of photo...
How to find peak position and FWHM of XRD data
• How to find peak posit...
How to calculate crystallites (grain) size from XRD data?
• Crystallites (grain) s...
Estimation of grain size through modifies Scherrer equation
• Grain (crystallites) s...
Crystallites size and strain using W-H plot method
• crystallites (grain) s...
Calculation of nanoparticle size through SEM image
• nanoparticles size fro...
How to find Miller indices of XRD peaks?
• How to label XRD peaks...
How to calculate d-spacing from XRD data?
• How to calculate d-spa...
How to calculate lattice constant (a, b, c) values from the XRD data?
• How to calculate latti...
How to calculate microstrain and dislocation density from XRD data?
• strain and dislocation...
How to calculate crystallinity from XRD data?
• how to calculate cryst...
How to smooth XRD data?
• How to smooth data (XR...
Baseline correction for XRD data
• Baseline correction fo...
Cyclic Voltammetry Data Analysis
• CV Data Analysis throu...
How to find bandgap energy using the Tauc plot method?
• Video
How to calculate bandgap energy using the Kubelka Munk function?
• Bandgap energy using K...
Understanding Tauc plot, 1240 (constant) and 2.303 constant
• Band gap energy (Tauc ...
How to know a material either have direct or indirect bandgap energy?
• How to know a material...
DSC Data Analysis
• DSC Analysis Through O...
TGA Data Analysis
• TGA Analysis Through O...
How to plot the double Y-axis in a single graph?
• TGA & DSC double plot ...
Electron paramagnetic resonance (EPR) data analysis (calculation of g-factor)
• Electron paramagnetic ...
_________________________________________
Music Source
Unconditionally by Broken Elegance 🎩 / brokenelegance Creative Commons - Attribution 3.0 Unported - CC BY 3.0 creativecommons.... Music promoted by Audio Library • Unconditionally - Brok...

[@From_Crowd_to_Nation]

Very good sir 👍 Nice effort I was using origion+Excel but followed long procedure , you made a good effort and short path to find FWHM and average crystallite size I appreciate you

[@evaristosalaya5111]

Thank you so much. Excellent video, easy to follow and well-explained.

[@sennali7634]

Written in a very detailed! Thank you so much!!

[@9715256854]

Your video was helpful to calculate the crystalline size. Thank You.

[@imyemouna9664]

I am very happy when i watch the video 😁

[@cuonglevan134]

Thank you for sharing, this really helpful, Respect !!

[@nanoworld6122]

Glad it was helpful!

[@tiffanyk5259]

So informative! Thanks a lot!

[@vadelrionneskara4623]

Thank you. Your video helped me prove D value in today’s mid term exam. It was 30 marks.

[@nanoworld6122]

All the best

[@idarssy]

Thankyou, for this great video, this so help me a lot ☀ thxx

[@nanoworld6122]

You’re welcome 😊

[@idarssy]

@@nanoworld6122 thankyou again, because i can pass my exam last week 😄😝

[@dr.poojashandilya6885]

Your video is so helpful, I really want to appreciate your efforts...thanks alot.....

[@nanoworld6122]

Glad to hear that

[@SaidAZ-pf2zo]

Thank you very much, Really It was very well explained, With image and music

[@tsungomm1914]

Thank you so much... Made my day

[@rafiqshaheen1158]

Its soo helpful for my exam preparation

[@nanoworld6122]

Glad to hear that

[@공포의어린이날]

thank you so much for your really well-explained video @@@!!!

[@nanoworld6122]

Glad it was helpful!

[@sanjeevkumarnitrourkela6637]

thank you sir....excellent explanation...for beginers

[@runfatan7086]

谢谢，非常有用！

[@shahinaawan7338]

Thank you so much, its very helpful. Thanks alot

[@lifesciences3889]

Helpful video.... thank you sir

[@yu-kaiwu7323]

Thank you so much, it's really helpful!

[@dr.m.bhuvaneshwaran6904]

Thank you so much sir, its very helpful. Thanks a lot

[@prg2457]

Habibi...classic job

[@magicalphysics9038]

Really nice, one small suggestion if u take this tutorial along with a clear oral explanation of yours it wil be more effective. Congratulations for such upcoming videos... Good luck👍

[@helpinghands5493]

Very nicely explained👍

[@nanoworld6122]

Thanks for liking

[@techanddesignnikhil]

thank you so much for your really well explained video.

[@dahcari6548]

Hi NanoWorld, I have question about size of material in video, I calculate size of material using Scherrer equation same in video but why 1/ My result after calculate in excel (the raw material has lower size than the material after treatment with H2SO4)- in my experiments H2SO4 will reduce size of material. I hope I would receive your answer soon. Thanks NanoWorld so much.

[@vv-ky4bi]

fantastic man...hatsoff u...

[@ayuulss7011]

thank you sir....excellent explanation...

[@ranjithvia]

Very useful one sir. thank you

[@aliyayousaf8383]

thank u so much for such a helpful video.

[@nanoworld6122]

My pleasure 😊

[@naas1634]

How to decide the y-scale when selecting the peaks? If I try different heights of the peaks while selecting them, the value turns out different.

[@erikatallyta4796]

Very good. Super easy to reproduce. Thank you.

[@nanoworld6122]

Glad it helped!

[@cigdemdikbas4573]

Thank you very much👏

[@malihaparvin4224]

appreciate your work. really helpful :)

[@nanoworld6122]

Thank you

[@samikchagurung6359]

How do I do the same in origin 6? There is no Peak and Baseline option available

[@ideasbyNTR]

When you collected peak position and FWHM values either it's 5 peaks on same plot, or same should be conducted for 5 samples separately?? Or 5/8 peaks from the single peak of any sample would be enough?

[@사서도서관]

Thank you for good video. But, I have a wondering that about your data that you had used. Is it raw data or normalised data?? If it were normalized, then I want to know what was the normallization process. Please tell me...

[@baoyuzhou7539]

真的很有用，特别是对于新手来说。

[@nanoworld6122]

谢谢

[@AbuIyaadAF]

Very much beneficial

[@magicofscience8899]

EXCELLANT👍👍👍

[@joharamin3640]

Thank you so much. A simple question, what are the parameters used for the fitting until converged. I got the COD(R^2) less than 0.5 and the fitting graph is so far of the beaks. I hope you all the best thank you.

[@nihelruiz3343]

thank you my friend

[@farrukhkhakimov1339]

Hello. How did you find the smooth one?

[@vishwajeet1211]

Thank you for making such a great work, I'm not getting precise Values of crystal size , they differ very large from each other so average is very much different, please guide 🙏🙏🙏

[@ZaratustraCoDM]

Thankyou very much :)

[@nanoworld6122]

Welcome!

[@thanhle-tr1ys]

Hey, thank you verry much

[@sudheerkumaryadav9061]

Why do we need to theta to convert in radian?

[@MuhammadSadiq-2729]

Because the values of FWHM are defined in radians so we need to convert the values of 2theta from degrees to radians. And also the mathematical relationships involved in diffraction theory are inherently based on trigonometric functions that use radians as their unit of measurement.

[@AnotherPlanet12]

You are fitting a Gauss for a Lorentzian function?

[@muhammadsaqib9392]

great job sir

[@muhammadumair9214]

hello Muhammad saqib? hope youll be fine, dear i have one thing to discus do you know how to calculate the miller indices through any way?

[@saghar_ghasemi]

Thank you very much for the helpful tutorial. May I know if we can consider this size as the nanocrystals size of our structure? In fact is there a difference between the crystallite size and particle size?

[@bruceliu9436]

sure, you could call this one domain size, which would be better differntiated from the particle size in terms of names.

[@meriembouhbou6992]

Thank you so much, very useful ==> Great Job (y)

[@gabrielamendoza8016]

Hello, for FWHM the peak 2 I always get 2. something in comparison with other peaks. I must say, in the graph the second peak is very close to the first one that the connection does not touch the base line.

[@MelomaniacEarth]

Which software?

[@guerfisouad7837]

Please help I cannot designate the vertices for each pik with a straight line. Whenever I designate a peak, it reads the values of x and y, but it does not draw a pik.

[@linshinat148]

Thank You so much

[@HelenL93]

is there a way to do this in an exam without using software? just estimate the particle size from the PXRD pattern? i have been given this as a past paper question

[@bhulidhaker8745]

PLEASE EXPLAIN ALL TYPE OF ERROR IN XRD

[@hodphypesitm]

theta can be put either in degrees or radians. It does not make difference provided you find the cos theta accordingly.

[@mdmazbahuddin5592]

Which method among DSC and XRD do you think would be more accurate for % crystallinity estimates and why? Do you think crystallinity depends on the crystal size? please explain a bit of detail. I have just begun studying, thnks

[@thiagorsvful]

No, crystallinity depends upon the intensity of the peaks and the lower the noises in the graph

[@ericzhao2687]

Thanks a lot. It is useful

[@trialunlock8706]

For converting angle theta to radian while determining the crystallite size from powder xrd spectrum why we are taking half circumference not full

[@alihasnain6204]

in data 2theta value is given so we need the value of theta so we divide the value of 2theta with 2, to get the value of theta so that we can put value of theta in scherrer formula

[@kumarswamy9777]

Please anyone help me out after 3:43 minute's how you all are getting next options Please help me am using origin 8 pro Or is any videos please send

[@varshinipreethi3189]

Sir this video is very useful. I prepared my sample by synthesis a zinc oxide nanoparticle but when I put my result in xpert highscore it shows copper and silicon oxide

[@muhammedmusharaf7966]

Thank you

[@abdullahiadamu7688]

Hi.. thank you for the knowledge you've been sharing with us. Please I couldn't analyse my xrd data using Origin. The graph doesn’t converge. It shows that mutual dependency exists between parameters. What is the solution please?

[@manjupriya6574]

I Had the same issue, when i zoomed the peaks and aligned the peak fit to the narrow line of the peak after some trials my graph converged.

[@juttwaryah..pindaywalyjutt5958]

Which software you used

[@NoorMohmed-ty6ty]

thanks a lot

[@darshanameena9776]

Sir please tell me that which method is best for finding crystalline size modified scherrer or W-H plot.

[@nanoworld6122]

W-H plot is the best method

[@darshanameena9776]

@@nanoworld6122 why?

[@Josimar.quimico]

Thank you!

[@lizatanggw2967]

Salute you!

[@bharatbhushanvarshne]

10:42, why are you dividing by 2 in the formula?

[@nanoworld6122]

Because it 2theta and i need theta only.

[@navinvijeyraj7713]

bro can you explain sin2psi technique for residual stress calculation of metal

[@rabiulislam3448]

what should be the unit of the calculated crystallite size? i think its not nm,it should be Angstrom

[@lalitarai9958]

thank you so much, it was very helpful. can you plz upload videos about DSC.

[@alanch2660]

I have a question in the Scherrer equation the value of theta, Is not necessary divide for two? Thank you for your good video.

[@nanoworld6122]

It is essential, you must divide it by 2.

[@innayk]

Thank you

[@muhsinkhan2431]

how u are selecting c[y] and A[X].

[@nanoworld6122]

Keep pressing the control button in your keyboard

[@belisariomartin3876]

excuse me, shouldn't FWHM be in 2Theta units too?

[@SauravKumar2]

hi.. can you help me in XRD analysis

[@TheBAbert]

Thank you! Excellent Video!! I only have some doubts. In my X-ray diffraction pattern appear 2 different TiO2 phases (anatse and rutile), 1.- Can I use this method if I want to measure just the anatase peaks? 2.- Do the rutile peaks affects this measurements?. 3.- Would it be valid if I select anatase and rutile peaks and calculate an average crystallite size for both phases?. Regards!!

[@AMVCreativity]

I found myself in a similar position but for an ferrous alloy lol. What did u do?

[@hema2503]

How to identify /remove FTO peaks from spectra, plz help

[@deepkumar92]

thanks bro

[@hasnainmustak2969]

I think your result is in angstrom. You need to convert that to nanometer. Correct me If I'm wrong.

[@hudaalattar206]

It would be better to add voice for explanation

[@dontseewhatyouwannasee3658]

thank you.

[@kharoumdairies]

appreciate it nice video..but music is irritating.

[@jasminm9165]

can you show how langevin fit done in origin using VSM data

[@gauravjamwal8095]

Can you please show the strain and crystallite size from Williamson hall methods for uniform deformation model? Thanks.

[@amanbayad17]

How to select Multiple peaks ?

[@vv-ky4bi]

Sir how can we measure the phase present in the NaOH treated natural fiber?? Or how can we analyse the natural fiber?

[@aamirahmed8389]

Can you plz tell me how to get the JCPDS file for a material.

[@nanoworld6122]

Send me an email, and tell me your required card no. like 01-023-0456 etc..

[@manuja6889]

Very helpful video Sir I followed the same method but I am not getting multiple peak values . I am getting only one FWHM value. Please answer me

[@nanoworld6122]

Your data might need a baseline correction. But I'm not sure yet, because I have not seen it yet. If you want me to have a look over your data, then send it to me at thenanoworld.com/contact-us/

[@ichahalwa8754]

i have poject witch i should use this logicial can you help me how i used for the begining how i importe cif file and how i used XRD please

[@naziaaslam916]

2θ β(2θ) β(θ) β(radian) θ(degree) θ(radian) D=.9λ/βcosθ =B2/2 =(C2*3.14)/180 =A2/2 =(E2*3.14)/180 =0.138654/(D2*COS(F2)) Is formula k according apki readings 57.63126 aa ri hain. Her bar change hon ge reaidngs formula change krnny sy??? Reply zroor kijye ga.

[@nanoworld6122]

Yes, If one value is changed then every value will changed. (I see an error in your formula, you should NOT divide beta by 2)

[@naziaaslam916]

@@nanoworld6122 Ok let me check again. Then I will tell you.

[@naziaaslam916]

Just this is my mistake?

[@naziaaslam916]

Yeah, I got 28. Thank u. Will u describe the reason why beta should not divide by 2?

[@nanoworld6122]

@@naziaaslam916 The sin theta represents the actual location (position) of the reflection (peaks), that's why we divide it by 2. While the broadness (FWHM ) of the peaks has nothing to do with the actual scale.

[@atanughosh8312]

Can you upload videos on XPS spectra , nanowire I-V characterization etc.

[@CrazyPhysics1]

for your reference you can refer kzbin.info/www/bejne/l2HQYa2ZepqebLc

[@zamzamarahmany5599]

What to do if the fit did not converge.maximum iteration of 400 reached I tried many times I am getting the same msg

[@sagarrawal8332]

How to find the corresponding value of y axix acrroding to peak position i.e x value?

[@bhagirathmahto4845]

Pls share the data for practice.

[@zahrasharifi8611]

Thank you for your very helping video. Would you mind filming how to draw W-H plot?

[@heryantobinhaeruddin2382]

kzbin.info/www/bejne/eZnQfmaFfcyWrMk

[@joseluisxochihuajuan7586]

Excellent video... I wanted to request the help to estimate the size of the TiO2 crystallite according to my XRD analysis. I have a problem, in the software of origin that I have installed, the commands do not appear.

[@muhammadumair9214]

download the latest version of the software, i hope this will help you.